Olefinically unsaturated phosphonate compounds, polymers made therefrom and their use
    1.
    发明授权
    Olefinically unsaturated phosphonate compounds, polymers made therefrom and their use 有权
    烯属不饱和膦酸酯化合物,由其制成的聚合物及其用途

    公开(公告)号:US09187503B2

    公开(公告)日:2015-11-17

    申请号:US13125074

    申请日:2009-10-06

    摘要: This invention relates to compounds of formulae (1a) and (1b) wherein R means H or C1- to C6-alkyl, X is a structural unit selected from the formulae  wherein m and k mean independently from each other a number from 1 to 12 for (4) and (5) and from 1 to 11 for (6), Y is a structural unit selected from the formulae wherein a, b independently from each other are integers from 1 to 10 R means hydrogen or C1- to C6-alkyl R2 means an alkylene or alkylidene group having 1 to 6 carbon atoms or an arylene or alkylarylene group having from 6 to 20 carbon atoms R3, R4, R5, R6 independently from each other mean an alkylene or alkylidene group having 1 to 6 carbon atoms or an arylene or alkylarylene group having from 6 to 20 carbon atoms, Z means a cation, and n means an integer being two or higher.

    摘要翻译: 本发明涉及式(1a)和(1b)的化合物,其中R表示H或C 1至C 6烷基,X是选自下式的结构单元:其中m和k彼此独立地表示1-12 对于(4)和(5),对于(6)为1至11,Y为选自下式的结构单元:其中a,b彼此独立地为1至10的整数。R表示氢或C1-至C6- 烷基R2表示碳原子数为1〜6的亚烷基或亚烷基或碳原子数为6〜20的亚芳基或亚烷基,R 3,R 4,R 5,R 6相互独立地表示碳原子数为1〜6的亚烷基或亚烷基 或具有6〜20个碳原子的亚芳基或亚烷基亚芳基,Z表示阳离子,n表示2以上的整数。

    Process for preparing ethylenedialkylphosphinic acids, esters and salts by means of acetylene and use thereof
    2.
    发明授权
    Process for preparing ethylenedialkylphosphinic acids, esters and salts by means of acetylene and use thereof 有权
    通过乙炔制备乙二烷基次膦酸,酯和盐的方法及其用途

    公开(公告)号:US09181487B2

    公开(公告)日:2015-11-10

    申请号:US13140212

    申请日:2009-12-15

    摘要: A process for preparing ethylenedialkylphosphinic acids, ethylenedialkylphosphinic esters and ethylenedialkylphosphinic salts, wherein a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, its salt or ester (II), b) the resultant alkylphosphonous acid, its salt or ester (II) is reacted with an acetylenic compound (V) in the presence of a catalyst B, to give the ethylenedialkylphosphinic acid derivative (III), and the catalyst A comprises transition metals, transition-metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition-metal compound and at least one ligand, and the catalyst B comprises peroxide-forming compounds, peroxo compounds and/or azo compounds.

    摘要翻译: 制备亚乙基二烷基次膦酸,亚乙基二烷基次膦酸酯和亚乙基二烷基次膦酸盐的方法,其中a)次膦酸源(I)在催化剂A存在下与烯烃(IV)反应,得到烷基亚磷酸,其盐或酯(II) b)在催化剂B的存在下,使得到的烷基亚磷酸,其盐或酯(II)与炔属化合物(V)反应,得到乙二烷基次膦酸衍生物(III),催化剂A包含过渡金属, 由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属化合物和/或催化剂体系,催化剂B包含形成过氧化物的化合物,过氧化合物和/或偶氮化合物。

    Black Pigment Composition For Heat-Shielding Coating, Heat-Shielding Coating Using Same And Use Of Same For Shading And Coating
    3.
    发明申请
    Black Pigment Composition For Heat-Shielding Coating, Heat-Shielding Coating Using Same And Use Of Same For Shading And Coating 审中-公开
    用于隔热涂料的黑色颜料组合物,使用相同的遮光涂料和用于遮蔽和涂布的相同用途

    公开(公告)号:US20150307688A1

    公开(公告)日:2015-10-29

    申请号:US14440326

    申请日:2013-10-09

    摘要: Provided are a black pigment composition for heat-shielding coatings which exhibits high infrared radiation transmittance, facilitates adjustment of hue when it is mixed with a chromatic coating and a white coating since it approximates the hue of carbon black pigment in the case of not only a dark color but a light color as well, and is also advantageous in terms of weather resistance and cost; a heat-shielding coating based on the same; and a shading method. The black pigment composition for heat-shielding coatings includes a phthalocyanine blue pigment as a first pigment, a phthalocyanine green pigment as a second pigment, and at least one other chromatic pigment, wherein, regarding the amounts in parts by weight of the phthalocyanine blue pigment as Mb, the phthalocyanine green pigment as Mg, and the total of the at least one other chromatic pigment as Mn, Mb+Mg+Mn=100 and 20

    摘要翻译: 本发明提供一种黑色颜料组合物,其具有高的红外线辐射透射率,可有效调节与彩色涂料和白色涂料混合时的色调,因为它不仅适用于炭黑颜料的色调, 深色但浅色,并且在耐候性和成本方面也是有利的; 基于其的热屏蔽涂层; 和遮蔽方法。 用于热屏蔽涂料的黑色颜料组合物包括作为第一颜料的酞菁蓝颜料,作为第二颜料的酞菁绿颜料和至少一种其它彩色颜料,其中关于酞菁蓝颜料的重量份 作为Mb,作为Mg的酞菁绿色颜料,以及作为Mn,Mb + Mg + Mn = 100和20

    Waxy Oxidation Products Of Rice Bran
    5.
    发明申请
    Waxy Oxidation Products Of Rice Bran 有权
    米糠的蜡状氧化产物

    公开(公告)号:US20150247039A1

    公开(公告)日:2015-09-03

    申请号:US14436624

    申请日:2013-10-11

    IPC分类号: C08L91/06

    CPC分类号: C08L91/06 C11C3/006

    摘要: The invention relates to waxy oxidation products of rice bran, which are characterized by an acid number measured according to DIN ISO 2114 of at least 70 mg KOH/g, preferably at least 100 mg KOH/g, most preferably at least 140 mg KOH/g, and their use for producing synthetic ester waxes by esterification with one or more mono- or polyvalent alcohols.

    摘要翻译: 本发明涉及米糠的蜡状氧化产物,其特征在于根据DIN ISO 2114测量的酸值至少为70mg KOH / g,优选至少100mg KOH / g,最优选至少140mg KOH / 以及它们用一种或多种单价或多价醇酯化制备合成酯蜡的用途。

    Polyester
    6.
    发明申请
    Polyester 审中-公开
    聚酯

    公开(公告)号:US20150240029A1

    公开(公告)日:2015-08-27

    申请号:US14421963

    申请日:2013-08-14

    IPC分类号: C08G63/672

    摘要: The present invention relates to polyester that can be obtained by polymerization of a) terephtalacid dimethylester, and b) ethylene glycol, and c) 1,2-propylene glycol, and d) one or a plurality of polyethylene glycols having weight average molecular weights in the range of 1,000 to 2,000 g/mol, and e) one methyl polyethylene glycol having a weight average molecular weight in the range of 1,050 to 1,350 g/mol, f) either when a plurality of compounds having a reticulating effect and 3 to 6 functions that are enabled for polycondensation are present or absent. The polyester according to the invention can be used in an advantageous manner, e.g. to modify hydrophobic surfaces, which can be used, e.g., in paper recycling.

    摘要翻译: 本发明涉及通过a)对苯二甲酸二甲酯和b)乙二醇和c)1,2-丙二醇的聚合得到的聚酯,和d)一种或多种重均分子量的聚乙二醇 1000〜2000g / mol的范围,e)重均分子量为1050〜1350g / mol的一种甲基聚乙二醇,f)当具有网状效果的多种化合物和3〜6 可进行缩聚的功能存在或不存在。 根据本发明的聚酯可以以有利的方式使用,例如, 以修饰疏水性表面,其可以用于例如纸回收。

    Polyesters
    7.
    发明申请
    Polyesters 审中-公开
    聚酯

    公开(公告)号:US20150203630A1

    公开(公告)日:2015-07-23

    申请号:US14418703

    申请日:2013-07-24

    IPC分类号: C08G63/66 C08G63/78

    摘要: Polyesters according to the following formula (I) are described wherein R1 and R2 independently of one another are H3C—(OC2H4)n—(OC3H6)m wherein the —(OC2H4) groups and the —(OC3H6) groups are arranged blockwise and the block consisting of the —(OC3H6) groups is bound to a COO group or are HO—(C3H6) or HO—(C4H8), n is based on a molar average a number of from 40 to 50, m is based on a molar average a number of from 1 to 7, and a+b is based on a molar average a number of from 4 to 9. The polyesters have an advantageous stability in alkaline environment, possess a beneficial solubility and advantageously are clearly soluble in alkaline compositions such as alkaline heavy duty washing liquids and also possess advantageous soil release properties.

    摘要翻译: 描述根据下式(I)的聚酯,其中R1和R2彼此独立地是H3C-(OC2H4)n-(OC3H6)m,其中 - (OC2H4)基团和 - (OC3H6)基团以块状排列,并且 由 - (OC 3 H 6)基组成的嵌段与COO基团结合,或者是HO-(C 3 H 6)或HO-(C 4 H 8),n基于摩尔平均数40至50,m基于摩尔 平均数为1至7,a + b为摩尔平均数4至9。聚酯在碱性环境中具有有利的稳定性,具有有益的溶解性,有利地清楚地溶于碱性组合物 作为碱性重垢洗涤液体,并且还具有有利的去污性能。

    Composition For The Production Of Hydrophilic Polystyrene Material
    10.
    发明申请
    Composition For The Production Of Hydrophilic Polystyrene Material 有权
    用于生产亲水性聚苯乙烯材料的组合物

    公开(公告)号:US20150087735A1

    公开(公告)日:2015-03-26

    申请号:US14399812

    申请日:2013-04-17

    IPC分类号: C08L25/06 C08J3/22

    摘要: The invention relates to a composition Z comprising a component B1, a component B2, a component D, a component E and a component P, wherein the component B1 is a polyethylene glycol having a hydroxyl number of from 25 to 600 mg KOH/g and an average molecular weight of 200 to 4000 g/mol; the component B2 is a polyethylene glycol having a hydroxyl number of from 0.1 to 24 mg KOH/g and an average molecular weight of higher than 4000 to about 10,000,000 g/mol; the component D is an earth alkali carbonate, the component E is a phyllosilicate, and the component P is a polystyrene and/or an alloy thereof. Composition Z is suitable to increase the hydrophilic properties of processed solid or foamed polystyrene material, especially for making a film, sheet or food tray.

    摘要翻译: 本发明涉及包含组分B1,组分B2,组分D,组分E和组分P的组合物Z,其中组分B1是羟值为25至600mg KOH / g的聚乙二醇和 平均分子量为200〜4000g / mol; 组分B2是羟值为0.1至24mg KOH / g,平均分子量高于4000至约10,000,000g / mol的聚乙二醇; 组分D是碱土金属碳酸盐,组分E是页硅酸盐,组分P是聚苯乙烯和/或它们的合金。 组合物Z适于增加加工的固体或泡沫聚苯乙烯材料的亲水性,特别是用于制备薄膜,片材或食品托盘。