摘要:
A hyperbranched polymer synthesizing method employs living radical polymerization of a monomer in the presence of a metal catalyst. The method includes forming a shell portion by introducing an acid-decomposable group to a core portion formed of a hyperbranched polymer synthesized by living radical polymerization; forming an acid group by partially decomposing the acid-decomposable group by an acid catalyst; precipitating a core-shell hyperbranched polymer contained in a first solution and having the acid group, by mixing the first solution with ultrapure water; and extracting, from a mixed solution into an organic solvent by liquid-liquid extraction, the core-shell hyperbranched polymer having the acid group, wherein the mixed solution contains a second solution containing the core-shell hyperbranched polymer precipitated at the precipitating and dissolved into the organic solvent, and the ultrapure water of an amount yielding a prescribed ratio of the ultrapure water relative to the organic solvent in the second solution.
摘要:
The present invention provides a hyperbranched polymer suitable as a polymer material for nanofabrication, in particular, photolithography. The hyperbranched polymer of the present invention is characterized by having a core portion prepared by a living radical polymerization of chloromethyl styrene or the like, and an acid decomposition group such as p-tert-butoxy styrene, which is linked to the core portion and present at the end of a molecule of the polymer.
摘要:
A method of synthesizing a hyperbranched polymer by living radical polymerization of a monomer in the presence of a metal catalyst includes at least adding a compound or setting the amount of the monomer in the living radical polymerization. The compound added is at least a compound represented by R1-A or a compound represented by R2—B—R3, where R1 denotes hydrogen, an alkyl group (1-10 carbons), aryl group (1-10 carbons), or aralkyl group (7-10 carbons), A denotes a cyano group, hydroxyl group, or nitro group, R2 and R3 denote hydrogen, alkyl groups (1-10 carbons), aryl groups (6-10 carbons), aralkyl groups (7-10 carbons), or dialkylamino groups (2-10 carbons), and B denotes a carbonyl group or sulfonyl group. Setting of the monomer amount includes setting the amount of monomer to be mixed into a reaction system at one mixing to be less than the total monomer to be mixed with the reaction system.
摘要:
The present invention provides a hyperbranched polymer that is capable of being used as a polymer material for nanofabrication including lithography, has enhanced dry etching resistance, sensitivity and surface smoothness, has a core shell structure and has an acid degradable repeating unit of tert-butyl vinylbenzoate ester in a shell portion, and a resist composition containing the hyperbranched polymer.
摘要:
The degassing apparatus removes liquid from a vacuum tank (1) with a suction pump (6) and supplies that liquid to a storage tank (9), sprays storage tank liquid into the vacuum tank through a convergent nozzle (7), removes gas from liquid in a state of reduced pressure inside the vacuum tank, and stores the degassed liquid in the storage tank. The storage tank is an airtight hermetically sealed tank provided with a reduced pressure retaining valve that discharges gas accumulated inside the storage tank.
摘要:
A packaging object supplying apparatus for supplying a packaging object to a packaging unit for packaging the packaging object into a predetermined fashion and specifically, a packaging object supplying apparatus comprising a packaging object combining portion for forming a combination of the packaging objects by combining two or more kinds of the packaging objects by a predetermined quantity in a predetermined array and a packaging object introducing portion for introducing the packaging objects combined by the packaging object combining portion to the packaging unit, a boxing apparatus comprising foldable box body supplying means, opening forming means, box body holding means, packaging object loading means, and lid forming means, a box body supplying apparatus for supplying a box body to the boxing apparatus.
摘要:
A braking control system includes an object detector, a host vehicle speed sensor, and a control unit configured to be electronically connected to at least the object detector and the host vehicle speed sensor for automatically controlling, depending on a host vehicle speed and a relative distance, a braking force needed for an automatic braking operation, containing preliminary braking control and supplementary braking control, without driver's braking action when a host vehicle is approaching a frontally positioned object. The control unit detects the presence or absence of a driver's intention for lane-changing. In the presence of the driver's intention for lane-changing, the preliminary braking control initiated prior to the driver's braking action is inhibited or the degree of limitation on the supplementary braking control, through which a value of a controlled quantity is brought closer to a target deceleration rate needed for collision-avoidance, is reduced.
摘要:
A traction control system is associated with a vehicular brake system which can control braking force for respective individual driving wheel independently of each other on the basis of an average wheel slippage data. The average wheel slippage data is derived introducing weighing technology giving higher weight for wheel slippage on a driving wheel, on which occurring smaller wheel slippage in comparison with the other. The traction control performs control of application of braking force for respective driving wheel independently of each other so that wheel traction recovering efficiency at respective driving wheel can be optimized.
摘要:
A first solution is mixed and diluted with diluting liquid to make a first dilute solution, a second solution is mixed and diluted with diluting liquid to make a second dilute solution, and the first dilute solution and second dilute solution, both diluted with diluting liquid, are mixed in a sealed tank.
摘要:
A choke valve is controlled finely suited to the running state of an engine. A throttle valve 8 and a choke valve 9 are provided in series on an intake pipe 6, and the opening degree of the choke valve 9 is controlled by a stepping motor. The choke valve opening degree upon start of engine (start opening degree) is determined depending on the engine temperature. The stepping motor 11 is initialized at the fully closed side of the choke valve 9 when the power source for starting the engine is turned on. The start opening degree of the choke valve is judged to be closer to the fully closed side or fully opened side, and the stepping motor 11 is initialized at the fully closed side if judged to be close to the fully closed side, and at the fully opened side if at the fully opened side.