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公开(公告)号：US4582658A
公开(公告)日：1986-04-15
申请号：US633737
申请日：1984-07-23
IPC分类号： C08G18/00 , B29C44/04 , B29C44/38 , C08G18/32 , C08G18/42 , C08G18/48 , C08J9/00 , C08J9/02 , C08J9/34 , C08L75/04 , B29C67/22
CPC分类号： C08J9/0061 , B29C44/04 , B29C44/445 , C08J9/0014 , B29K2075/00 , C08J2375/04 , C08J2491/00 , Y10S264/83
摘要： A first reaction mixture, prepared from (a) isocyanates with isocyanate contents of from 5 to 50% and (b) compounds with molecular weights of from 32 to 10,000 which contain at least two isocyanate-reactive hydrogen atoms, in an equivalent ratio of component "a" to component "b" of 0.8:1 to 5:1, from 0.1 to 20% of a blowing agent and, optionally, other known additives, is introduced into the rigid cavity of a closed mold. After this mixture has become resistant to permeation, but is still compressible, a second reaction mixture, either the same or different from the first reaction mixture, prepared from (c) isocyanates having isocyanate contents of from 5 to 50% and (d) compounds with molecular weights of from 32 to 10,000 which contain at least two isocyanate-reactive hydrogen atoms, in an equivalent ratio of component "c" to component "d" of from 0.8:1 to 5:1, specific internal mold release agents and optionally blowing agents and other additives, is introduced into the mold, such that it surrounds the first mixture and compresses it. A third, optional, reaction mixture, the same as or different from the second mixture, may also be employed in a manner similar to the introduction of the second mixture. The final composite plastic part releases smoothly from the mold.
摘要翻译： 由（a）异氰酸酯含量为5至50％的异氰酸酯制备的第一反应混合物和（b）分子量为32至10,000的含有至少两个异氰酸酯反应性氢原子的化合物，其组分 0.8至1：5的“a”组分“b”，0.1至20％的发泡剂和任选的其它已知添加剂被引入到封闭模具的刚性腔中。 在该混合物变得耐渗透但仍然是可压缩之后，由（c）异氰酸酯含量为5至50％的异氰酸酯和（d）化合物制备的与第一反应混合物相同或不同的第二反应混合物 分子量为32至10,000，其含有至少两个异氰酸酯反应性氢原子，组分“c”与组分“d”的当量比为0.8:1至5:1，特定内部脱模剂和任选地 发泡剂和其它添加剂引入模具中，使得其包围第一混合物并将其压缩。 可以以与引入第二混合物相似的方式使用与第二混合物相同或不同的第三种任选的反应混合物。 最终的复合塑料部件从模具平滑地释放。
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2.发明授权
公开(公告)号：US4539166A
公开(公告)日：1985-09-03
申请号：US491692
申请日：1983-05-05
申请人： Adolf Richartz , Wolfgang Reichmann , Ulrich Knipp
发明人： Adolf Richartz , Wolfgang Reichmann , Ulrich Knipp
IPC分类号： B32B5/18 , B29C44/04 , C08G18/00 , C08G18/16 , C08G18/32 , C08G18/42 , C08G18/48 , C08G18/62 , C08J9/00 , C08J9/02 , C08J9/34 , C08L75/04 , B29D27/04
CPC分类号： C08J9/0061 , B29C44/04 , B29C44/445 , B29K2075/00 , C08J2375/04 , C08J2483/00 , Y10S264/83
摘要： A first reaction mixture, prepared from (a) aromatic isocyanates with isocyanate contents of from 5 to 50%, and (b) compounds with molecular weights of from 32 to 10,000 which contain at least two isocyanate-reactive hydrogen atoms, in an equivalent ratio of component "a" to component "b" of 0.8:1 to 5:1, from 0.1 to 20% of a blowing agent and, optionally, other known additives, is introduced into a closed mold with a rigid cavity. After this mixture has become resistant to permeation, but is still compressible, a second reaction mixture, prepared from (c) aliphatic and/or cycloaliphatic polyisocyanates having isocyanate contents of from 5 to 50% and (d) compounds with molecular weights of from 32 to 10,000 which contain at least two isocyanate-reactive hydrogen atoms, in an equivalent ratio of component "c" to component "d" of from 0.8:1 to 5:1, an internal mold release agent and optionally blowing agents and other additives, is introduced into the mold, such that the second mixture surrounds the first mixture and compresses it. A third, optional, reaction mixture, the same as or different from the second mixture, may also be employed in a manner similar to the introduction of the second mixture. The final composite plastic part releases smoothly from the mold and evidences good lightfast and colorfast properties.
摘要翻译： 由（a）异氰酸酯含量为5至50％的芳族异氰酸酯制备的第一反应混合物和（b）分子量为32至10,000的含有至少两个异氰酸酯反应性氢原子的化合物，其当量比 的组分“a”与组分“b”的比例为0.8:1至5:1，将0.1至20％的发泡剂和任选的其它已知添加剂引入具有刚性腔的封闭模具中。 在该混合物已经变得耐渗透但仍然是可压缩的情况下，由（c）异氰酸酯含量为5至50％的脂族和/或脂环族多异氰酸酯制备的第二反应混合物和（d）分子量为32的化合物 至10,000，其含有至少两个异氰酸酯反应性氢原子，组分“c”与组分“d”的当量比为0.8:1至5:1，内部脱模剂和任选的发泡剂和其它添加剂， 被引入模具中，使得第二混合物围绕第一混合物并将其压缩。 可以以与引入第二混合物相似的方式使用与第二混合物相同或不同的第三种任选的反应混合物。 最终的复合塑料部件从模具中平滑地释放，并且证明具有良好的耐光性和耐色性。
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3.发明授权Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes 失效具有高乙二醇含量的均相，储存稳定的多元醇组合物及其用于生产聚氨酯的用途
公开(公告)号：US4554340A
公开(公告)日：1985-11-19
申请号：US703059
申请日：1985-02-19
CPC分类号： C08G18/667 , C08G18/3206 , C08G18/6674 , C08G2120/00 , C08G2130/00
摘要： A homogeneous, storage-stable, emulsifier-free polyol mixture having a high mixed OH-number and a high ethylene glycol content comprising 100 parts of a relatively high molecular weight polyalkylene oxide polyol having an OH-number of from 20 to 210, which contains at least 5%, and less than 80%, by weight, of terminal ethylene oxide blocks, from 0.1 to 30 parts of a low molecular weight diol mixture having an OH-- number of 1200 to 1650 in the form of a reaction product of 1 mole of ethylene glycol with 0.1 to 0.5 moles of propylene oxide, optionally, up to 5 parts of di- and/or tri-functional compounds containing reactive hydrogen atoms and having a molecular weight of from 32 to 399, and optionally, other auxiliaries and additives known in the production of polyurethanes. Also, polyurethanes produced using these polyol mixtures.
摘要翻译： 具有高混合OH-数和高乙二醇含量的均匀，储存稳定，无乳化剂的多元醇混合物，其包含100份具有20至210的OH-数的相对高分子量的聚环氧烷多元醇，其含有 至少5重量％和小于80重量％的末端环氧乙烷嵌段，0.1至30重量份的羟基数为1200至1650的低分子量二醇混合物，其反应产物为1 摩尔的乙二醇与0.1至0.5摩尔的环氧丙烷，任选的至多5份含有反应性氢原子且分子量为32至399的二官能和/或三官能化合物，以及任选的其它助剂和 在聚氨酯生产中已知的添加剂。 此外，使用这些多元醇混合物制备的聚氨酯。
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4.发明授权Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes 失效具有高乙二醇含量的均相，储存稳定的多元醇组合物及其用于生产聚氨酯的用途
公开(公告)号：US4518521A
公开(公告)日：1985-05-21
申请号：US497626
申请日：1983-05-24
CPC分类号： C08G18/667 , C08G18/3206 , C08G18/6674 , C08G2120/00 , C08G2130/00
摘要： A homogeneous, storage-stable, emulsifier-free polyol mixture having a high mixed OH-number and a high ethylene glycol content comprising 100 parts of a relatively high molecular weight polyalkylene oxide polyol having an OH-number of from 20 to 210, which contains at least 5%, and less than 80%, by weight, of terminal ethylene oxide blocks, from 0.1 to 30 parts of a low molecular weight diol mixture having an OH-number of 1200 to 1650 in the form of a reaction product of 1 mole of ethylene glycol with 0.1 to 0.5 moles of propylene oxide, optionally, up to 5 parts of di- and/or tri-functional compounds containing reactive hydrogen atoms and having a molecular weight of from 32 to 399, and optionally, other auxiliaries and additives known in the production of polyurethanes. Also, polyurethanes produced using these polyol mixtures.
摘要翻译： 具有高混合OH-数和高乙二醇含量的均匀，储存稳定，无乳化剂的多元醇混合物，其包含100份具有20至210的OH-数的相对高分子量的聚环氧烷多元醇，其含有 至少5重量％和小于80重量％的末端环氧乙烷嵌段，0.1至30重量份的羟基数为1200至1650的低分子量二醇混合物，其反应产物为1 摩尔的乙二醇与0.1至0.5摩尔的环氧丙烷，任选的至多5份含有反应性氢原子且分子量为32至399的二官能和/或三官能化合物，以及任选的其它助剂和 在聚氨酯生产中已知的添加剂。 此外，使用这些多元醇混合物制备的聚氨酯。
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5.发明授权Single-phase, storage-stable polyol compositions containing salts and the use thereof in the production of polyurethanes 失效含有盐的单相，储存稳定的多元醇组合物及其在生产聚氨酯中的用途
公开(公告)号：US4436841A
公开(公告)日：1984-03-13
申请号：US497640
申请日：1983-05-24
CPC分类号： C08G18/6674 , C08K5/053 , C08G2120/00 , C08G2130/00 , Y10S521/914
摘要： A single-phase, storage-stable, emulsifier-free polyol mixture comprising 100 parts of a relatively high molecular weight polyoxyalkylene polyol of OH number from 20 to 120, which has at least 5% and less than 80% by weight, of terminal oxyethylene blocks; from 1 to 100 parts of a low molecular weight diol mixture which is a reaction product of ethylene glycol, butane diol-1,4, or a mixture of ethylene glycol and butane diol-1,4, with from 0.05 to 0.50 mols of alkyl oxiranes; from 0.1 to 5 parts of solubilizing additives comprising one or more salts, the cations of which are from Groups I, II and III of the Periodic Table, ammonium or mono- to tetra-alkyl ammonium ions, and the anions of which are produced by removing at least one proton from an acid having a K.sub.s value of at least 10.sup.-7 ; and, optionally, other compounds having isocyanate-reactive hydrogen atoms and other auxiliaries and additives for polyurethane production. Also polyurethanes produced using these polyol mixtures.
摘要翻译： 一种单相，储存稳定，不含乳化剂的多元醇混合物，其包含100份具有20-120的OH数量的相对高分子量的聚氧化烯多元醇，其具有至少5重量％且小于80重量％的末端氧化乙烯 块 1至100份低分子量二醇混合物，其是乙二醇，丁二醇-1,4-或乙二醇和丁二醇-1,4-的混合物与0.05至0.50摩尔烷基的反应产物 环氧乙烷 0.1至5份包含一种或多种盐的增溶添加剂，其阳离子来自周期表第I，II和III族，铵或一至四烷基铵离子，其阴离子由 从Ks值至少为10-7的酸中除去至少一个质子; 和任选的具有异氰酸酯反应性氢原子的其它化合物和用于聚氨酯生产的其它助剂和添加剂。 还使用这些多元醇混合物制备聚氨酯。
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公开(公告)号：US4195031A
公开(公告)日：1980-03-25
申请号：US965648
申请日：1978-12-20
申请人： Wolfgang Reichmann , Klaus Konig , Johannes Koster
发明人： Wolfgang Reichmann , Klaus Konig , Johannes Koster
IPC分类号： C07C265/02 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/04 , C07C265/04 , C07C118/00
CPC分类号： C07C263/04
摘要： The instant invention relates to an improved process for the continuous production of an aliphatic monoisocyanate from the corresponding N-alkyl carbamic acid aryl ester. More particularly, the invention is directed to a process for the continuous production of monoisocyanates corresponding to the formulaR--NCOin whichR represents an aliphatic hydrocarbon radical containing 1 to 3 carbon atoms comprising thermally decomposing the corresponding N-alkylcarbamic acid aryl esters corresponding to the formulaR--NH--CO--O--R'in whichR has the meaning above andR' represents a radical of the type obtained by removing the hydroxyl group from a monophenol having a boiling point below 250.degree. C. at normal pressure, and separating the decomposition products by decomposition, further characterized in that(a) a solution of the N-alkylcarbamic acid aryl ester in an organic solvent, which solvent is inert under the reaction conditions and has a boiling point lying at least 20.degree. C. above the boiling point of the monoisocyanate to be formed, is heated to a temperature of from 160.degree. C. to 250.degree. C. at normal pressure or at slightly reduced pressure within the range of 200 to 1013 mbar, thereby resulting in the decomposition of the ester into the corresponding monoisocyanate and the corresponding phenol, as well as the evaporation of the solvent and the decomposition products, and(b) the vapors formed are fed into a distillation column with the monoisocyanate obtained at the head of the column and with the phenol and at least a major portion of the solvent obtained from a side stream or from several side streams.
摘要翻译： 本发明涉及从相应的N-烷基氨基甲酸芳基酯连续制备脂族单异氰酸酯的改进方法。 更具体地说，本发明涉及连续制备相应于式R-NCO的单异氰酸酯的方法，其中R代表含有1至3个碳原子的脂族烃基，包括热分解相应的N-烷基氨基甲酸芳基酯 式R-NH-CO-OR'其中R具有上述含义，R'表示通过在常压下从沸点低于250℃的单酚除去羟基得到的类型的基团，并且分离 分解产物，其特征还在于（a）N-烷基氨基甲酸芳基酯在有机溶剂中的溶液，该溶剂在反应条件下是惰性的，并且沸点至少在20℃以上 要形成的单异氰酸酯的沸点在常压或稍微减压的范围内加热到160℃至250℃的温度 e为200至1013毫巴，从而导致酯分解成相应的单异氰酸酯和相应的苯酚，以及溶剂和分解产物的蒸发，和（b）所形成的蒸气进料到蒸馏塔 与在柱的头部和苯酚获得的单异氰酸酯以及从侧流或从多个侧流获得的至少大部分溶剂。
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公开(公告)号：US4746681A
公开(公告)日：1988-05-24
申请号：US36834
申请日：1987-04-10
CPC分类号： C08G18/6685 , C08G18/10 , C08G18/5027 , C08G18/5048 , C08G2101/0008 , C08G2101/0033 , C08G2101/0066 , C08G2120/00 , Y10S264/14
摘要： Molded polyurea foam parts having densities of from 200 to 600 kg/m.sup.3 and a compact skin are made by reacting a polyisocyanate component with a polyamine component in a closed mold at an isocyanate index of from 70 to 130. The polyamine component generally includes (1) an aminopolyether having a molecular weight of from 1800 to 12,000 and 2 to 3 isocyanate reactive groups of which at least 90% are aromatically bound primary and/or secondary amino groups, (2) an aromatic diamine, (3) a foaming agent and optionally (4) known auxiliaries and additives. The polyisocyanate component includes any aromatic di- and/or poly-isocyanate. Parts produced by this process have excellent mechanical properties and a well-defined solid skin.
摘要翻译： 通过使多异氰酸酯组分与多胺组分在封闭模具中以70至130的异氰酸酯指数反应制备密度为200至600kg / m 3的模制聚脲泡沫部件和紧密表皮。多胺组分通常包括（1 ）分子量为1800〜12,000的氨基聚醚和2〜3个异氰酸酯反应性基团，其中至少90％是芳族结合的伯和/或仲氨基，（2）芳族二胺，（3）发泡剂和 （4）已知的助剂和添加剂。 多异氰酸酯组分包括任何芳族二 - 和/或多异氰酸酯。 通过该方法生产的部件具有优异的机械性能和明确的固体皮肤。
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8.发明授权Process for the manufacture of elastic polyurethane foams capable of being flame laminated and high frequency welded 失效用于制造能够被火焰层压和高频焊接的弹性聚氨酯泡沫体的方法
公开(公告)号：US4306037A
公开(公告)日：1981-12-15
申请号：US183538
申请日：1980-09-02
CPC分类号： C08G18/3221 , C08G18/6674 , C08G2101/0008 , C08G2101/0033 , C08G2101/005 , C08G2101/0083
摘要： The instant invention is directed to a process for the production of elastic polyurethane foams capable of being flame laminated and high frequency welded, comprising reacting(a) polyisocyanates with(b) polyethers having a molecular weight of from 400 to 10,000 and having at least two hydroxyl groups and(c) hydroxy-pivalic acid neopentylglycol ester of the formula: ##STR1## used in a quantity of from 1 to 20% by weight, based on the hydroxyl polyether, in the presence of a blowing agent.The instant invention is also directed to the polyurethane foams prepared thereby.
摘要翻译： 本发明涉及生产能够进行火焰层压和高频焊接的弹性聚氨酯泡沫体的方法，包括使（a）多异氰酸酯与（b）分子量为400至10,000的聚醚并且具有至少两个 羟基和（c）下式的羟基 - 新戊酸新戊二醇酯，其用量为1至20重量％，基于羟基聚醚，在发泡剂存在下。 本发明还涉及由其制备的聚氨酯泡沫。
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公开(公告)号：US4220749A
公开(公告)日：1980-09-02
申请号：US917765
申请日：1978-06-21
IPC分类号： C08G18/00 , C07C67/00 , C07C239/00 , C07C241/00 , C07C265/14 , C07C273/18 , C07C275/62 , C08G18/78 , C08G18/80 , C07C27/24 , C08G18/72
CPC分类号： C08G18/808 , C07C273/1827 , C07C275/62 , C08G18/7818
摘要： This invention relates to a new process for the production of organic polyisocyanates containing polyuret groups, to polyisocyanates obtainable by this process and to the use of the products obtained by the process as an isocyanate component in the production of polyurethane plastics.
摘要翻译： 本发明涉及生产含有聚脲基团的有机聚异氰酸酯的新方法，可通过该方法获得的多异氰酸酯以及通过该方法获得的产品作为异氰酸酯组分用于生产聚氨酯塑料中的用途。
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10.发明授权Process for the production of microcellular moldings from diisocyanate and compounds containing groups obtained by reacting amino groups with carbon dioxide 失效用于从二异氰酸酯生产微孔成型体的方法和含氨基与二氧化碳反应得到的化合物
公开(公告)号：US4499038A
公开(公告)日：1985-02-12
申请号：US549040
申请日：1983-11-07
申请人： Walter Schafer , Hans-Joachim Meiners , Klaus Seel , Wolfgang Reichmann , Kuno Wagner , Kurt Findeisen
发明人： Walter Schafer , Hans-Joachim Meiners , Klaus Seel , Wolfgang Reichmann , Kuno Wagner , Kurt Findeisen
IPC分类号： C08G18/00 , B29B15/00 , B29C43/00 , B29C45/00 , C08G18/32 , C08G18/50 , C08G18/66 , C08G101/00 , C08J9/02 , C08G18/14
CPC分类号： C08G18/5048 , C08G18/3265 , C08G18/503 , C08G18/667 , C08G2120/00
摘要： The present invention is directed to a process for the production of polyurea-based microcellular moldings comprising reacting(a) at least one diisocyanate or polyisocyanate containing only aromatically bound isocyanate groups,(b) at least one compound containing at least two isocyanate-reactive groups, and(c) optionally the auxiliaries and additives known in polyurethane chemistry, in closed molds, components (a)-(c) being processed as a one-shot system by reaction injection molding, characterized in that component (b) comprises at least one polyether compound (b1) optionally in admixture with other isocyanate-reactive compounds and containing at least 3 aliphatically bonded ether groups and n-aliphatically bonded isocyanate-reactive groups, n standing for an integer or, statistically a fraction of from 2-4(i) at least (100:n) % of the isocyanate-reactive groups present in component (b1) being aliphatically bonded primary and/or secondary amino groups,(ii) at least 10 equivalent % of said amino groups being present in the form of ammonium carbamate groups having a functionality of two in the isocyanate addition reaction, of the type obtained by reacting aliphatically bonded, primary or secondary amino groups with carbon dioxide,(iii) the unmodified compounds containing at least 3 ether groups having a molecular weight of from 200 to 10,000 and(iv) at least 0,2 equivalent % of all isocyanate-reactive groups of the total component (b) being ammonium carbamate groups.The present invention also relates to said compounds (b) optionally in admixture with the auxiliaries and additives known in polyurethane chemistry.
摘要翻译： 本发明涉及一种制备聚脲基微孔成型体的方法，其包括使（a）至少一种仅含芳香结合的异氰酸酯基团的二异氰酸酯或多异氰酸酯，（b）至少一种含有至少两个异氰酸酯反应性基团的化合物 ，和（c）任选地在聚氨酯化学中已知的助剂和添加剂，在封闭模具中，组分（a） - （c）通过反应注射成型作为一步法处理，其特征在于组分（b）至少包含 一种聚醚化合物（b1）任选地与其它异氰酸酯反应性化合物混合并且含有至少3个脂族键合的醚基团和n-脂肪键合的异氰酸酯反应性基团，n代表整数，或统计学上为2-4 i）组分（b1）中存在的至少（100：n）％的异氰酸酯 - 反应性基团是脂族键合的伯和/或仲氨基，（ii）至少10当量 所述氨基的％以异氰酸酯加成反应中官能度为2的氨基甲酸铵基团的形式存在，其通过脂族键合，伯或仲氨基与二氧化碳反应而获得的类型，（iii）未修饰的化合物含有 至少3个分子量为200至10,000的醚基和（iv）总组分（b）的所有异氰酸酯反应性基团的至少0.2当量％为氨基甲酸铵基团。 本发明还涉及所述化合物（b），任选地与聚氨酯化学中已知的助剂和添加剂混合。
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