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    Adamantane derivative, method for producing the same, resin composition containing the adamantane derivative and use thereof
    1.
    发明授权
    Adamantane derivative, method for producing the same, resin composition containing the adamantane derivative and use thereof 有权
    金刚烷衍生物，其制造方法，含有金刚烷衍生物的树脂组合物及其用途

    公开(公告)号：US08022151B2

    公开(公告)日：2011-09-20

    申请号：US12598041

    申请日：2008-04-28

    申请人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

    发明人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

    IPC分类号： C08G59/12 ,  C08L63/00

    CPC分类号： C07D303/16 ,  C08G59/24 ,  C08G59/3218 ,  C08G59/42 ,  C08L63/00 ,  G03F7/038

    摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.

    摘要翻译： 提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。 生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

    ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, RESIN COMPOSITION CONTAINING THE ADAMANTANE DERIVATIVE AND USE THEREOF
    2.
    发明申请
    ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, RESIN COMPOSITION CONTAINING THE ADAMANTANE DERIVATIVE AND USE THEREOF 有权
    亚胺衍生物，其制备方法，含有衍生物的树脂组合物及其用途

    公开(公告)号：US20100093947A1

    公开(公告)日：2010-04-15

    申请号：US12598041

    申请日：2008-04-28

    申请人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

    发明人： Yasunari Okada ,  Hidetoshi Ono ,  Katsuki Ito

    IPC分类号： C08L63/00 ,  C08G63/06 ,  C08L67/00

    CPC分类号： C07D303/16 ,  C08G59/24 ,  C08G59/3218 ,  C08G59/42 ,  C08L63/00 ,  G03F7/038

    摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.

    摘要翻译： 提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。 生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

    ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITION, AND CURED PRODUCT OF THE RESIN COMPOSITION
    3.
    发明申请
    ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITION, AND CURED PRODUCT OF THE RESIN COMPOSITION 审中-公开
    衍生物衍生物，其生产方法，树脂组合物和树脂组合物的固化产物

    公开(公告)号：US20100048757A1

    公开(公告)日：2010-02-25

    申请号：US12447308

    申请日：2007-10-24

    申请人： Yasunari Okada ,  Hideki Yamane ,  Katsuki Ito ,  Nobuaki Matsumoto

    发明人： Yasunari Okada ,  Hideki Yamane ,  Katsuki Ito ,  Nobuaki Matsumoto

    IPC分类号： C08F2/46 ,  C07C69/54 ,  C08L31/02

    CPC分类号： G03F7/027 ,  C07C67/08 ,  C07C69/54 ,  C07C2603/74 ,  C08F20/20 ,  C08F20/28

    摘要： Disclosed herein is an adamantane derivative represented by the following general formula (I): (wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, ═O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.

    摘要翻译： 本文公开了由以下通式（I）表示的金刚烷衍生物：其中R表示氢原子，氟原子，甲基或三氟甲基; Y表示氢原子，羟基，由式 两个Y一起，一个羧基或一个碳原子数1〜20的烃基或碳原子数3〜20的环状烃基，m为13，n为3，m为12，n为4，p为 1个以上的整数），其制造方法，含有金刚烷衍生物的树脂组合物及其固化物。 本发明提供了作为各种涂布剂，微透镜，薄膜冷凝器，液晶滤色器着色组合物，纳米压印等形成的图案组织器等有利的固化产物，具有透明性，耐热性，良好的机械性能 ，低体积收缩率和低的线性膨胀系数，以及含有金刚烷基的（甲基）丙烯酸酯以制备固化产物，其制备方法和树脂组合物。

    ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION CONTAINING ADAMANTANE DERIVATIVE
    6.
    发明申请
    ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION CONTAINING ADAMANTANE DERIVATIVE 有权
    亚胺衍生物，其制备方法和含有衍生物的树脂组合物

    公开(公告)号：US20100056663A1

    公开(公告)日：2010-03-04

    申请号：US12516102

    申请日：2007-11-21

    申请人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Akio Kojima

    发明人： Katsuki Ito ,  Yasunari Okada ,  Hideki Yamane ,  Akio Kojima

    IPC分类号： C08F2/46 ,  C07C39/04 ,  C07D303/02 ,  C08G65/08 ,  C07C69/52

    CPC分类号： C08F20/30 ,  C07C39/17 ,  C07C67/26 ,  C07C2603/74 ,  C07D303/30 ,  C08G59/3218 ,  H05K3/287 ,  C07C69/54

    摘要： The present invention is an adamantane derivative which provides optical characteristics such as transparency, (long term) light resistance and the like, long term heat resistance, electric characteristics such as dielectric constant and the like, and good mechanical properties; a production method thereof; and a resin composition containing the above-mentioned adamantane derivative that is an adamantane derivative represented by general formulae (I) to (III); for example, a production method of an adamantane derivative represented by the general formula (III) by reacting an adamantane derivative represented by the general formula (II) with acrylates, a resin composition containing an adamantane derivative represented by the general formula (II) and an epoxy resin curing agent, and a resin composition containing an adamantane derivative represented by the general formula (III) and a thermopolymerization initiator or a photopolymerization initiator.In the formula, R1 represents CnH2n+1 (n is an integer of 1 to 10); R2 represents H, CH3, F or CF3; j is an integer of 1 to 4; k is an integer of 0 to 3; m is an integer of 2 to 5; and j+k+m≦6.

    摘要翻译： 本发明是提供透明性，长期耐光性等长期耐热性，介电常数等电特性等良好的机械特性的光学特性的金刚烷衍生物。 其制造方法; 和含有上述通式（I）〜（III）所示的金刚烷衍生物的金刚烷衍生物的树脂组合物; 例如通过使通式（II）表示的金刚烷衍生物与丙烯酸酯反应的通式（III）表示的金刚烷衍生物的制造方法，含有通式（II）表示的金刚烷衍生物的树脂组合物和 环氧树脂固化剂和含有由通式（III）表示的金刚烷衍生物和热聚合引发剂或光聚合引发剂的树脂组合物。 在该式中，R 1表示C n H 2n + 1（n为1〜10的整数）。 R2代表H，CH3，F或CF3; j为1〜4的整数， k为0〜3的整数， m为2〜5的整数， 和j + k + m＆nlE; 6。

    POLYMERIZABLE COMPOUND HAVING ADAMANTANE STRUCTURE, PROCESS FOR PRODUCTION OF THE SAME, AND RESIN COMPOSITION
    9.
    发明申请
    POLYMERIZABLE COMPOUND HAVING ADAMANTANE STRUCTURE, PROCESS FOR PRODUCTION OF THE SAME, AND RESIN COMPOSITION 审中-公开
    具有ADAMANTANE结构的可聚合化合物，其生产方法和树脂组合物

    公开(公告)号：US20100022730A1

    公开(公告)日：2010-01-28

    申请号：US12376122

    申请日：2007-07-09

    申请人： Naoyoshi Hatakeyama ,  Hidetoshi Ono ,  Katsuki Ito

    发明人： Naoyoshi Hatakeyama ,  Hidetoshi Ono ,  Katsuki Ito

    IPC分类号： C08F18/20 ,  C07C69/54 ,  C07C69/593

    CPC分类号： C07C67/10 ,  C07C67/29 ,  C07C2601/14 ,  C07C2603/74 ,  C08F220/24 ,  G03F7/0046 ,  G03F7/027 ,  G03F7/0397 ,  G03F7/11 ,  G03F7/2041 ,  C07C69/653

    摘要： A polymerizable compound having a fluorinated substituent (Z) represented by the general formula (1), an adamantane structure and a polymerizable group (A) having the structure represented by the general formula (1), a production method thereof, and a photoresist composition, a thermocurable resin composition and a photocurable resin composition containing a polymer obtained using the polymerizable compound are provided. Use of the polymerizable compound with the adamantane structure and a resin composition thereof in the present invention provides in the field of photolithography the effect of preventing a liquid immersion medium from penetration and improving dry etching resistance in a liquid immersion exposure method as well as reducing adhesion to a mold and improving dry etching resistance in a nanoimprint method.

    摘要翻译： 具有由通式（1）表示的氟化取代基（Z），金刚烷结构和具有通式（1）表示的结构的聚合性基团（A）的聚合性化合物，其制造方法和光致抗蚀剂组合物 提供了一种耐热树脂组合物和含有使用该聚合性化合物得到的聚合物的光固化性树脂组合物。 在本发明中使用具有金刚烷结构的可聚合化合物和其树脂组合物在光刻领域中提供了防止液浸介质渗透的效果，并且在液浸曝光方法中提高了耐干蚀刻性以及降低附着力 并且在纳米压印方法中提高干蚀刻电阻。