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公开(公告)号：US06245221B1
公开(公告)日：2001-06-12
申请号：US09326826
申请日：1999-06-07
申请人： William C. Baird, Jr. , Gary B. McVicker , James J. Schorfheide , Darryl P. Klein , Sylvain S. Hantzer , Michel Daage , Michele S. Touvelle , Edward S. Ellis , David E. W. Vaughan , Jingguang Chen
发明人： William C. Baird, Jr. , Gary B. McVicker , James J. Schorfheide , Darryl P. Klein , Sylvain S. Hantzer , Michel Daage , Michele S. Touvelle , Edward S. Ellis , David E. W. Vaughan , Jingguang Chen
IPC分类号： C10G4500
CPC分类号： C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh, and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 在相对温和的条件下，含有贵金属的催化剂存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）的方法。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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公开(公告)号：US5928498A
公开(公告)日：1999-07-27
申请号：US917070
申请日：1997-08-22
申请人： Gary B. McVicker , James J. Schorfheide , William C. Baird, Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E. W. Vaughan , Jingguang G. Chen , Sylvain S. Hantzer
发明人： Gary B. McVicker , James J. Schorfheide , William C. Baird, Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E. W. Vaughan , Jingguang G. Chen , Sylvain S. Hantzer
CPC分类号： C10G25/003 , C10G45/10 , C10G45/62 , C10G65/04 , C10G65/043 , C10G65/08
摘要： A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.
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公开(公告)号：US6103106A
公开(公告)日：2000-08-15
申请号：US326843
申请日：1999-06-07
申请人： Gary B. McVicker , James J. Schorfheide , William C. Baird Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E.W. Vaughan , Jingguang Chen , Sylvain S. Hantzer
发明人： Gary B. McVicker , James J. Schorfheide , William C. Baird Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E.W. Vaughan , Jingguang Chen , Sylvain S. Hantzer
CPC分类号： C10G67/06 , C10G45/10 , C10G65/04 , C10G65/043 , C10G65/08
摘要： A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.
摘要翻译： 多重稠环杂环有机硫化合物的加氢脱硫（HDS）和存在于石油和石油化工流中的环化合物的开环方法。 该方法在氢气，一种或多种贵金属催化剂和硫化氢吸附剂材料的存在下进行。
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4.发明授权公开(公告)号：US06221240B1
公开(公告)日：2001-04-24
申请号：US09326827
申请日：1999-06-07
申请人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
发明人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
IPC分类号： C10G4500
CPC分类号： C10G25/003 , C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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5.发明授权
公开(公告)号：US5925239A
公开(公告)日：1999-07-20
申请号：US918639
申请日：1997-08-22
申请人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang G. Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
发明人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang G. Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
CPC分类号： C10G25/003 , C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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公开(公告)号：US5935420A
公开(公告)日：1999-08-10
申请号：US918641
申请日：1997-08-22
申请人： William C. Baird, Jr. , Gary B. McVicker , James J. Schorfheide , Darryl P. Klein , Sylvain Hantzer , Michel Daage , Michele S. Touvelle , Edward S. Ellis , David E.W. Vaughan , Jingguang G. Chen
发明人： William C. Baird, Jr. , Gary B. McVicker , James J. Schorfheide , Darryl P. Klein , Sylvain Hantzer , Michel Daage , Michele S. Touvelle , Edward S. Ellis , David E.W. Vaughan , Jingguang G. Chen
CPC分类号： C10G25/003 , C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh, and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 在相对温和的条件下，含有贵金属的催化剂存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）的方法。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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公开(公告)号：US06723230B1
公开(公告)日：2004-04-20
申请号：US09620796
申请日：2000-07-21
申请人： Jingguang G. Chen , Leo D. Brown , William C. Baird, Jr. , Gary B. McVicker , Edward S. Ellis , Michele S. Touvelle , Darryl P. Klein , David E. W. Vaughan
发明人： Jingguang G. Chen , Leo D. Brown , William C. Baird, Jr. , Gary B. McVicker , Edward S. Ellis , Michele S. Touvelle , Darryl P. Klein , David E. W. Vaughan
IPC分类号： C10G2500
CPC分类号： C10G45/10 , B01J20/0229 , B01J20/06 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3466 , B01J23/89 , B01J23/94 , B01J38/06 , B01J2220/56 , C10G25/003 , C10G45/04 , C10G45/62 , C10G65/043
摘要： A process to regenerate iron-based hydrogen sulfide sorbents using steam. The steam is preferably mixed with hydrogen-containing gas and/or an inert gas, such as nitrogen. In a preferred embodiment, the sorbent is first exposed to the steam and then exposed to a hydrogen-containing gas at regeneration conditions.
摘要翻译： 使用蒸汽再生铁基硫化氢吸附剂的方法。 蒸汽优选与含氢气体和/或惰性气体如氮气混合。 在优选的实施方案中，首先将吸附剂暴露于蒸汽，然后在再生条件下暴露于含氢气体。
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公开(公告)号：US06649043B1
公开(公告)日：2003-11-18
申请号：US09620865
申请日：2000-07-21
申请人： Jingguang G. Chen , Leo D. Brown , William C. Baird, Jr. , Gary B. McVicker , Edward S. Ellis , Michele S. Touvelle , Darryl P. Klein , David E. W. Vaughan
发明人： Jingguang G. Chen , Leo D. Brown , William C. Baird, Jr. , Gary B. McVicker , Edward S. Ellis , Michele S. Touvelle , Darryl P. Klein , David E. W. Vaughan
IPC分类号： C10G4500
CPC分类号： C10G45/10 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J2220/56 , C07C7/163 , C10G25/003 , C10G45/04 , C10G45/62 , C10G65/043
摘要： A process to regenerate metal oxide desulfurization sorbents using an oxidizing and reducing atmosphere. The sorbents may be mono- or multi-metallic in nature, and preferably comprise Cu, Ni and/or Co. If desired, secondary metals may be incorporated to increase regeneration efficiency and/or capacity. Other additives may be used to suppress hydrocarbon cracking. A sorbent containing Zn may be combined with an Fe, Co, Ni, Mo, or W catalyst or a noble metal catalyst and combinations thereof.
摘要翻译： 使用氧化还原气氛再生金属氧化物脱硫吸附剂的方法。 吸附剂本质上可以是单金属或多金属的，并且优选包含Cu，Ni和/或Co。如果需要，可以引入二次金属以提高再生效率和/或容量。 可以使用其它添加剂来抑制烃裂解。 含有Zn的吸附剂可以与Fe，Co，Ni，Mo或W催化剂或贵金属催化剂及其组合组合。
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公开(公告)号：US5763731A
公开(公告)日：1998-06-09
申请号：US631472
申请日：1996-04-12
申请人： Gary B. McVicker , Michele S. Touvelle , Carl W. Hudson , David E. W. Vaughan , Michel Daage , Sylvain Hantzer , Darryl P. Klein , Edward S. Ellis , Bruce R. Cook , Owen C. Feeley , Joseph E. Baumgartner
发明人： Gary B. McVicker , Michele S. Touvelle , Carl W. Hudson , David E. W. Vaughan , Michel Daage , Sylvain Hantzer , Darryl P. Klein , Edward S. Ellis , Bruce R. Cook , Owen C. Feeley , Joseph E. Baumgartner
CPC分类号： C07C5/31 , C07C2523/46 , Y10S585/94
摘要： Naphthenic rings in naphthenic ring-containing compounds in a feedstream are selectively opened wherein at least about 50 wt. % of the ring compounds in the feedstream are characterized as containing at least one C.sub.6 ring having at least one substituent containing 3 or more carbon atoms. The naphthenic rings are opened without significant dealkylation of any pendant substituents on the ring. The feedstream, containing such compounds, is contacted with a supported catalyst containing a metal selected from Ir, Ru, or a mixture thereof, which catalyst when reacted with a feed comprised of 20 wt. % n-butylcyclohexane in heptane diluent will result in: a) at least a 10% yield of C.sub.10 paraffin yield/%C.sub.10 ring disappearance.
摘要翻译： 选择性地打开进料流中的环烷环化合物中的环状环，其中至少约50wt。 进料流中的环化合物的％表征为含有至少一个具有至少一个含有3个或更多个碳原子的取代基的C 6环。 打开环烷环，而环上没有任何侧挂取代基的显着脱烷基化。 将含有这些化合物的原料流与含有选自Ir，Ru或其混合物的金属的负载型催化剂接触，该催化剂与20重量％ ％庚烷稀释剂中的正丁基环己烷将导致：a）至少10％的C10石蜡产率/％C10环消失。
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10.发明授权Ring opening with group VIII metal catalysts supported on modified substrate 有权开环与第VIII族金属催化剂负载在改性底物上公开(公告)号：US06586650B2
公开(公告)日：2003-07-01
申请号：US09897191
申请日：2001-07-02
申请人： William C. Baird, Jr. , Darryl P. Klein , Michele S. Touvelle , Jingguang G. Chen , Gary B. McVicker
发明人： William C. Baird, Jr. , Darryl P. Klein , Michele S. Touvelle , Jingguang G. Chen , Gary B. McVicker
IPC分类号： C07C513
CPC分类号： B01J23/58 , C07C5/13 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/12 , C07C2523/26 , C07C2523/42 , C07C2523/46
摘要： A process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst comprising at least one Group VIII metal selected from Ir, Pt, Rh, and Ru, wherein these metals are supported on an alkali metal or alkaline-earth metal modified support in an amount effective for opening a naphthene ring-containing compound at a tertiary carbon site.
摘要翻译： 一种用于开环环烷环的环烷环化合物的方法，以及可用于该方法的催化剂。 环烷烃开环催化剂是包含至少一种选自Ir，Pt，Rh和Ru的Ⅷ族金属的催化剂，其中这些金属以有效打开环烷烃的量负载在碱金属或碱土金属改性的载体上 含碳化合物在叔碳位点。
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