摘要:
This invention relates to fibrils. It more particularly refers to carbon/graphite fibrils and to an improved process for producing such. Carbon fibrils as used herein means graphitic fibrils having high surface area, high Young's modulus of elasticity and high tensile strength which are grown catalytically from available sources of carbon.
摘要:
A process for preparing carbon fibrils by contacting a source of carbon with a supported catalyst that includes at least one multivalent transition metal having a size of about to 700 A deposited on an inorganic substrate having a size up to about 400 microns.
摘要:
A process for preparing carbon fibrils by contacting a source of carbon with a supported catalyst that includes at least one multivalent transition metal having a size of about 35 to 700 A deposited on an inorganic substrate having a size of up to about 400 microns.
摘要:
Methods of preparing single walled carbon nanotubes are provided. An arrangement comprising one or more layers of fullerene in contact with one side of a metal layer and a solid carbon source in contact with the other side of metal layer is prepared. The fullerene/metal layer/solid carbon source arrangement is then heated to a temperature below where the fullerenes sublime. Alternatively, a non-solid carbon source may be used in place of a solid carbon source or the metal layer may simply be saturated with carbon atoms. A multiplicity of single walled carbon nanotubes are grown on the fullerene side of the metal layer, wherein at least 80% of the single walled carbon nanotubes in said multiplicity have a diameter within ±5% of a single walled carbon nanotube diameter D present in said multiplicity, said diameter D being in the range between 0.6-2.2 nm.
摘要:
Graphitic nanotubes, which includes tubular fullerenes (commonly called “buckytubes”) and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.
摘要:
This invention relates to rigid porous carbon structures and to methods of making same. The rigid porous structures have a high surface area which are substantially free of micropores. Methods for improving the rigidity of the carbon structures include causing the nanofibers to form bonds or become glued with other nanofibers at the fiber intersections. The bonding can be induced by chemical modification of the surface of the nanofibers to promote bonding, by adding "gluing" agents and/or by pyrolyzing the nanofibers to cause fusion or bonding at the interconnect points.
摘要:
A new method for preparing a supported catalyst is herein provided. A carbon nanotube structure such as a rigid porous structure is formed from carbon nanotubes. A metal catalyst is then loaded or deposited onto the carbon nanotube structure. The loaded carbon nanotube is preferably ground to powder form.
摘要:
Methods of preparing single walled carbon nanotubes from a metal catalyst having deposited thereon fullerenes are provided. Fullerenes are deposited onto a metal catalyst precursor or metal catalyst. In the presence of a carbon containing gas, the metal catalyst precursor/fullerene composition is then exposed to conditions suitable for reducing the metal catalyst precursor, for subliming the fullerene and for growing single walled carbon nanotubes. The fullerenes form the end caps for the resulting single walled carbon nanotubes, which are uniform in diameter.
摘要:
The present invention relates to a field emission device comprising an anode and a cathode, wherein said cathode includes carbon nanotubes nanotubes which have been subjected to energy, plasma, chemical, or mechanical treatment. The present invention also relates to a field emission cathode comprising carbon nanotubes which have been subject to such treatment. A method for treating the carbon nanotubes and for creating a field emission cathode is also disclosed. A field emission display device containing carbon nanotube which have been subject to such treatment is further disclosed.
摘要:
This invention relates to rigid porous carbon structures and to methods of making same. The rigid porous structures have a high surface area which are substantially free of micropores. Methods for improving the rigidity of the carbon structures include causing the nanofibers to form bonds or become glued with other nanofibers at the fiber intersections. The bonding can be induced by chemical modification of the surface of the nanofibers to promote bonding, by adding “gluing” agents and/or by pyrolyzing the nanofibers to cause fusion or bonding at the interconnect points.