公开(公告)号：US20070004950A1

公开(公告)日：2007-01-04

申请号：US11171801

申请日：2005-06-30

申请人： Wharton Sinkler ,  Robert Broach ,  Natasha Erdman ,  Thomas Reynolds ,  John Chen ,  Stephen Wilson ,  Paul Barger

发明人： Wharton Sinkler ,  Robert Broach ,  Natasha Erdman ,  Thomas Reynolds ,  John Chen ,  Stephen Wilson ,  Paul Barger

IPC分类号： C07C1/00 ,  B01J27/182 ,  B01J27/00

CPC分类号： B01J29/005 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/62 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.

摘要翻译： 公开并要求保护用于将甲醇转化为轻质烯烃的催化剂以及制备和使用该催化剂的方法。 SAPO-34是根据本发明从其制备中受益的特定催化剂。 种子材料用于制造具有比在催化剂主要部分中发现的EL金属含量更高的催化剂。 分子筛主要具有大致长方体形状的晶体结构，具有较低的断层密度和较轻的烯烃选择性。

公开(公告)号：US07977273B2

公开(公告)日：2011-07-12

申请号：US12431269

申请日：2009-04-28

申请人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

发明人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

IPC分类号： B01J27/182 ,  C01B33/26

CPC分类号： B01J29/005 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/62 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.

公开(公告)号：US07972989B2

公开(公告)日：2011-07-05

申请号：US12431297

申请日：2009-04-28

申请人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

发明人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

IPC分类号： B01J27/182 ,  C01B33/26

CPC分类号： B01J29/005 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/62 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.

公开(公告)号：US07547812B2

公开(公告)日：2009-06-16

申请号：US11171801

申请日：2005-06-30

申请人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

发明人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

IPC分类号： C07C1/00 ,  B01J27/182

CPC分类号： B01J29/005 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/62 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.

摘要翻译： 公开并要求保护用于将甲醇转化为轻质烯烃的催化剂以及制备和使用该催化剂的方法。 SAPO-34是根据本发明从其制备中受益的特定催化剂。 种子材料用于制造具有比在催化剂主要部分中发现的EL金属含量更高的催化剂。 分子筛主要具有大致长方体形状的晶体结构，具有较低的断层密度和较轻的烯烃选择性。

公开(公告)号：US07973208B2

公开(公告)日：2011-07-05

申请号：US12431284

申请日：2009-04-28

申请人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

发明人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

IPC分类号： C07C1/02

CPC分类号： B01J29/005 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/62 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.

摘要翻译： 公开并要求保护用于将甲醇转化为轻质烯烃的催化剂以及制备和使用该催化剂的方法。 SAPO-34是根据本发明从其制备中受益的特定催化剂。 种子材料用于制造具有比在催化剂主要部分中发现的EL金属含量更高的催化剂。 分子筛主要具有大致长方体形状的晶体结构，具有较低的断层密度和较轻的烯烃选择性。

公开(公告)号：US20090209411A1

公开(公告)日：2009-08-20

申请号：US12431269

申请日：2009-04-28

申请人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

发明人： Wharton Sinkler ,  Robert W. Broach ,  Natasha Erdman ,  Thomas M. Reynolds ,  John Q. Chen ,  Stephen T. Wilson ,  Paul T. Barger

IPC分类号： B01J27/182 ,  B01J27/14

CPC分类号： B01J29/005 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/62 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.

摘要翻译： 公开并要求保护用于将甲醇转化为轻质烯烃的催化剂以及制备和使用该催化剂的方法。 SAPO-34是根据本发明从其制备中受益的特定催化剂。 种子材料用于制造具有比在催化剂主要部分中发现的EL金属含量更高的催化剂。 分子筛主要具有大致长方体形状的晶体结构，具有较低的断层密度和较轻的烯烃选择性。

公开(公告)号：US08693626B2

公开(公告)日：2014-04-08

申请号：US13162762

申请日：2011-06-17

申请人： Simon Russell Bare ,  Shelly D Kelly ,  Wharton Sinkler ,  Nan Greenlay

发明人： Simon Russell Bare ,  Shelly D Kelly ,  Wharton Sinkler ,  Nan Greenlay

IPC分类号： G01N23/223 ,  G01T1/36

CPC分类号： G01N23/2206 ,  G01N23/087 ,  G01N23/223 ,  G01N2223/076 ,  G01N2223/203 ,  G01N2223/405 ,  G01N2223/645

摘要： Methods are disclosed utilizing synchrotron X-ray microscopy including x-ray fluorescence and x-ray absorption spectra to probe elemental distribution and elemental speciation within a material, and particularly a solid that may have one or more elements distributed on a solid substrate. Representative materials are relatively homogeneous in composition on the macroscale but relatively heterogeneous on the microscale. The analysis of such materials, particularly on a macroscale at which their heterogeneous nature can be observed, provides valuable insights into the relationships or correlations between localized concentrations of elements and/or their species, and concentrations of other components of the materials. Sample preparation methods, involving the use of a reinforcing agent, which are advantageously used in such methods are also disclosed.

摘要翻译： 公开利用包括X射线荧光和X射线吸收光谱的同步加速器X射线显微镜以探测材料内的元素分布和元素形态的方法，特别是可以具有分布在固体基底上的一种或多种元素的固体。 代表性材料在宏观尺度上的组成相对均匀，但在微尺度上相对异质。 对这些材料的分析，特别是在可观察其异质性的宏观尺度上，分析了元素和/或其物质的局部浓度和材料的其他成分的浓度之间的关系或相关性的有价值的见解。 还公开了有利地用于这些方法中的使用增强剂的样品制备方法。

公开(公告)号：US08304593B2

公开(公告)日：2012-11-06

申请号：US12365536

申请日：2009-02-04

申请人： Hayim Abrevaya ,  Julio C. Marte ,  Stephen T. Wilson ,  Susan C. Koster ,  John E. Bauer ,  Wharton Sinkler ,  Ben A. Wilson ,  Lance L. Jacobsen

发明人： Hayim Abrevaya ,  Julio C. Marte ,  Stephen T. Wilson ,  Susan C. Koster ,  John E. Bauer ,  Wharton Sinkler ,  Ben A. Wilson ,  Lance L. Jacobsen

IPC分类号： C07C5/22

CPC分类号： C07C5/2737 ,  C07C5/2775 ,  C07C15/08

摘要： The present invention comprises a hydrocarbon-conversion process using an improved MgAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve has a specific combination of crystal configuration, being limited in diameter and length, specified crystallinity as measured by an X-Ray Diffraction Index (XRDI), and a narrow range of magnesium content.

摘要翻译： 本发明包括使用改进的MgAPSO-31分子筛的烃转化方法，其表现出芳烃转化率的转化率和选择性的有利组合。 筛子具有晶体构型的特定组合，其直径和长度受到限制，通过X射线衍射指数（XRDI）测量的特定结晶度和镁含量的窄范围。

公开(公告)号：US06752980B1

公开(公告)日：2004-06-22

申请号：US10395639

申请日：2003-03-21

申请人： Jaime G. Moscoso ,  Wharton Sinkler ,  Gregory J. Lewis ,  Deng-Yang Jan ,  Susan C. Koster

发明人： Jaime G. Moscoso ,  Wharton Sinkler ,  Gregory J. Lewis ,  Deng-Yang Jan ,  Susan C. Koster

IPC分类号： C01B3948

CPC分类号： C10G11/05 ,  B01J29/50 ,  B01J29/70 ,  B01J2229/16 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/06 ,  C01B39/065 ,  C01B39/48

摘要： An aluminosilicate zeolite and substituted version designated UZM-16 have been synthesized. These zeolites are prepared using benzyltrimethyl-ammonium (BzTMA) cation or a combination of BzTMA and at least one other quaternary ammonium cation These zeolites have a structure that is related to offretite, but shows structurally different and distinct features. The UZM-16 zeolites can be dealuminated to form UZM-16HS zeolites which have different acidity, porosity and ion-exchange properties. Both UZM-16 and UZM-16HS are useful in various hydrocarbon conversion processes.

摘要翻译： 已经合成了一种硅铝酸盐沸石，并且被认定为UZM-16的取代物。 这些沸石使用苄基三甲基铵（BzTMA）阳离子或BzTMA和至少一种其他季铵阳离子的组合制备。这些沸石具有与白云母相关的结构，但显示出结构上不同和明显的特征。 UZM-16沸石可以脱铝以形成具有不同酸度，孔隙率和离子交换性能的UZM-16HS沸石。 UZM-16和UZM-16HS都可用于各种烃转化过程。

公开(公告)号：US20100152511A1

公开(公告)日：2010-06-17

申请号：US12365536

申请日：2009-02-04

申请人： Hayim Abrevaya ,  Julio C. Marte ,  Stephen T. Wilson ,  Susan C. Koster ,  John E. Bauer ,  Wharton Sinkler ,  Ben A. Wilson ,  Lance L. Jacobsen

发明人： Hayim Abrevaya ,  Julio C. Marte ,  Stephen T. Wilson ,  Susan C. Koster ,  John E. Bauer ,  Wharton Sinkler ,  Ben A. Wilson ,  Lance L. Jacobsen

IPC分类号： C07C5/22

CPC分类号： C07C5/2737 ,  C07C5/2775 ,  C07C15/08

摘要： The present invention comprises a hydrocarbon-conversion process using an improved MgAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve has a specific combination of crystal configuration, being limited in diameter and length, specified crystallinity as measured by an X-Ray Diffraction Index (XRDI), and a narrow range of magnesium content.

摘要翻译： 本发明包括使用改进的MgAPSO-31分子筛的烃转化方法，其表现出芳烃转化率的转化率和选择性的有利组合。 筛子具有晶体构型的特定组合，其直径和长度受到限制，通过X射线衍射指数（XRDI）测量的特定结晶度和镁含量的窄范围。