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1.发明授权2-(alkylcarbonyloxy)-1, 1-difluoroethanesulfonic acid salt and method for producing the same 有权2-（烷基羰氧基）-1,1-二氟乙磺酸盐及其制备方法公开(公告)号：US08581009B2
公开(公告)日：2013-11-12
申请号：US12678250
申请日：2008-09-05
IPC分类号： C07C31/34
CPC分类号： C07C309/17 , C07C29/147 , C07C67/08 , C07C67/14 , C07C303/32 , C07C309/08 , C07C309/12 , C07C313/04 , C07C381/12 , C07C2602/42 , C07C2603/74 , G03F7/0045 , G03F7/0046 , C07C31/34 , C07C69/653 , C07C69/63 , C07C69/753
摘要： By using an organic base when a carboxylic acid bromodifluoroethyl ester is sulfinated by using a sulfinating agent, there is obtained 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfinic acid ammonium salt. By oxidizing the 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfinic acid ammonium salt, there is obtained 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfonic acid ammonium salt. By using the 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfonic acid ammonium salt as a raw material and exchanging it into an onium salt directly or through saponification/esterification, there can be obtained a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid onium salt.
摘要翻译： 通过使用硫酸化剂将羧酸溴二氟乙酯磺化时，通过使用有机碱，得到2-（烷基羰氧基）-1,1-二氟乙烷亚磺酸铵盐。 通过氧化2-（烷基羰基氧基）-1,1-二氟乙烷亚磺酸铵盐，得到2-（烷基羰氧基）-1,1-二氟乙磺酸铵盐。 通过使用2-（烷基羰氧基）-1,1-二氟乙磺酸铵盐作为原料，直接或通过皂化/酯化将其交换为鎓盐，可以得到2-烷基羰基氧基-1,1-二氟乙磺酸 盐盐
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2.发明申请Processes for Production of 2-Bromo-2,2-Difluoroethanol and 2-(Alkylcarbonyloxy)-1, 1-Difluoroethanesulfonic Acid Salt 有权制备2-溴-2,2-二氟乙醇和2-（烷基羰氧基）-1,1-二氟乙磺酸盐的方法公开(公告)号：US20110319652A1
公开(公告)日：2011-12-29
申请号：US13223605
申请日：2011-09-01
IPC分类号： C07C69/54
CPC分类号： C07C309/17 , C07C29/147 , C07C67/08 , C07C67/14 , C07C303/32 , C07C309/08 , C07C309/12 , C07C313/04 , C07C381/12 , C07C2602/42 , C07C2603/74 , G03F7/0045 , G03F7/0046 , C07C31/34 , C07C69/653 , C07C69/63 , C07C69/753
摘要： Disclosed is a process for producing 2-bromo-2,2-difluoroethanol, which comprises reducing a bromodifluoroacetic acid derivative represented by the formula [1] by using an ate hydride complex as a reducing agent. 2-Bromo-2,2-difluoroethanol thus produced can be used as the starting material to carry out the esterification step, the sulfination step and the oxidation step in this order, thereby producing a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid salt, wherein A represents a substituted or unsubstituted linear, branched or cyclic alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 15 carbon atoms, a heteroaryloxy group having 4 to 15 carbon atoms, or a halogen atom.
摘要翻译： 公开了一种2-溴-2,2-二氟乙醇的制备方法，其包括使用氢化物络合物作为还原剂还原式[1]表示的溴二氟乙酸衍生物。 可以使用如此制备的2-溴-2,2-二氟乙醇作为起始原料，依次进行酯化步骤，硫化步骤和氧化步骤，由此制备2-烷基羰基氧基-1,1-二氟乙磺酸盐 其中A表示取代或未取代的具有1至20个碳原子的直链，支链或环状烷氧基，取代或未取代的碳原子数6〜15的芳氧基，碳原子数4〜15的杂芳氧基或卤素原子。
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3.发明申请2-(Alkylcarbonyloxy)-1, 1-Difluoroethanesulfonic Acid Salt and Method for Producing the Same 有权2-（烷基羰氧基）-1,1-二氟乙磺酸盐及其制备方法公开(公告)号：US20110034721A1
公开(公告)日：2011-02-10
申请号：US12678250
申请日：2008-09-05
IPC分类号： C07C69/74
CPC分类号： C07C309/17 , C07C29/147 , C07C67/08 , C07C67/14 , C07C303/32 , C07C309/08 , C07C309/12 , C07C313/04 , C07C381/12 , C07C2602/42 , C07C2603/74 , G03F7/0045 , G03F7/0046 , C07C31/34 , C07C69/653 , C07C69/63 , C07C69/753
摘要： By using an organic base when a carboxylic acid bromodifluoroethyl ester is sulfinated by using a sulfinating agent, there is obtained 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfinic acid ammonium salt. By oxidizing the 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfinic acid ammonium salt, there is obtained 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfonic acid ammonium salt. By using the 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfonic acid ammonium salt as a raw material and exchanging it into an onium salt directly or through saponification/esterification, there can be obtained a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid onium salt.
摘要翻译： 通过使用硫酸化剂将羧酸溴二氟乙酯磺化时，通过使用有机碱，得到2-（烷基羰氧基）-1,1-二氟乙烷亚磺酸铵盐。 通过氧化2-（烷基羰基氧基）-1,1-二氟乙烷亚磺酸铵盐，得到2-（烷基羰氧基）-1,1-二氟乙磺酸铵盐。 通过使用2-（烷基羰氧基）-1,1-二氟乙磺酸铵盐作为原料，直接或通过皂化/酯化将其交换为鎓盐，可以得到2-烷基羰基氧基-1,1-二氟乙磺酸 盐盐
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4.发明申请Processes for Production of 2-Bromo-2,2-Difluoroethanol and 2-(Alkylcarbonyloxy)-1,1-Difluoroethanesulfonic Acid Salt 有权制备2-溴-2,2-二氟乙醇和2-（烷基羰基氧基）-1,1-二氟乙磺酸盐的方法公开(公告)号：US20110015431A1
公开(公告)日：2011-01-20
申请号：US12678223
申请日：2008-09-05
IPC分类号： C07C67/16 , C07C309/08 , C07C309/10 , C07C29/143
CPC分类号： C07C309/17 , C07C29/147 , C07C67/08 , C07C67/14 , C07C303/32 , C07C309/08 , C07C309/12 , C07C313/04 , C07C381/12 , C07C2602/42 , C07C2603/74 , G03F7/0045 , G03F7/0046 , C07C31/34 , C07C69/653 , C07C69/63 , C07C69/753
摘要： Disclosed is a process for producing 2-bromo-2,2-difluoroethanol, which comprises reducing a bromodifluoroacetic acid derivative represented by the formula [1] by using an ate hydride complex as a reducing agent. 2-Bromo-2,2-difluoroethanol thus produced can be used as the starting material to carry out the esterification step, the sulfination step and the oxidation step in this order, thereby producing a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid salt, wherein A represents a substituted or unsubstituted linear, branched or cyclic alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 15 carbon atoms, a heteroaryloxy group having 4 to 15 carbon atoms, or a halogen atom.
摘要翻译： 公开了一种2-溴-2,2-二氟乙醇的制备方法，其包括使用氢化物络合物作为还原剂还原式[1]表示的溴二氟乙酸衍生物。 可以使用如此制备的2-溴-2,2-二氟乙醇作为起始原料，依次进行酯化步骤，硫化步骤和氧化步骤，由此制备2-烷基羰基氧基-1,1-二氟乙磺酸盐 其中A表示取代或未取代的具有1至20个碳原子的直链，支链或环状烷氧基，取代或未取代的碳原子数6〜15的芳氧基，碳原子数4〜15的杂芳氧基或卤素原子。
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5.发明授权Processes for production of 2-bromo-2,2-difluoroethanol and 2-(alkylcarbonyloxy)-1, 1-difluoroethanesulfonic acid salt 有权制备2-溴-2,2-二氟乙醇和2-（烷基羰氧基）-1,1-二氟乙磺酸盐的方法公开(公告)号：US08222448B2
公开(公告)日：2012-07-17
申请号：US13223605
申请日：2011-09-01
IPC分类号： C07C69/54
CPC分类号： C07C309/17 , C07C29/147 , C07C67/08 , C07C67/14 , C07C303/32 , C07C309/08 , C07C309/12 , C07C313/04 , C07C381/12 , C07C2602/42 , C07C2603/74 , G03F7/0045 , G03F7/0046 , C07C31/34 , C07C69/653 , C07C69/63 , C07C69/753
摘要： Disclosed is a process for producing 2-bromo-2,2-difluoroethanol, which comprises reducing a bromodifluoroacetic acid derivative represented by the formula [1] by using an ate hydride complex as a reducing agent. 2-Bromo-2,2-difluoroethanol thus produced can be used as the starting material to carry out the esterification step, the sulfination step and the oxidation step in this order, thereby producing a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid salt, wherein A represents a substituted or unsubstituted linear, branched or cyclic alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 15 carbon atoms, a heteroaryloxy group having 4 to 15 carbon atoms, or a halogen atom.
摘要翻译： 公开了一种2-溴-2,2-二氟乙醇的制备方法，其包括使用氢化物络合物作为还原剂还原式[1]表示的溴二氟乙酸衍生物。 可以使用如此制备的2-溴-2,2-二氟乙醇作为起始原料，依次进行酯化步骤，硫化步骤和氧化步骤，由此制备2-烷基羰基氧基-1,1-二氟乙磺酸盐 其中A表示取代或未取代的具有1至20个碳原子的直链，支链或环状烷氧基，取代或未取代的碳原子数6〜15的芳氧基，碳原子数4〜15的杂芳氧基或卤素原子。
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6.发明授权Processes for production of 2-bromo-2,2-difluoroethanol and 2-(alkylcarbonyloxy)-1,1-difluoroethanesulfonic acid salt 有权制备2-溴-2,2-二氟乙醇和2-（烷基羰基氧基）-1,1-二氟乙磺酸盐的方法公开(公告)号：US08110711B2
公开(公告)日：2012-02-07
申请号：US12678223
申请日：2008-09-05
IPC分类号： C07C29/143 , C07C67/16 , C07C309/08 , C07C309/10
CPC分类号： C07C309/17 , C07C29/147 , C07C67/08 , C07C67/14 , C07C303/32 , C07C309/08 , C07C309/12 , C07C313/04 , C07C381/12 , C07C2602/42 , C07C2603/74 , G03F7/0045 , G03F7/0046 , C07C31/34 , C07C69/653 , C07C69/63 , C07C69/753
摘要： Disclosed is a process for producing 2-bromo-2,2-difluoroethanol, which comprises reducing a bromodifluoroacetic acid derivative represented by the formula [1] by using an ate hydride complex as a reducing agent. 2-Bromo-2,2-difluoroethanol thus produced can be used as the starting material to carry out the esterification step, the sulfination step and the oxidation step in this order, thereby producing a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid salt, wherein A represents a substituted or unsubstituted linear, branched or cyclic alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 15 carbon atoms, a heteroaryloxy group having 4 to 15 carbon atoms, or a halogen atom.
摘要翻译： 公开了一种2-溴-2,2-二氟乙醇的制备方法，其包括使用氢化物络合物作为还原剂还原式[1]表示的溴二氟乙酸衍生物。 可以使用如此制备的2-溴-2,2-二氟乙醇作为起始原料，依次进行酯化步骤，硫化步骤和氧化步骤，由此制备2-烷基羰基氧基-1,1-二氟乙磺酸盐 其中A表示取代或未取代的具有1至20个碳原子的直链，支链或环状烷氧基，取代或未取代的碳原子数6〜15的芳氧基，碳原子数4〜15的杂芳氧基或卤素原子。
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公开(公告)号：US07956142B2
公开(公告)日：2011-06-07
申请号：US12514168
申请日：2007-11-09
申请人： Tomoki Nagai , Takuma Ebata , Makoto Shimizu , Jonathan Joachim Jodry , Satoru Narizuka , Masaki Fujiwara
发明人： Tomoki Nagai , Takuma Ebata , Makoto Shimizu , Jonathan Joachim Jodry , Satoru Narizuka , Masaki Fujiwara
IPC分类号： C08F128/02
CPC分类号： C07C309/12 , C07C381/12 , C08F20/38 , G03F7/0045 , G03F7/0046 , G03F7/0392
摘要： A resin that includes a repeating unit shown by the following formula (10) has an excellent performance as a radiation sensitive acid generator, and exhibits only a small adverse effect on the environment and a human body. wherein R1 represents a hydrogen atom or the like, M+ represents a specific cation, and n is an integer from 1 to 5.
摘要翻译： 包含下式（10）所示的重复单元的树脂作为辐射敏感性酸发生剂具有优异的性能，并且对环境和人体仅表现出小的不利影响。 其中R1表示氢原子等，M +表示特定阳离子，n为1至5的整数。
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公开(公告)号：US20100063232A1
公开(公告)日：2010-03-11
申请号：US12514168
申请日：2007-11-09
申请人： Tomoki Nagai , Takuma Ebata , Makoto Shimizu , Jonathan Joachim Jodry , Satoru Narizuka , Masaki Fujiwara
发明人： Tomoki Nagai , Takuma Ebata , Makoto Shimizu , Jonathan Joachim Jodry , Satoru Narizuka , Masaki Fujiwara
IPC分类号： C08F28/02 , C07C69/533
CPC分类号： C07C309/12 , C07C381/12 , C08F20/38 , G03F7/0045 , G03F7/0046 , G03F7/0392
摘要： A resin that includes a repeating unit shown by the following formula (10) has an excellent performance as a radiation sensitive acid generator, and exhibits only a small adverse effect on the environment and a human body. wherein R1 represents a hydrogen atom or the like, M+ represents a specific cation, and n is an integer from 1 to 5.
摘要翻译： 包含下式（10）所示的重复单元的树脂作为辐射敏感性酸发生剂具有优异的性能，并且对环境和人体仅表现出小的不利影响。 其中R1表示氢原子等，M +表示特定阳离子，n为1至5的整数。
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公开(公告)号：US07414148B2
公开(公告)日：2008-08-19
申请号：US11923197
申请日：2007-10-24
IPC分类号： C07C309/57 , C07C309/19
CPC分类号： C07C313/04 , C07C303/02 , C07C303/32 , C07C381/12 , C07C2603/74 , C07C309/17
摘要： A process for producing an alkoxycarbonylfluoroalkanesulfonate represented by the formula [1] is provided. This process includes the steps of (a) reacting a halofluoroalkanoate represented by the formula [2], with a sulfinating agent, thereby obtaining an alkoxycarbonylfluoroalkanesulfinate represented by the formula [3]; and (b) reacting the alkoxycarbonylfluoroalkanesulfinate with an oxidizing agent, thereby obtaining the target alkoxycarbonylfluoroalkanesulfonate. Furthermore, it is possible to react the obtained alkoxycarbonylfluoroalkanesulfonate with a monovalent onium salt to conduct a salt exchange, thereby obtaining a alkoxycarbonylfluoroalkanesulfonic acid onium salt represented by the formula [4].
摘要翻译： 提供由式[1]表示的制备烷氧基羰基氟烷基磺酸盐的方法。 该方法包括以下步骤：（a）使由式[2]表示的卤氟烷酸酯与硫酸化剂反应，从而得到由式[3]表示的烷氧基羰基氟烷基亚磺酸酯。 和（b）使烷氧基羰基氟亚烷基亚磺酸酯与氧化剂反应，从而得到目标烷氧基羰基氟烷基磺酸酯。 此外，可以使所得到的烷氧基羰基氟烷基磺酸盐与单价鎓盐进行盐交换，从而得到由式[4]表示的烷氧基羰基氟烷基磺酸鎓盐。
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10.发明授权Sulfonic acid salt and derivative thereof, photo-acid generator, and process for production of sulfonic acid salt 有权磺酸盐及其衍生物，光酸发生剂，以及磺酸盐的制备方法公开(公告)号：US08889888B2
公开(公告)日：2014-11-18
申请号：US13000643
申请日：2009-07-06
IPC分类号： C07D209/96 , C07C309/70 , C07C303/22 , C07D311/78 , C07D333/46 , G03F7/039 , C07C381/12 , C07D335/02 , C07C309/82 , G03F7/004 , C07C309/12 , C07C25/18 , C07D209/76
CPC分类号： C07C381/12 , C07C25/18 , C07C303/22 , C07C309/12 , C07C309/82 , C07C2603/74 , C07D209/76 , C07D311/78 , C07D333/46 , C07D335/02 , G03F7/0045 , G03F7/0046 , G03F7/0397
摘要： A fluorine-containing sulfonic acid salt or a compound having a fluorine-containing sulfonic acid group, either of which having a structure represented by the following general formula (1), is provided. Such a salt or compound can act as a suitable photo-acid generator, and can form a resist pattern having excellent sensitivity, resolution and mask-dependence. [In general formula (1), R represents a substituted or unsubstituted linear or branched monovalent hydrocarbon group having 1 to 30 carbon atoms, a substituted or unsubstituted monovalent hydrocarbon group having 3 to 30 carbon atoms and a cyclic or a partially cyclic structure, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted monovalent heterocyclic organic group having 4 to 30 carbon atoms.]
摘要翻译： 提供含氟磺酸盐或具有含氟磺酸基的化合物，其具有由以下通式（1）表示的结构。 这样的盐或化合物可以用作合适的光酸发生剂，并且可以形成具有优异的灵敏度，分辨率和掩模依赖性的抗蚀剂图案。 [通式（1）中，R表示取代或未取代的碳原子数1〜30的直链或支链一价烃基，取代或未取代的碳原子数3〜30的一价烃基和环状或部分环状结构， 取代或未取代的碳原子数为6〜30的芳基，取代或未取代的碳原子数为4〜30的1价杂环有机基。
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