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1.发明授权Filled nanoporous polymer membrane composites for protective clothing and methods for making them 失效用于防护服的填充纳米多孔聚合物膜复合材料及其制备方法公开(公告)号：US08686054B2
公开(公告)日：2014-04-01
申请号：US13443552
申请日：2012-04-10
IPC分类号： B01J49/00
CPC分类号： A62D5/00 , B01D67/0006 , B01D69/02 , B01D69/10 , B01D69/105 , B01D2313/48 , B01D2323/286 , B01D2325/08 , B01D2325/36 , B01D2325/38
摘要： A new class of membranes for use in protective clothing. More specifically, the present invention relates to a polymer-polymer membrane with an ionic polymer located within the nanopores of a porous polymer host membrane. A method for making the polymer-polymer membranes involves filling porous polymers with ionic polymers. The porous polymers may be fabricated by a template synthesis which involves sorption. The ionic polymers may be filled in the nanopores of the porous polymer by plasma-induced graft copolymerization of the ionic polymer with the porous polymeric host membrane.
摘要翻译： 用于防护服的新一类膜。 更具体地，本发明涉及一种聚合物 - 聚合物膜，其具有位于多孔聚合物主膜的纳米孔内的离子聚合物。 制备聚合物 - 聚合物膜的方法包括用离子聚合物填充多孔聚合物。 多孔聚合物可以通过涉及吸附的模板合成来制造。 离子聚合物可以通过等离子体诱导的离子聚合物与多孔聚合物主膜的接枝共聚而填充在多孔聚合物的纳米孔中。
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2.发明申请FILLED NANOPOROUS POLYMER MEMBRANE COMPOSITES FOR PROTECTIVE CLOTHING AND METHODS FOR MAKING THEM 有权用于保护衣服的填充纳米聚合物膜复合材料及其制备方法公开(公告)号：US20100160466A1
公开(公告)日：2010-06-24
申请号：US12301176
申请日：2007-05-24
IPC分类号： C08J5/22
CPC分类号： A62D5/00 , B01D67/0006 , B01D69/02 , B01D69/10 , B01D69/105 , B01D2313/48 , B01D2323/286 , B01D2325/08 , B01D2325/36 , B01D2325/38
摘要： A new class of membranes for use in protective clothing. More specifically, the present invention relates to a polymer-polymer membrane with an ionic polymer located within the nanopores of a porous polymer host membrane. A method for making the polymer-polymer membranes involves filling porous polymers with ionic polymers. The porous polymers may be fabricated by a template synthesis which involves sorption. The ionic polymers may be filled in the nanopores of the porous polymer by plasma-induced graft copolymerization of the ionic polymer with the porous polymeric host membrane.
摘要翻译： 用于防护服的新一类膜。 更具体地说，本发明涉及一种聚合物 - 聚合物膜，其具有位于多孔聚合物主膜的纳米孔内的离子聚合物。 制备聚合物 - 聚合物膜的方法包括用离子聚合物填充多孔聚合物。 多孔聚合物可以通过涉及吸附的模板合成来制造。 离子聚合物可以通过等离子体诱导的离子聚合物与多孔聚合物主膜的接枝共聚而填充在多孔聚合物的纳米孔中。
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3.发明授权Filled nanoporous polymer membrane composites for protective clothing and methods for making them 有权用于防护服的填充纳米多孔聚合物膜复合材料及其制备方法公开(公告)号：US08173713B2
公开(公告)日：2012-05-08
申请号：US12301176
申请日：2007-05-24
IPC分类号： C08J5/20
CPC分类号： A62D5/00 , B01D67/0006 , B01D69/02 , B01D69/10 , B01D69/105 , B01D2313/48 , B01D2323/286 , B01D2325/08 , B01D2325/36 , B01D2325/38
摘要： A new class of membranes for use in protective clothing. More specifically, the present invention relates to a polymer-polymer membrane with an ionic polymer located within the nanopores of a porous polymer host membrane. A method for making the polymer-polymer membranes involves filling porous polymers with ionic polymers. The porous polymers may be fabricated by a template synthesis which involves sorption. The ionic polymers may be filled in the nanopores of the porous polymer by plasma-induced graft copolymerization of the ionic polymer with the porous polymeric host membrane.
摘要翻译： 用于防护服的新一类膜。 更具体地，本发明涉及一种聚合物 - 聚合物膜，其具有位于多孔聚合物主膜的纳米孔内的离子聚合物。 制备聚合物 - 聚合物膜的方法包括用离子聚合物填充多孔聚合物。 多孔聚合物可以通过涉及吸附的模板合成来制造。 离子聚合物可以通过等离子体诱导的离子聚合物与多孔聚合物主膜的接枝共聚而填充在多孔聚合物的纳米孔中。
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公开(公告)号：US09884944B2
公开(公告)日：2018-02-06
申请号：US13698399
申请日：2011-05-18
CPC分类号： C08J5/04 , C08G2261/126 , C08G2261/46 , C08K9/04 , C08K9/10 , C08L63/00 , C08L71/02 , C08L79/085 , C08L77/00
摘要： Functionalized polymer matrix and/or reinforcement materials that are capable of a thermoreversible Diels-Alder reaction are useful for making composite materials. Also disclosed is a composite material which includes one or both of functionalized reinforcement materials and functionalized polymer matrix materials, as well as a method for repairing a composite material including the step of thermally treating the composite material at a temperature sufficient to react a functionality on one of the reinforcement material and the polymer matrix material with another functionality via a Diels-Alder reaction. A method of making a composite material including functionalizing one or both of a reinforcing material and a polymer matrix material with a first reactive group, providing a second reactive group capable of undergoing a Diels-Alder reaction with the first reactive group and reacting the first and second reactive groups to form a composite material, is also described.
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5.发明申请RENEWABLE BIO-BASED (METH) ACRYLATED MONOMERS AS VINYL ESTER CROSS-LINKERS 审中-公开可重复生物（甲基）丙烯酸酯单体作为乙烯酯交联剂公开(公告)号：US20140249285A1
公开(公告)日：2014-09-04
申请号：US14237170
申请日：2012-08-10
IPC分类号： C08F224/00 , C08F124/00 , C07D493/04
摘要： Anhydrosugar-based monomers prepared from isosorbide, isomannide, and isoidide and resin systems containing these anhydrosugar-based monomers that are partially to fully bio-based, which may produce materials having properties that meet or exceed the properties of similar petroleum derived vinyl ester resins.
摘要翻译： 由异山梨醇，异麦芽糖苷，以及含有部分完全生物基的这些基于脱硫基糖基的单体的树脂体系制备的基于脱水糖基的单体，其可以生产具有达到或超过类似的石油衍生的乙烯基酯树脂的性质的材料。
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公开(公告)号：US10544265B2
公开(公告)日：2020-01-28
申请号：US15543550
申请日：2016-01-29
摘要： The invention relates to the use of dicyanamide-containing ionic liquids which decrease the cure temperature of cyanate esters to form unique thermoset polymers having a triazine network. These thermoset polymers having the triazine network have an ionic character allowing for use in varied applications. The thermoset polymers described herein are useful in high temperature performance composites, and their high Tg makes them useful as a substitute for epoxies in the microelectronics industry. The thermoset polymers have good fracture toughness, excellent substrate adhesion, low shrinkage, and low moisture uptake.
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公开(公告)号：US10428175B2
公开(公告)日：2019-10-01
申请号：US15507532
申请日：2015-09-11
申请人： Drexel University , The United States of America as represented by the Secretary of the Army , Giuseppe R. Palmese , Fengshuo Hu , Xing Geng , John J. La Scala
发明人： Giuseppe R. Palmese , Fengshuo Hu , Xing Geng , John J. La Scala
IPC分类号： C08G59/20 , C08G59/22 , C08G59/24 , C08G59/28 , C08G59/32 , C08G59/50 , C08L63/00 , C08L63/02 , C08L63/04 , C08G59/14 , C08G59/06 , C08K3/00 , C09D163/00 , C11C3/00 , C08K3/013
摘要： Grafted triglycerides comprising a triglyceride grafted with a fatty acid residue containing 4 to 30 carbon atoms are reacted with an epoxide resin and an amine curing agent to yield an epoxy thermoset. The grafted triglyceride is prepared by reaction of an epoxidized triglyceride with a fatty acid. By varying the length of the fatty residue, the number of fatty residues per triglyceride, the identity of the epoxy resin and the amine curing agent, it is possible to prepare epoxy thermosets that exhibit superior physical properties compared to the properties of epoxy thermosets prepared without the grafted triglyceride, or as compared to epoxy thermosets wherein the epoxidized triglyceride is used in place of the grafted triglyceride.
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公开(公告)号：US20130059988A1
公开(公告)日：2013-03-07
申请号：US13698399
申请日：2011-05-18
IPC分类号： C08G59/14
CPC分类号： C08J5/04 , C08G2261/126 , C08G2261/46 , C08K9/04 , C08K9/10 , C08L63/00 , C08L71/02 , C08L79/085 , C08L77/00
摘要： Functionalized polymer matrix and/or reinforcement materials that are capable of a thermoreversible Diels-Alder reaction are useful for making composite materials. Also disclosed is a composite material which includes one or both of functionalized reinforcement materials and functionalized polymer matrix materials, as well as a method for repairing a composite material including the step of thermally treating the composite material at a temperature sufficient to react a functionality on one of the reinforcement material and the polymer matrix material with another functionality via a Diels-Alder reaction. A method of making a composite material including functionalizing one or both of a reinforcing material and a polymer matrix material with a first reactive group, providing a second reactive group capable of undergoing a Diels-Alder reaction with the first reactive group and reacting the first and second reactive groups to form a composite material, is also described.
摘要翻译： 能够进行热可逆Diels-Alder反应的官能化聚合物基质和/或增强材料可用于制备复合材料。 还公开了一种复合材料，其包括官能化增强材料和官能化聚合物基质材料中的一种或两种，以及用于修复复合材料的方法，所述复合材料包括在足以使功能性反应的温度下热处理复合材料的步骤 的增强材料和具有另一官能团的聚合物基质材料通过Diels-Alder反应。 一种制备复合材料的方法，包括使第一反应性基团与增强材料和聚合物基质材料中的一者或两者官能化，提供能够与第一反应性基团进行狄尔斯 - 阿尔德反应的第二反应基团，并使第一和 还描述了形成复合材料的第二反应性基团。
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公开(公告)号：US08785547B2
公开(公告)日：2014-07-22
申请号：US13990360
申请日：2011-11-07
IPC分类号： C08F120/40 , C08F222/40 , C08L31/02 , C08L67/06 , C08F269/00 , C08F8/44
CPC分类号： C08K5/1515 , C08F8/44 , C08F120/40 , C08F222/40 , C08F269/00 , C08K3/013 , C08K5/101 , C08L31/02 , C08L67/06 , C11C3/04 , C11C3/08
摘要： Grafted triglycerides comprising an acrylated triglyceride grafted with a fatty acid residue containing 4 to 28 carbon atoms. Also described are methods for making a grafted triglyceride and for curing a material selected from vinyl esters and unsaturated polyesters and mixtures thereof and optionally a reactive diluent. The method includes the steps of mixing a grafted triglyceride of the present invention with a material selected from vinyl esters, unsaturated polyesters and mixtures thereof to form a mixture, and curing the mixture to form a cured resin system. A cured resin system comprising a cured product obtained by the foregoing method and composites containing the cured product and a filler or reinforcing material are also disclosed. This method also includes use of the grafted triglycerides to make toughened resin and composite systems with reduced hazardous air pollutants without significantly reducing the glass transition temperature and significantly increasing the viscosity.
摘要翻译： 接枝甘油三酸酯，其包含用含有4至28个碳原子的脂肪酸残基接枝的丙烯酸酯化的甘油三酯。 还描述了制备接枝甘油三酯和固化选自乙烯基酯和不饱和聚酯及其混合物和任选的反应性稀释剂的材料的方法。 该方法包括将本发明的接枝甘油三酯与选自乙烯基酯，不饱和聚酯及其混合物的材料混合以形成混合物，并固化该混合物以形成固化的树脂体系的步骤。 还公开了包含通过上述方法获得的固化产物和含有固化产物和填料或增强材料的复合材料的固化树脂体系。 该方法还包括使用接枝的甘油三酯来制造具有减少的有害空气污染物的增韧树脂和复合体系，而不显着降低玻璃化转变温度并显着提高粘度。
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公开(公告)号：US20130253127A1
公开(公告)日：2013-09-26
申请号：US13990360
申请日：2011-11-07
IPC分类号： C08F120/40 , C08L31/02
CPC分类号： C08K5/1515 , C08F8/44 , C08F120/40 , C08F222/40 , C08F269/00 , C08K3/013 , C08K5/101 , C08L31/02 , C08L67/06 , C11C3/04 , C11C3/08
摘要： Grafted triglycerides comprising an acrylated triglyceride grafted with a fatty acid residue containing 4 to 28 carbon atoms. Also described are methods for making a grafted triglyceride and for curing a material selected from vinyl esters and unsaturated polyesters and mixtures thereof and optionally a reactive diluent. The method includes the steps of mixing a grafted triglyceride of the present invention with a material selected from vinyl esters, unsaturated polyesters and mixtures thereof to form a mixture, and curing the mixture to form a cured resin system. A cured resin system comprising a cured product obtained by the foregoing method and composites containing the cured product and a filler or reinforcing material are also disclosed. This method also includes use of the grafted triglycerides to make toughened resin and composite systems with reduced hazardous air pollutants without significantly reducing the glass transition temperature and significantly increasing the viscosity.
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