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1.发明申请公开(公告)号：US20130091682A1
公开(公告)日：2013-04-18
申请号：US13698185
申请日：2010-06-30
申请人： Yahong Zhang , Yanli Huo , Stéphane Costeux , Thomas H. Kalantar
发明人： Yahong Zhang , Yanli Huo , Stéphane Costeux , Thomas H. Kalantar
CPC分类号： E04B1/806 , B29C39/003 , B32B5/16 , B82Y30/00 , C08G18/0823 , C08J3/212 , C08J2375/04 , C08K3/36 , C08K7/26 , Y10S977/781 , Y10T29/49826 , C08L75/04
摘要： An article contains inorganic nanoporous particles bound together by water dispersible polyurethane, the article having 75 volume-percent or more inorganic nanoporous particles based on total article volume and having a density of 0.14 grams per cubic centimeter or less and a thermal conductivity of 25 milliWatts per meter*Kelvin or less and having a thickness of at least 0.5 centimeters. A process for preparing such an article includes dispersing inorganic nanoporous particles into an aqueous dispersion of dispersible polyurethane to form a dispersion, casting the dispersion into a mold, and drying to form an article. A method for using such an article includes placing the article in a structure between two areas that can differ in temperature.
摘要翻译： 一种制品包含由水分散性聚氨酯结合在一起的无机纳米多孔颗粒，该制品基于总制品体积具有75体积％或更多的无机纳米多孔颗粒，并且具有0.14克/立方厘米或更小的密度和25毫瓦的热导率 米*开尔文或更小，厚度至少为0.5厘米。 制备这种制品的方法包括将无机纳米多孔颗粒分散到可分散聚氨酯的水分散体中以形成分散体，将分散体浇铸到模具中，并干燥以形成制品。 使用这种制品的方法包括将制品放置在温度不同的两个区域之间的结构中。
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公开(公告)号：US09650500B2
公开(公告)日：2017-05-16
申请号：US13879522
申请日：2010-11-15
CPC分类号： C08K7/26 , C08J3/126 , C08J9/32 , C08J2325/06 , C08J2433/00 , C08K7/22 , Y10T428/249921 , Y10T428/249972 , Y10T428/268 , C08L51/06
摘要： Prepare an article of manufacture by providing a latex of hollow latex particles with a rigid inner shell and adhesive outer shell, providing nanoporous particles and dispersing them into the latex and drying the latex so as to cause the hollow latex particle to bind to one another and form an article of manufacture containing nanoporous particles and hollow latex particles wherein the hollow latex particles are bound directly to one another to form a continuous matrix and the nanoporous particles are dispersed within the continuous matrix of hollow latex particles.
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公开(公告)号：US20130224464A1
公开(公告)日：2013-08-29
申请号：US13879522
申请日：2010-11-15
IPC分类号： C08K7/26
CPC分类号： C08K7/26 , C08J3/126 , C08J9/32 , C08J2325/06 , C08J2433/00 , C08K7/22 , Y10T428/249921 , Y10T428/249972 , Y10T428/268 , C08L51/06
摘要： Prepare an article of manufacture by providing a latex of hollow latex particles with a rigid inner shell and adhesive outer shell, providing nanoporous particles and dispersing them into the latex and drying the latex so as to cause the hollow latex particle to bind to one another and form an article of manufacture containing nanoporous particles and hollow latex particles wherein the hollow latex particles are bound directly to one another to form a continuous matrix and the nanoporous particles are dispersed within the continuous matrix of hollow latex particles.
摘要翻译： 通过提供具有刚性内壳和粘合剂外壳的中空胶乳颗粒的胶乳来制备制品，提供纳米多孔颗粒并将其分散在胶乳中并干燥胶乳，以使中空胶乳颗粒彼此结合， 形成包含纳米多孔颗粒和中空胶乳颗粒的制品，其中中空胶乳颗粒彼此直接结合以形成连续基质，并且纳米多孔颗粒分散在中空胶乳颗粒的连续基体内。
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公开(公告)号：US09718938B2
公开(公告)日：2017-08-01
申请号：US13504561
申请日：2010-11-01
CPC分类号： C08J9/0066 , C08J9/0023 , C08J9/0071 , C08J9/122 , C08J2201/024 , C08J2201/03
摘要： Prepare a polymeric foam article having a thermoplastic polymer matrix defining multiple cells therein, wherein the polymeric foam article has the following characteristics: (a) the thermoplastic polymer matrix contains dispersed within it nano-sized nucleating additive particles that have at least two orthogonal dimensions that are less than 30 nanometers in length; (b) possesses at least one of the following two characteristics: (i) has an effective nucleation site density of at least 3×1014 sites per cubic centimeter of pre-foamed material; and (ii) has an average cell size of 300 nanometers or less; and (c) has a porosity percentage of more than 50 percent by rapidly expanding at a foaming temperature a foamable polymer composition containing the nucleating additive and a blowing agent containing at least one of carbon dioxide, nitrogen and argon.
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公开(公告)号：US20120225272A1
公开(公告)日：2012-09-06
申请号：US13504561
申请日：2010-11-01
CPC分类号： C08J9/0066 , C08J9/0023 , C08J9/0071 , C08J9/122 , C08J2201/024 , C08J2201/03
摘要： Prepare a polymeric foam article having a thermoplastic polymer matrix defining multiple cells therein, wherein the polymeric foam article has the following characteristics: (a) the thermoplastic polymer matrix contains dispersed within it nano-sized nucleating additive particles that have at least two orthogonal dimensions that are less than 30 nanometers in length; (b) possesses at least one of the following two characteristics: (i) has an effective nucleation site density of at least 3×1014 sites per cubic centimeter of pre-foamed material; and (ii) has an average cell size of 300 nanometers or less; and (c) has a porosity percentage of more than 50 percent by rapidly expanding at a foaming temperature a foamable polymer composition containing the nucleating additive and a blowing agent containing at least one of carbon dioxide, nitrogen and argon.
摘要翻译： 制备具有在其中限定多个细胞的热塑性聚合物基质的聚合物泡沫制品，其中聚合物泡沫制品具有以下特征：（a）热塑性聚合物基质在其内分散有至少两个正交尺寸的纳米尺寸的成核添加剂颗粒， 长度小于30纳米; （b）具有以下两个特征中的至少一个：（i）有效成核位点密度为每立方厘米预发泡材料至少3×1014个位点; 和（ii）具有300纳米或更小的平均泡孔尺寸; 和（c）通过在发泡温度下快速膨胀含有所述成核添加剂的发泡性聚合物组合物和含有二氧化碳，氮和氩中的至少一种的发泡剂，具有大于50％的孔隙率。
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公开(公告)号：US09145478B2
公开(公告)日：2015-09-29
申请号：US14238679
申请日：2012-09-14
IPC分类号： C08J9/12 , B29C44/34 , B29K105/04
CPC分类号： C08J9/122 , B29C44/3446 , B29C44/348 , B29K2105/041 , C08J2201/03 , C08J2203/06 , C08J2203/08 , C08J2205/042 , C08J2325/04 , C08J2333/12
摘要： Prepare a polymeric nanofoam using a continuous extrusion process by providing a polymer melt of a polymer composition in an extruder, introducing carbon dioxide to a concentration above the solubility in the polymer melt, cooling the polymer melt without increasing the pressure to achieve conditions where all of the carbon dioxide is soluble in the polymer composition and then extruding the polymer composition and carbon dioxide mixture through an extrusion die so as to experience a pressure drop of at least five MegaPascals at a rate of at least ten MegaPascals per second and allowing the polymer composition to expand into a polymeric nanofoam.
摘要翻译： 通过在挤出机中提供聚合物组合物的聚合物熔体来制备聚合物纳米电影，将二氧化碳引入高于聚合物熔体中的溶解度的浓度，冷却聚合物熔体而不增加压力，以达到所有 二氧化碳可溶于聚合物组合物中，然后通过挤出模头挤出聚合物组合物和二氧化碳混合物，以便以至少10兆帕/秒的速率经历至少5兆帕斯卡的压降，并允许聚合物组合物 扩展成聚合物纳米烟雾。
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公开(公告)号：US20140221512A1
公开(公告)日：2014-08-07
申请号：US14238679
申请日：2012-09-14
IPC分类号： C08J9/12
CPC分类号： C08J9/122 , B29C44/3446 , B29C44/348 , B29K2105/041 , C08J2201/03 , C08J2203/06 , C08J2203/08 , C08J2205/042 , C08J2325/04 , C08J2333/12
摘要： Prepare a polymeric nanofoam using a continuous extrusion process by providing a polymer melt of a polymer composition in an extruder, introducing carbon dioxide to a concentration above the solubility in the polymer melt, cooling the polymer melt without increasing the pressure to achieve conditions where all of the carbon dioxide is soluble in the polymer composition and then extruding the polymer composition and carbon dioxide mixture through an extrusion die so as to experience a pressure drop of at least five MegaPascals at a rate of at least ten MegaPascals per second and allowing the polymer composition to expand into a polymeric nanofoam.
摘要翻译： 通过在挤出机中提供聚合物组合物的聚合物熔体来制备聚合物纳米电影，将二氧化碳引入高于聚合物熔体中的溶解度的浓度，冷却聚合物熔体而不增加压力，以达到所有 二氧化碳可溶于聚合物组合物中，然后通过挤出模头挤出聚合物组合物和二氧化碳混合物，以便以至少10兆帕/秒的速率经历至少5兆帕斯卡的压降，并允许聚合物组合物 扩展成聚合物纳米烟雾。
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公开(公告)号：US20140200283A1
公开(公告)日：2014-07-17
申请号：US14238746
申请日：2012-09-14
CPC分类号： C08L33/20 , B32B5/32 , C08J9/0061 , C08J9/122 , C08J2203/06 , C08J2333/06 , C08J2425/12 , C08J2455/02 , C08L33/10
摘要： A polymeric nanofoam has a continuous polymer phase containing at least one (meth)acrylic-free acrylonitrile-containing copolymer and at least one (meth)acrylic polymer where the concentration of (meth)acrylic polymer is in a range of 5-90 weight-percent of the total continuous polymer phase while the amount of methacrylic copolymer is 50 weight-percent or less of the total continuous polymer phase; the polymeric foam having a porosity of at least 50%, an absence of nano-sized nucleating additives and at least one of the following: (a) a number average cell size of 500 nanometers or less; and (b) an effective nucleation site density of at least 1×1014 sites per cubic centimeter of prefoamed material. The total weight of copolymerized acrylonitrile is in a range of 3-28 weight-percent based on total continuous polymer phase weight. At least one (meth)acrylic-free acrylonitrile-containing copolymer has a higher glass transition temperature than all of the (meth)acrylic polymers.
摘要翻译： 聚合物纳米纤维具有包含至少一种（甲基）丙烯酸 - 丙烯腈共聚物和至少一种（甲基）丙烯酸类聚合物的连续聚合物相，其中（甲基）丙烯酸聚合物的浓度在5-90重量％ 的总连续聚合物相的百分比，而甲基丙烯酸共聚物的量为总连续聚合物相的50重量％或更少; 所述聚合物泡沫具有至少50％的孔隙率，不存在纳米尺寸的成核添加剂和以下至少一种：（a）500纳米或更小的数均孔数; 和（b）有效成核位点密度为每立方厘米预发泡材料至少1×1014个位点。 基于总连续聚合物相重量，共聚丙烯腈的总重量在3-28重量％的范围内。 至少一种（甲基）丙烯酸 - 含丙烯腈的共聚物具有比所有（甲基）丙烯酸聚合物更高的玻璃化转变温度。
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