公开(公告)号：US08022151B2

公开(公告)日：2011-09-20

申请号：US12598041

申请日：2008-04-28

申请人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

发明人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

IPC分类号： C08G59/12 ,  C08L63/00

CPC分类号： C07D303/16 ,  C08G59/24 ,  C08G59/3218 ,  C08G59/42 ,  C08L63/00 ,  G03F7/038

摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.

摘要翻译： 提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。 生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

公开(公告)号：US20100093947A1

公开(公告)日：2010-04-15

申请号：US12598041

申请日：2008-04-28

申请人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

发明人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

IPC分类号： C08L63/00 ,  C08G63/06 ,  C08L67/00

CPC分类号： C07D303/16 ,  C08G59/24 ,  C08G59/3218 ,  C08G59/42 ,  C08L63/00 ,  G03F7/038

摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.

摘要翻译： 提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。 生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

公开(公告)号：US20100130712A1

公开(公告)日：2010-05-27

申请号：US12594254

申请日：2008-03-31

申请人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Shinobu Yamao

发明人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Shinobu Yamao

IPC分类号： C08F124/00 ,  C07D205/04

CPC分类号： C07D303/12 ,  C07D305/06 ,  C08F220/28 ,  C08F220/32 ,  C08G65/105 ,  C08G65/18 ,  C08L63/00

摘要： Provided is a cured resin of an adamantane derivative having a specific structure, which has excellent optical properties such as transparency and (long-term) light stability, long-term heat resistance, dielectric constant, and mechanical properties, and which can be utilized suitably in the field of electronic and optical materials.

摘要翻译： 提供具有特定结构的金刚烷衍生物的固化树脂，其具有优异的光学性能如透明度和（长期）光稳定性，长期耐热性，介电常数和机械性能，并且可以适当地使用 在电子和光学材料领域。

公开(公告)号：US08110614B2

公开(公告)日：2012-02-07

申请号：US12516102

申请日：2007-11-21

申请人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Akio Kojima

发明人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Akio Kojima

IPC分类号： C08F2/46 ,  C08F20/10 ,  C07C39/04 ,  C07C69/52 ,  C07D303/00 ,  C07D301/27 ,  C08G65/08

CPC分类号： C08F20/30 ,  C07C39/17 ,  C07C67/26 ,  C07C2603/74 ,  C07D303/30 ,  C08G59/3218 ,  H05K3/287 ,  C07C69/54

摘要： Adamantane derivatives are provided including a phenolic hydroxyl group-containing adamantane derivative, a glycidyloxy group-containing adamantane derivative, and an adamantyl group-containing epoxy modified acrylate, which exhibit excellent transparency, light resistance, and heat resistance properties. Also provided are resin compositions containing the adamantane derivatives. Further provided are corresponding methods for producing the adamantane derivatives, as well as the resin compositions containing the same.

摘要翻译： 提供了金刚烷衍生物，其包括含有酚羟基的金刚烷衍生物，含缩水甘油氧基的金刚烷衍生物和含金刚烷基的环氧改性丙烯酸酯，其表现出优异的透明性，耐光性和耐热性。 还提供含有金刚烷衍生物的树脂组合物。 还提供了用于制备金刚烷衍生物的相应方法，以及含有该金刚烷衍生物的树脂组合物。

公开(公告)号：US20100048757A1

公开(公告)日：2010-02-25

申请号：US12447308

申请日：2007-10-24

申请人： Yasunari Okada ,  Hideki Yamane ,  Katsuki Ito ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hideki Yamane ,  Katsuki Ito ,  Nobuaki Matsumoto

IPC分类号： C08F2/46 ,  C07C69/54 ,  C08L31/02

CPC分类号： G03F7/027 ,  C07C67/08 ,  C07C69/54 ,  C07C2603/74 ,  C08F20/20 ,  C08F20/28

摘要： Disclosed herein is an adamantane derivative represented by the following general formula (I): (wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, ═O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.

摘要翻译： 本文公开了由以下通式（I）表示的金刚烷衍生物：其中R表示氢原子，氟原子，甲基或三氟甲基; Y表示氢原子，羟基，由式 两个Y一起，一个羧基或一个碳原子数1〜20的烃基或碳原子数3〜20的环状烃基，m为13，n为3，m为12，n为4，p为 1个以上的整数），其制造方法，含有金刚烷衍生物的树脂组合物及其固化物。 本发明提供了作为各种涂布剂，微透镜，薄膜冷凝器，液晶滤色器着色组合物，纳米压印等形成的图案组织器等有利的固化产物，具有透明性，耐热性，良好的机械性能 ，低体积收缩率和低的线性膨胀系数，以及含有金刚烷基的（甲基）丙烯酸酯以制备固化产物，其制备方法和树脂组合物。

公开(公告)号：US20100056663A1

公开(公告)日：2010-03-04

申请号：US12516102

申请日：2007-11-21

申请人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Akio Kojima

发明人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Akio Kojima

IPC分类号： C08F2/46 ,  C07C39/04 ,  C07D303/02 ,  C08G65/08 ,  C07C69/52

CPC分类号： C08F20/30 ,  C07C39/17 ,  C07C67/26 ,  C07C2603/74 ,  C07D303/30 ,  C08G59/3218 ,  H05K3/287 ,  C07C69/54

摘要： The present invention is an adamantane derivative which provides optical characteristics such as transparency, (long term) light resistance and the like, long term heat resistance, electric characteristics such as dielectric constant and the like, and good mechanical properties; a production method thereof; and a resin composition containing the above-mentioned adamantane derivative that is an adamantane derivative represented by general formulae (I) to (III); for example, a production method of an adamantane derivative represented by the general formula (III) by reacting an adamantane derivative represented by the general formula (II) with acrylates, a resin composition containing an adamantane derivative represented by the general formula (II) and an epoxy resin curing agent, and a resin composition containing an adamantane derivative represented by the general formula (III) and a thermopolymerization initiator or a photopolymerization initiator.In the formula, R1 represents CnH2n+1 (n is an integer of 1 to 10); R2 represents H, CH3, F or CF3; j is an integer of 1 to 4; k is an integer of 0 to 3; m is an integer of 2 to 5; and j+k+m≦6.

摘要翻译： 本发明是提供透明性，长期耐光性等长期耐热性，介电常数等电特性等良好的机械特性的光学特性的金刚烷衍生物。 其制造方法; 和含有上述通式（I）〜（III）所示的金刚烷衍生物的金刚烷衍生物的树脂组合物; 例如通过使通式（II）表示的金刚烷衍生物与丙烯酸酯反应的通式（III）表示的金刚烷衍生物的制造方法，含有通式（II）表示的金刚烷衍生物的树脂组合物和 环氧树脂固化剂和含有由通式（III）表示的金刚烷衍生物和热聚合引发剂或光聚合引发剂的树脂组合物。 在该式中，R 1表示C n H 2n + 1（n为1〜10的整数）。 R2代表H，CH3，F或CF3; j为1〜4的整数， k为0〜3的整数， m为2〜5的整数， 和j + k + m＆nlE; 6。

公开(公告)号：US20070129532A1

公开(公告)日：2007-06-07

申请号：US10588080

申请日：2005-02-01

申请人： Naoyoshi Hatakeyama ,  Shinji Tanaka ,  Hidetoshi Ono ,  Yasunari Okada

发明人： Naoyoshi Hatakeyama ,  Shinji Tanaka ,  Hidetoshi Ono ,  Yasunari Okada

IPC分类号： C08G69/14

CPC分类号： C07C69/54 ,  C07C67/29 ,  C07C303/28 ,  C07C309/66 ,  C07C2603/74

摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl(meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.

摘要翻译： 本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。 将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。 分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体 例如光刻领域的感光性树脂。

公开(公告)号：US20090156854A1

公开(公告)日：2009-06-18

申请号：US12363895

申请日：2009-02-02

申请人： Naoyoshi HATAKEYAMA ,  Shinji Tanaka ,  Hidetoshi Ono ,  Yasunari Okada

发明人： Naoyoshi HATAKEYAMA ,  Shinji Tanaka ,  Hidetoshi Ono ,  Yasunari Okada

IPC分类号： C07C255/01 ,  C07C69/533

CPC分类号： C07C69/54 ,  C07C67/29 ,  C07C303/28 ,  C07C309/66 ,  C07C2603/74

摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl (meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.

摘要翻译： 本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。 将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。 分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体 例如光刻领域的感光性树脂。

公开(公告)号：US07528279B2

公开(公告)日：2009-05-05

申请号：US10588080

申请日：2005-02-01

申请人： Naoyoshi Hatakeyama ,  Shinji Tanaka ,  Hidetoshi Ono ,  Yasunari Okada

发明人： Naoyoshi Hatakeyama ,  Shinji Tanaka ,  Hidetoshi Ono ,  Yasunari Okada

IPC分类号： C07C69/54 ,  C07C67/29 ,  C07C303/28 ,  C07C303/44 ,  C07C309/66

CPC分类号： C07C69/54 ,  C07C67/29 ,  C07C303/28 ,  C07C309/66 ,  C07C2603/74

摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl(meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.

摘要翻译： 本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。 将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。 分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体 例如光刻领域的感光性树脂。

公开(公告)号：US20090062481A1

公开(公告)日：2009-03-05

申请号：US12279772

申请日：2007-02-01

申请人： Hajime Ito ,  Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Hajime Ito ,  Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C08L63/00 ,  C07D305/06 ,  C07D303/12

CPC分类号： C07D303/30 ,  C07D305/06 ,  C08G59/24 ,  C08G59/42

摘要： To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions.An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Y represents a group represented by the formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16−m) and p and q are each an integer of 1 to 5.

摘要翻译： 为了提供金刚烷衍生物，具有金刚烷骨架的化合物，含有它们的组合物可以提供具有优异的光学性质如透明性和耐光性，长期耐热性和电特性如介电常数的固化产物和光学电子部件 使用组合物。 由通式（I）表示的金刚烷衍生物，具有由通式（VII）或（VIII）表示的金刚烷骨架的化合物，含有它们的组合物和使用该树脂组合物的光学电子部件。 在该式中，W表示例如氢原子，X表示例如由通式（II）表示的基团，Y表示由式（V）或（VI）表示的基团，R1表示 甲基或乙基，R2表示可以含有O或S的C1〜C10烃基，m为2〜4的整数，k为0〜（16-m）的整数，p和q各自为 1〜5的整数。