摘要:
A process for the hydrogenation of aromatic dinitriles to the corresponding cycloaliphatic aminomethyl compounds by(1) hydrogenating the nitrile in an ether solvent containing water and ammonia using nickel or cobalt as catalyst,(2) removing by-products from the aromatic diamine thus produced,(3) subjecting the aromatic diamine to hydrogenation with a ruthenium catalyst in an aqueous solvent system devoid of ammonia and(4) isolating the cycloaliphatic diamine product.
摘要:
A process for the hydrogenation of aromatic bis-methylamines, such as m- and p-xylylenediamine, to the corresponding cycloaliphatic compound by hydrogenating the bis-methylamine in water as a solvent system, devoid of added ammonia and in the presence of a supported ruthenium catalyst.
摘要:
Isoparaffins and olefins are alkylated in the liquid phase by contact with a solid superacid such as sulfated zirconia containing heteropolyacids or polyoxoanions. High octane number blending components for motor fuel and other valuable products are obtained, with important advantages over processes using liquid acid catalysts, and over vapor phase alkylation with solid superacid catalysts.
摘要:
New catalyst compositions comprise sulfated and calcined mixtures of (1) a support comprising an oxide or hydroxide of a Group IV-A element, (2) an oxide or hydroxide of a Group VI, VII or VIII metal, (3) an oxide or hydroxide of a Group I-B, II-B, III-A, III-B, IV-B, V-A or VI-A metal and (4) a metal of the Lanthanide Series of the Periodic Table. A process for alkylation of acyclic saturated compounds with acyclic unsaturated compounds utilizing such catalyst compositions.
摘要:
Polymeric complexes formed between a thermally-condensed polyacrylonitrile polymer and transition metal salts, including rare earth metals, have been found to be effective catalysts for the oxidation of compounds containing activated carbon-hydrogen bonds such as olefins, or secondary and tertiary alkylaromatics, to form valuable oxidation products, particularly hydroperoxides or their decomposition products.
摘要:
A process is provided for the enhanced recovery of oil with steam in reservoirs containing high concentrations of dissolved salts, wherein certain diaryl sulfonated surfactants are employed in conjunction with the steam which posses high tolerance for said salts. These surfactants are comprised of compositions having (1) two aromatic rings in their nucleus, such as diphenyl, diarylalkane, or naphthalene groups; (2) at least one alkyl group having 18 or more carbon atoms; and a second alkyl group having from 1-4 carbon atoms; and (3) two functional groups comprising at least one and preferably two sulfonate groups, although one of the sulfonate groups may be replaced with a carboxyl or hydroxyl groups. At least about 65% of the diaromatic compounds should contain two functional groups, preferably sulfonates, with the remainder comprising a monofunctional-substituted compound containing either a sulfonate group, a carboxylate group, or an hydroxyl group.In a further embodiment of this invention, the diaryl sulfonated surfactants may be admixed with other co-surfactants and/or hydrotropes and silicates.
摘要:
Organometallic complexes formed between hexaalkylphosphoramides (HAPA) and metal salts, including rare earth metals, have been found to be effective catalyst for the oxidation of secondary and tertiary alkylaromatics to form valuable oxidation products, particularly the corresponding hydroperoxides. Novel complexes formed between HAPA and metal salts of the lanthanide series have been found to be especially effective in the selective formation of the hydroperoxides at high conversion rates. By substantially increasing the agitation and/or aeration of the reaction medium it is possible to increase these high conversion rates still further.
摘要:
An ammoxidation process for the preparation of nitriles by reaction of m- or p-xylene with ammonia and oxygen using as catalyst an .alpha.-alumina supported vanadiumalkali metal bronze promoted with niobium, whereby a high proportion of dinitrile product is obtained. The invention also embodies the niobium promoted catalyst.
摘要:
An ammoxidation process for preparing nitriles from m- and p-xylene whereby the formation of carbon oxides is held to a minimum which comprises reacting the xylene and ammonia at a temperature of from about 375.degree.C. to about 500.degree.C. and in the presence of added oxygen, the molar ratio of ammonia to xylene being about 3:1 or less, the molar ratio of oxygen to xylene being about 3:1 or less, the volume percent concentration of the feed being preferably about 3% to 10% hydrocarbon, 7% to 20% ammonia, and 10% to 20% oxygen, and the catalyst for said reaction comprising at least about 1 to 10% by weight of a vanadium bronze supported on .alpha.-alumina.
摘要:
New catalyst compositions comprise sulfated and calcined mixtures of (1) a support comprising an oxide or hydroxide of a Group IV-A element, (2) an oxide or hydroxide of a Group VI, VII or VIII metal, (3) an oxide or hydroxide of a Group I-B, II-B, III-A, III-B, IV-B, V-A or VI-A metal and (4) a metal of the Lanthanide Series of the Periodic Table. A process for alkylation of acyclic saturated compounds with acyclic unsaturated compounds utilizing such catalyst compositions.