公开(公告)号：US10266541B2

公开(公告)日：2019-04-23

申请号：US15817045

申请日：2017-11-17

Applicant: XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

Inventor： Jianming Yang ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Jun Yuan ,  Wei Wang ,  Yani Li ,  Weiqiang Wang ,  Jian Lu

IPC: C07D487/08 ,  B01J27/18 ,  C07D203/02 ,  C07D295/023 ,  B01J21/02 ,  B01J21/06 ,  B01J19/00 ,  B01J31/02

Abstract: Disclosed are a joint production method and device for aziridine, piperazine and triethylenediamine. The method comprises: reaction 1, preparing piperazine and triethylenediamine by taking ethanol amine as a raw material under the existence of a cyclamine catalyst; reaction 2, preparing aziridine by taking the ethanol amine as the raw material under the existence of a catalyst B; and taking heat released in the reaction 1 as a heat source of heat absorption in the reaction 2. The device comprises a reactor 1 for carrying out the reaction 1 and the heat exchange between reaction materials of the reaction 1 and the raw material of the reaction 2 and a reactor 2 for carrying out the reaction 2. According to the present invention, the same raw material, namely the ethanol amine is adopted, aziridine, piperazine and triethylenediamine can be produced in a joint manner, the heat released in the reaction 1 is used for preheating materials in the reaction 2, so that heat coupling between the reactions is implemented, energy conservation is facilitated and competitiveness of the device is improved.

公开(公告)号：US09920008B2

公开(公告)日：2018-03-20

申请号：US15105499

申请日：2014-09-05

Applicant: XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

Inventor： Jianming Yang ,  Jian Lu ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Yani Li ,  Fengwei Zhao ,  Weiqiang Wang ,  Wei Wang

IPC: C07D203/08 ,  B01J27/182 ,  B01J37/04 ,  B01J37/08 ,  B01J37/26 ,  B01J37/28 ,  B01J21/06 ,  B01J21/08 ,  B01J23/78 ,  B01J37/00 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC classification number: C07D203/08 ,  B01J21/063 ,  B01J21/08 ,  B01J23/78 ,  B01J27/182 ,  B01J27/1853 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0217 ,  B01J37/04 ,  B01J37/082 ,  B01J37/088 ,  B01J37/26 ,  B01J37/28 ,  B01J2523/00 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/842

Abstract: The present invention relates to a catalyst for synthesizing ethylenimine as well as a preparation method and application thereof. The related catalyst comprises a carrier and metal ions loaded on the carrier; the carrier is a composite oxide comprising titanium, silicon and phosphorus elements; the metal ions are magnesium ions, iron ions and cesium ions; the molar ratio of the magnesium ions to the iron ions to the cesium ions is (1-10):1:0.1; the mass of all metal ions is 0.5-10 percent of that of the carrier. In the related preparation method, a catalyst precursor is roasted at the temperature of 350-650° C., so that the catalyst is obtained; the catalyst precursor is the mixture of the carrier, soluble salt of magnesium, soluble salt of iron and soluble salt of cesium. The present invention also provides the application of the catalyst to synthesis of the ethylenimine by using amino alcohol as the raw material. Compared with a common catalyst which has the requirement on the temperature of over 400° C., the catalyst of the present invention obviously reduces the reaction temperature. The prepared catalyst can catalyze the intramolecular dehydration reaction of the amino alcohol and has relatively excellent selectivity.

公开(公告)号：US20170022207A1

公开(公告)日：2017-01-26

申请号：US15105883

申请日：2014-09-05

Applicant: XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

Inventor： Jianming Yang ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Jun Yuan ,  Wei Wang ,  Yani Li ,  Weiqiang Wang ,  Jian Lu

IPC: C07D487/08 ,  B01J31/02 ,  B01J19/00 ,  B01J27/18 ,  C07D203/02 ,  C07D295/023

CPC classification number: C07D487/08 ,  B01J19/0046 ,  B01J21/02 ,  B01J21/063 ,  B01J27/18 ,  B01J31/0237 ,  B01J2219/00452 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/0072 ,  B01J2231/44 ,  B01J2531/002 ,  C07D203/02 ,  C07D295/023

Abstract: Disclosed are a joint production method and device for aziridine, piperazine and triethylenediamine. The method comprises: reaction 1, preparing piperazine and triethylenediamine by taking ethanol amine as a raw material under the existence of a cyclamine catalyst; reaction 2, preparing aziridine by taking the ethanol amine as the raw material under the existence of a catalyst B; and taking heat released in the reaction 1 as a heat source of heat absorption in the reaction 2. The device comprises a reactor 1 for carrying out the reaction 1 and the heat exchange between reaction materials of the reaction 1 and the raw material of the reaction 2 and a reactor 2 for carrying out the reaction 2. According to the present invention, the same raw material, namely the ethanol amine is adopted, aziridine, piperazine and triethylenediamine can be produced in a joint manner, the heat released in the reaction 1 is used for preheating materials in the reaction 2, so that heat coupling between the reactions is implemented, energy conservation is facilitated and competitiveness of the device is improved.

Abstract translation: 公开了用于氮丙啶，哌嗪和三亚乙基二胺的联合制备方法和装置。 该方法包括：反应1，在环胺催化剂存在下，以乙醇胺为原料制备哌嗪和三亚乙基二胺; 反应2，在催化剂B存在下以乙醇胺为原料制备氮丙啶; 并且将反应1中释放的热作为反应2中的热吸收热源。该装置包括用于进行反应1的反应器1和反应1的反应物质与反应原料之间的热交换 2和用于进行反应2的反应器2.根据本发明，采用相同的原料即乙醇胺，可以以联合方式制备氮丙啶，哌嗪和三亚乙基二胺，反应1中释放的热量 用于在反应2中预热材料，从而实现反应之间的热耦合，促进节能并提高装置的竞争力。

公开(公告)号：US20160318863A1

公开(公告)日：2016-11-03

申请号：US15105499

申请日：2014-09-05

Applicant: XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

Inventor： Jianming Yang ,  Jian Lu ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Yani Li ,  Fengwei Zhao ,  Weiqiang Wang ,  Wei Wang

IPC: C07D203/08 ,  B01J27/182 ,  B01J35/00 ,  B01J37/26 ,  B01J37/04 ,  B01J37/00 ,  B01J37/08 ,  B01J23/78 ,  B01J21/08

CPC classification number: C07D203/08 ,  B01J21/063 ,  B01J21/08 ,  B01J23/78 ,  B01J27/182 ,  B01J27/1853 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0217 ,  B01J37/04 ,  B01J37/082 ,  B01J37/088 ,  B01J37/26 ,  B01J37/28 ,  B01J2523/00 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/842

Abstract: The present invention relates to a catalyst for synthesizing ethylenimine as well as a preparation method and application thereof. The related catalyst comprises a carrier and metal ions loaded on the carrier; the carrier is a composite oxide comprising titanium, silicon and phosphorus elements; the metal ions are magnesium ions, iron ions and cesium ions; the molar ratio of the magnesium ions to the iron ions to the cesium ions is (1-10):1:0.1; the mass of all metal ions is 0.5-10 percent of that of the carrier. In the related preparation method, a catalyst precursor is roasted at the temperature of 350-650° C., so that the catalyst is obtained; the catalyst precursor is the mixture of the carrier, soluble salt of magnesium, soluble salt of iron and soluble salt of cesium. The present invention also provides the application of the catalyst to synthesis of the ethylenimine by using amino alcohol as the raw material. Compared with a common catalyst which has the requirement on the temperature of over 400° C., the catalyst of the present invention obviously reduces the reaction temperature. The prepared catalyst can catalyze the intramolecular dehydration reaction of the amino alcohol and has relatively excellent selectivity.

Abstract translation: 本发明涉及一种合成乙烯亚胺的催化剂及其制备方法和应用。 相关催化剂包含负载在载体上的载体和金属离子; 载体是包含钛，硅和磷元素的复合氧化物; 金属离子是镁离子，铁离子和铯离子; 镁离子与铁离子与铯离子的摩尔比为（1-10）：1：0.1; 所有金属离子的质量为载体的质量的0.5-10％。 在相关的制备方法中，将催化剂前体在350-650℃的温度下焙烧，得到催化剂; 催化剂前体是载体，镁的可溶盐，铁的可溶性盐和铯的可溶性盐的混合物。 本发明还提供了通过使用氨基醇作为原料来催化合成乙烯亚胺的应用。 与对超过400℃的温度要求的普通催化剂相比，本发明的催化剂明显降低了反应温度。 制备的催化剂可以催化氨基醇的分子内脱水反应，并具有较好的选择性。

公开(公告)号：US20180093993A1

公开(公告)日：2018-04-05

申请号：US15817045

申请日：2017-11-17

Applicant: XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

Inventor： Jianming Yang ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Jun Yuan ,  Wei Wang ,  Yani Li ,  Weiqiang Wang ,  Jian Lu

IPC: C07D487/08 ,  C07D203/02 ,  B01J19/00 ,  B01J21/02 ,  B01J21/06 ,  B01J27/18 ,  B01J31/02 ,  C07D295/023

CPC classification number: C07D487/08 ,  B01J19/0046 ,  B01J21/02 ,  B01J21/063 ,  B01J27/18 ,  B01J31/0237 ,  B01J2219/00452 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/0072 ,  B01J2231/44 ,  B01J2531/002 ,  C07D203/02 ,  C07D295/023

Abstract: Disclosed are a joint production method and device for aziridine, piperazine and triethylenediamine. The method comprises: reaction 1, preparing piperazine and triethylenediamine by taking ethanol amine as a raw material under the existence of a cyclamine catalyst; reaction 2, preparing aziridine by taking the ethanol amine as the raw material under the existence of a catalyst B; and taking heat released in the reaction 1 as a heat source of heat absorption in the reaction 2. The device comprises a reactor 1 for carrying out the reaction 1 and the heat exchange between reaction materials of the reaction 1 and the raw material of the reaction 2 and a reactor 2 for carrying out the reaction 2. According to the present invention, the same raw material, namely the ethanol amine is adopted, aziridine, piperazine and triethylenediamine can be produced in a joint manner, the heat released in the reaction 1 is used for preheating materials in the reaction 2, so that heat coupling between the reactions is implemented, energy conservation is facilitated and competitiveness of the device is improved.

公开(公告)号：US09850250B2

公开(公告)日：2017-12-26

申请号：US15105883

申请日：2014-09-05

Applicant: XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

Inventor： Jianming Yang ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Jun Yuan ,  Wei Wang ,  Yani Li ,  Weiqiang Wang ,  Jian Lu

IPC: C07D487/08 ,  C07D203/02 ,  C07D295/023 ,  B01J27/18 ,  B01J21/02 ,  B01J21/06 ,  B01J19/00 ,  B01J31/02

CPC classification number: C07D487/08 ,  B01J19/0046 ,  B01J21/02 ,  B01J21/063 ,  B01J27/18 ,  B01J31/0237 ,  B01J2219/00452 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/0072 ,  B01J2231/44 ,  B01J2531/002 ,  C07D203/02 ,  C07D295/023

Abstract: Disclosed are a joint production method and device for aziridine, piperazine and triethylenediamine. The method comprises: reaction 1, preparing piperazine and triethylenediamine by taking ethanol amine as a raw material under the existence of a cyclamine catalyst; reaction 2, preparing aziridine by taking the ethanol amine as the raw material under the existence of a catalyst B; and taking heat released in the reaction 1 as a heat source of heat absorption in the reaction 2. The device comprises a reactor 1 for carrying out the reaction 1 and the heat exchange between reaction materials of the reaction 1 and the raw material of the reaction 2 and a reactor 2 for carrying out the reaction 2. According to the present invention, the same raw material, namely the ethanol amine is adopted, aziridine, piperazine and triethylenediamine can be produced in a joint manner, the heat released in the reaction 1 is used for preheating materials in the reaction 2, so that heat coupling between the reactions is implemented, energy conservation is facilitated and competitiveness of the device is improved.