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    Non-crystalline polyamine/carbonic acid salt compositions, a process for their preparation and their use for the production of polyurethane ureas, especially foamed coatings
    1.
    发明授权
    Non-crystalline polyamine/carbonic acid salt compositions, a process for their preparation and their use for the production of polyurethane ureas, especially foamed coatings 失效
    非结晶多胺/碳酸盐组合物，其制备方法及其用于生产聚氨酯脲，特别是泡沫涂料的用途

    公开(公告)号：US4469856A

    公开(公告)日：1984-09-04

    申请号：US434788

    申请日：1982-10-18

    申请人： Werner Rasshofer ,  Wilhelm Thoma ,  Anton Schmitz

    发明人： Werner Rasshofer ,  Wilhelm Thoma ,  Anton Schmitz

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C209/00 ,  C07C211/09 ,  C07C211/36 ,  C07C213/00 ,  C07C215/12 ,  C08G18/10 ,  C08G18/32 ,  C08G18/65 ,  C08J9/02 ,  C09D175/04 ,  C08G18/81

    CPC分类号： C08G18/10

    摘要： This invention relates to new liquid or fluid polyamine/carbonic acid salt compositions free from crystalline content and their preparation from mixtures containing at least one aliphatic or cycloaliphatic polyamine, an aliphatic or cycloaliphatic hydroxyamine having at least one hydroxyl group and at least one amino group, and water and optionally diluents and/or conventional auxiliary agents and additives, by the addition of carbon dioxide. The proportion of polyamine to hydroxyamine is in the range of from about 95:5 to 10:90 % by weight, the quantity of water added is from about 0.01 to 5 mol of H.sub.2 O per amine equivalent (but at least 1 mol of water per mol of CO.sub.2) and the quantity of CO.sub.2 added is from about 0.01 to 0.99 mol of CO.sub.2 per amine equivalent. The invention further relates to the use of these liquid polyamine/carbonic acid salt compositions for the production of foamed polyurethane ureas, especially for coating substrates or for the production of sheet products, using prepolymers preferably containing blocked isocyanate groups and the liquid polyamine/carbonic acid salt compositions as chain lengthening agents and/or crosslinking agents and at the same time as physiologically harmless blowing agents.

    摘要翻译： 本发明涉及不含结晶含量的新的液体或流体多胺/碳酸盐组合物，它们由含有至少一种脂族或脂环族多胺，至少具有一个羟基和至少一个氨基的脂族或脂环族羟胺的混合物制备， 和水以及任选的稀释剂和/或常规助剂和添加剂，通过加入二氧化碳。 多胺与羟基胺的比例在约95:5至10:90重量％的范围内，加入的水的量为约0.01至5摩尔每胺相当的H 2 O（但每个至少1摩尔水 二氧化碳的摩尔数），加入的二氧化碳的量为每个胺当量约0.01至0.99mol的CO 2。 本发明还涉及这些液态多胺/碳酸盐组合物用于生产泡沫聚氨酯脲，特别是用于涂覆基材或用于生产片状产品的优选使用含有封端异氰酸酯基团的预聚物和液态多胺/碳酸 盐组合物作为增链剂和/或交联剂，并且同时具有生理上无害的发泡剂。

    Device and process for producing plastic components, especially polyurethane moldings
    2.
    发明授权
    Device and process for producing plastic components, especially polyurethane moldings 失效
    用于生产塑料部件，特别是聚氨酯模制品的装置和工艺

    公开(公告)号：US6136238A

    公开(公告)日：2000-10-24

    申请号：US142445

    申请日：1998-09-04

    申请人： Werner Rasshofer ,  Henry Muller ,  Achim Symannek

    发明人： Werner Rasshofer ,  Henry Muller ,  Achim Symannek

    IPC分类号： B29C33/38 ,  B29C44/00 ,  B29K75/00 ,  B29K105/04 ,  C08G18/66 ,  C22C38/00 ,  C22C38/22 ,  C22C38/24 ,  C22C38/30 ,  C22C38/52 ,  B29C41/38 ,  B29C44/02

    CPC分类号： C08G18/6696 ,  B29C33/38 ,  C08G2101/0033 ,  C08G2125/00

    摘要： The present invention relates to a process for preparing solid, microcellular or expanded plastic molded items, characterized in that said molded items are produced in molds in which the internal surfaces consist of steel with the percentage composition:a) Fe: having a wt % greater than 0 wt % and less than 100 wt %;b) at least one element selected from the group consisting of W, Mo, or V, wherein if W is selected, W is present from a range greater than 0 wt % to 40 wt %; wherein if Mo is selected, Mo is present from a range greater than 0 wt % to 12 wt %; and if V is selected, V is present from a range greater than 0 wt % to 5 wt %;c) at least one element selected from the group consisting of Cr, Al, wherein if Cr is selected, Cr is present in a concentration of greater than 0 wt % to 15 wt %; and if Al is selected, Al is present in a concentration of greater than 0 wt % to 15 wt %;d) optionally, carbon at a concentration ranging from 0.1 to 1.5 wt %;e) optionally, cobalt at a concentration ranging from 0.1 to 10 wt %; andf) optionally, nitrogen in a nitriding layer at a concentration ranging from greater than 0 wt % to 10 wt %.

    摘要翻译： PCT No.PCT / EP97 / 00952 Sec。 371日期：1998年9月4日 102（e）1998年9月4日PCT PCT 1997年2月27日提交PCT公布。 第WO97 / 34021号公报 日期：1997年9月18日本发明涉及一种制备固体，微孔或膨胀塑料模塑制品的方法，其特征在于，所述模制品在模具中制造，其中内表面由具有百分比组成的钢组成：a）Fe： 重量％大于0重量％且小于100重量％; b）选自W，Mo或V中的至少一种元素，其中如果选择W，W存在于大于0重量％至40重量％的范围内; 其中如果选择Mo，则Mo在大于0重量％至12重量％的范围内存在; 并且如果选择V，则V从大于0重量％至5重量％的范围存在; c）选自Cr，Al中的至少一种元素，其中如果选择Cr，则Cr以大于0wt％至15wt％的浓度存在; 并且如果选择Al，则Al以大于0重量％至15重量％的浓度存在; d）任选地，浓度为0.1至1.5重量％的碳; e）任选地，浓度为0.1至10重量％的钴; 和f）任选地，氮化层中的氮浓度范围为大于0重量％至10重量％。

    Polyamine crosslinking agent formulation and its preparation
    3.
    发明授权
    Polyamine crosslinking agent formulation and its preparation 失效
    多胺交联剂配方及其制备

    公开(公告)号：US5705594A

    公开(公告)日：1998-01-06

    申请号：US767564

    申请日：1996-12-16

    申请人： Klaus Konig ,  Otto Neuner ,  Werner Rasshofer

    发明人： Klaus Konig ,  Otto Neuner ,  Werner Rasshofer

    IPC分类号： C07D251/34 ,  C08G59/50 ,  C08J3/24 ,  C08K5/3492 ,  C08L63/00 ,  C08L73/02 ,  C08L79/02 ,  C08G18/08 ,  C08G18/10

    CPC分类号： C08G59/5086 ,  C07D251/34

    摘要： Liquid polyamine crosslinking agent formulations based on trimerized toluylene 2,4- and/or 2,6-diisocyanate, with formation of an isocyanurate structure and hydrolysis of the isocyanate groups to amine groups, are described. The novel crosslinking agent formulations have a content of 40 to 80% of the total weight of the solids content of the crosslinking agent formulation of 1,3,5-tris-(3-amino-4-methyl-phenyl,2-methyl-3-aminophenyl) isocyanurate (I) which is not further condensed, and a content of not more than 1.0% of the total weight of the crosslinking agent formulations of toluylene-2,4- and/or -2,6-diamine (III). For the preparation, toluylene diisocyanate is trimerized, to form the isocyanurate structure, until 10 to 25% of the NCO groups have been reacted. The toluylene diisocyanate which has not undergone condensation is then distilled off, the bottom product formed by this operation is taken up directly in a solvent A and the 30 to 70% strength by weight solution formed by this procedure is metered into a hydrolysis in water/N,N-dialkyl-carboxylic acid amide in the presence of a catalytic amount of a basic catalyst. After the hydrolysis, the crosslinking agent formulations are brought to a solids content of 35 to 60% of the total weight of the formulation by distilling off a portion of the solvents and adding a solvent B.

    摘要翻译： 描述了基于三聚甲苯2,4-和/或2,6-二异氰酸酯的液态多胺交联剂制剂，其形成异氰脲酸酯结构和将异氰酸酯基团水解为胺基。 新型交联剂配方的含量为交联剂配方的1,3,5-三（3-氨基-4-甲基 - 苯基，2-甲基 - 苯基） - 苯胺的固体含量的总重量的40-80％ 3-氨基苯基）异氰脲酸酯（I），其不再进一步缩合，并且不大于甲苯-2,4-和/或-2,6-二胺（III）的交联剂配方的总重量的1.0重量％ ）。 为了制备，将甲苯二异氰酸酯进行三聚，形成异氰脲酸酯结构，直到10〜25％的NCO基团都已反应。 然后蒸馏除去未进行冷凝的甲苯二异氰酸酯，将通过该操作形成的底部产物直接溶于溶剂A中，并将通过该方法形成的30-70重量％的重量浓度的溶液计量加入水/ N，N-二烷基 - 羧酸酰胺在催化量的碱性催化剂存在下反应。 水解后，通过蒸馏掉一部分溶剂并加入溶剂B使交联剂配方的固体含量达到制剂总重量的35至60％。

    Polyamines and a process for their production from polyisocyanates
    6.
    发明授权
    Polyamines and a process for their production from polyisocyanates 失效
    多胺及其由多异氰酸酯制备的方法

    公开(公告)号：US4724252A

    公开(公告)日：1988-02-09

    申请号：US895629

    申请日：1986-08-11

    申请人： Werner Rasshofer

    发明人： Werner Rasshofer

    IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/18 ,  C08G18/20 ,  C08G18/50 ,  C08G18/83

    CPC分类号： C08G18/5021 ,  C08G18/10 ,  C08G18/1858 ,  C08G18/2027 ,  C08G18/2063

    摘要： Polyamines containing aromatically bound primary amino groups are prepared in a single stage process by hydrolyzing an isocyanate in the presence of a compound containing an amidine and/or guanidine group and a water-miscible, aprotic-dipolar solvent. This hydrolysis is carried out at from 20.degree. to 210.degree. C. with the reactants being in substantially homogeneous phase. The isocyanate starting material contains aromatically bound NCO groups and has NCO content of from 0.5 to 40 wt. %. The compound containing amidine and/or guanidine groups functions as a catalyst and is used in a quantity of at least 0.001 parts by weight for every 100 parts by weight of isocyanate. The water-miscible solvent is used in a quantity of at least 10 parts by weight for every 100 parts by weight of polyisocyanate. The polyamines thus-produced are particularly useful in the production of polyurethanes.

    摘要翻译： 通过在含有脒和/或胍基和水混溶性非质子偶极溶剂的化合物的存在下水解异氰酸酯，在单阶段方法中制备含芳香结合的伯氨基的多胺。 该水解在20至210℃下进行，反应物基本上是均匀的相。 异氰酸酯原料含有芳香结合的NCO基团，并且NCO含量为0.5〜40wt。 ％。 含有脒和/或胍基的化合物用作催化剂，并且对于每100重量份的异氰酸酯，其用量至少为0.001重量份。 该水混溶性溶剂的使用量相对于每100重量份多异氰酸酯至少为10重量份。 如此生产的聚胺在聚氨酯的生产中特别有用。

    Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes
    8.
    发明授权
    Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes 失效
    具有高乙二醇含量的均相，储存稳定的多元醇组合物及其用于生产聚氨酯的用途

    公开(公告)号：US4554340A

    公开(公告)日：1985-11-19

    申请号：US703059

    申请日：1985-02-19

    申请人： Rudolf Heusch ,  Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz

    发明人： Rudolf Heusch ,  Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz

    IPC分类号： C08G18/32 ,  C08G18/66

    CPC分类号： C08G18/667 ,  C08G18/3206 ,  C08G18/6674 ,  C08G2120/00 ,  C08G2130/00

    摘要： A homogeneous, storage-stable, emulsifier-free polyol mixture having a high mixed OH-number and a high ethylene glycol content comprising 100 parts of a relatively high molecular weight polyalkylene oxide polyol having an OH-number of from 20 to 210, which contains at least 5%, and less than 80%, by weight, of terminal ethylene oxide blocks, from 0.1 to 30 parts of a low molecular weight diol mixture having an OH-- number of 1200 to 1650 in the form of a reaction product of 1 mole of ethylene glycol with 0.1 to 0.5 moles of propylene oxide, optionally, up to 5 parts of di- and/or tri-functional compounds containing reactive hydrogen atoms and having a molecular weight of from 32 to 399, and optionally, other auxiliaries and additives known in the production of polyurethanes. Also, polyurethanes produced using these polyol mixtures.

    摘要翻译： 具有高混合OH-数和高乙二醇含量的均匀，储存稳定，无乳化剂的多元醇混合物，其包含100份具有20至210的OH-数的相对高分子量的聚环氧烷多元醇，其含有 至少5重量％和小于80重量％的末端环氧乙烷嵌段，0.1至30重量份的羟基数为1200至1650的低分子量二醇混合物，其反应产物为1 摩尔的乙二醇与0.1至0.5摩尔的环氧丙烷，任选的至多5份含有反应性氢原子且分子量为32至399的二官能和/或三官能化合物，以及任选的其它助剂和 在聚氨酯生产中已知的添加剂。 此外，使用这些多元醇混合物制备的聚氨酯。

    Process for the preparation of a cellular polyurethane
    9.
    发明授权
    Process for the preparation of a cellular polyurethane 失效
    制备细胞聚氨酯的方法

    公开(公告)号：US4500656A

    公开(公告)日：1985-02-19

    申请号：US594054

    申请日：1984-03-28

    申请人： Werner Rasshofer ,  Ernst-Christoph Prolingheuer

    发明人： Werner Rasshofer ,  Ernst-Christoph Prolingheuer

    IPC分类号： C08G18/32 ,  C08G18/65 ,  C08G18/14

    CPC分类号： C08G18/3296 ,  C08G18/6535 ,  Y10S521/904

    摘要： The present invention relates to a process for the preparation of a cellular polyurethane by the reaction of(A) a polyisocyanate with(B) an isocyanate reactive component containing(1) at least one component having a molecular weight of about 60-2000 and a functionality of 2 to 8, containing isocyanate reactive groups,(2) optionally at least one component having a molecular weight of about 2000 to 12,000 and a functionality of 2 to 8 containing isocyanate reactive groups.(3) about 0.1 to 30 parts, based on 100 parts of (B1)+(B2), of a liquid adduct of an amine and carbon dioxide, and(4) optionally water, blowing agents, foam stabilizers, catalysts and other auxiliary agents and additives,characterized in that the liquid adduct of amine and carbon dioxide is liquid at 20.degree. C., optionally contains water, and is an adduct of carbon dioxide and an amine having at least one amino group and containing at least one primary, secondary or tertiary hydroxyl group, which amine may be solid or liquid at 20.degree. C.

    摘要翻译： 本发明涉及通过（A）多异氰酸酯与（B）异氰酸酯反应性成分的反应制备细胞聚氨酯的方法，所述异氰酸酯反应性成分含有（1）至少一种分子量为约60-2000的成分和 含有异氰酸酯反应性基团的官能度为2至8，（2）任选地至少一种分子量为约2000至12,000且官能度为2至8的含异氰酸酯反应性基团的组分。 （3）约0.1至30份，基于100份（B1）+（B2）的胺和二氧化碳的液体加合物，和（4）任选的水，发泡剂，泡沫稳定剂，催化剂和其它助剂 试剂和添加剂，其特征在于胺和二氧化碳的液体加合物在20℃下为液体，任选地含有水，并且是二氧化碳和具有至少一个氨基并且含有至少一个伯， 二羟基或叔羟基，该胺在20℃下可以是固体或液体。