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    Partial combustion catalyst of palladium on a zirconia support and a process for using it
    2.
    发明授权
    Partial combustion catalyst of palladium on a zirconia support and a process for using it 失效
    钯在氧化锆载体上的部分燃烧催化剂及其使用方法

    公开(公告)号：US5405260A

    公开(公告)日：1995-04-11

    申请号：US97957

    申请日：1993-07-27

    申请人： Ralph A. Della Betta ,  Kazunori Tsurumi ,  Toru Shoji ,  Robert L. Garten

    发明人： Ralph A. Della Betta ,  Kazunori Tsurumi ,  Toru Shoji ,  Robert L. Garten

    IPC分类号： B01D53/86 ,  B01J23/38 ,  B01J23/44 ,  B01J37/02 ,  F23D21/00

    CPC分类号： B01D53/8628 ,  B01J23/38 ,  B01J23/44 ,  B01J37/0225 ,  F01N2330/02

    摘要： This invention is a catalyst comprising palladium on a support containing zirconium and a partial combustion process in which the fuel is partially combusted using that catalyst. The choice of catalysts and supports solves a problem dealing with the long term stability of palladium as a partial combustion catalyst. The catalyst structure is stable in operation, has a comparatively low operating temperature, has a low temperature a which oxidation begins, and yet is not susceptible to temperature "runaway". The combustion gas produced by the catalytic process typically is at a temperature below the autocombustive temperature and may be used at that temperature or it may be fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.

    摘要翻译： 本发明是一种催化剂，其包含在含有锆的载体上的钯和部分燃烧方法，其中使用该催化剂将燃料部分燃烧。 催化剂和载体的选择解决了作为部分燃烧催化剂的钯的长期稳定性的问题。 催化剂结构在运行中稳定，工作温度较低，氧化开始时温度低，而且不易受“失控”的影响。 通过催化过程产生的燃烧气体通常处于低于自燃温度的温度，并且可以在该温度下使用，或者可以将其供给到其他燃烧阶段，以进一步用于燃气轮机，炉，锅炉等。

    Graded palladium-containing partial combustion catalyst
    3.
    发明授权
    Graded palladium-containing partial combustion catalyst 失效
    分级含钯部分燃烧催化剂

    公开(公告)号：US5258349A

    公开(公告)日：1993-11-02

    申请号：US617973

    申请日：1990-11-26

    申请人： Ralph A. Dalla Betta ,  Kazunori Tsurumi ,  Toru Shoji

    发明人： Ralph A. Dalla Betta ,  Kazunori Tsurumi ,  Toru Shoji

    IPC分类号： B01J23/44 ,  B01J35/00 ,  F23C13/00 ,  B01J21/06 ,  B01J23/66 ,  B01J35/04

    CPC分类号： F23C13/00 ,  B01J23/44 ,  B01J35/0006

    摘要： This invention is a graded catalyst comprising palladium and also a partial combustion process in which the fuel is partially combusted using that catalyst. The catalyst utilizes a catalytic support structure suitable for high flow rates of combustible gas mixtures through it. The catalyst is situated on the support so that in the flowing gas stream a leading portion of the support has a higher combustion activity, such as by a higher concentration of catalytic metal, than has the trailing portion. The combination of graded catalyst and support provides a low "light off" temperature for the combustible gas (only a low preheat temperature is needed to cause the combustion reaction to begin) and yet does not cause "hot spots" to occur because of excess activity. The combustion gas produced by the catalytic process may be at a temperature below the adiabatic combustive temperature, may be used at that temperature, or fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.

    摘要翻译： 本发明是一种包含钯的分级催化剂，也是使用该催化剂将燃料部分燃烧的部分燃烧过程。 该催化剂使用适合于通过其的可燃气体混合物的高流速的催化支撑结构。 催化剂位于载体上，使得在流动的气流中，载体的引导部分具有比具有后部的更高的燃烧活性，例如通过较高浓度的催化金属。 分级催化剂和载体的组合为可燃气体提供低的“轻度关闭”温度（仅需要低预热温度才能使燃烧反应开始），并且不会由于过量的活性而引起“热点” 。 通过催化过程产生的燃烧气体可能处于低于绝热燃烧温度的温度，可以在该温度下使用，或者进料到其它燃烧阶段，以进一步用于燃气轮机，炉，锅炉等。

    Graded palladium-containing partial combustion catalyst and a process for using it
    5.
    发明授权
    Graded palladium-containing partial combustion catalyst and a process for using it 失效
    分级含钯部分燃烧催化剂及其使用方法

    公开(公告)号：US5248251A

    公开(公告)日：1993-09-28

    申请号：US856462

    申请日：1992-03-24

    申请人： Ralph A. Dalla Betta ,  Kazunori Tsurumi ,  Toru Shoji

    发明人： Ralph A. Dalla Betta ,  Kazunori Tsurumi ,  Toru Shoji

    IPC分类号： B01J23/44 ,  B01J35/00 ,  F23C13/00

    CPC分类号： F23C13/00 ,  B01J23/44 ,  B01J35/0006

    摘要： This invention is a graded catalyst comprising palladium and also a partial combustion process in which the fuel is partially combusted using that catalyst. The catalyst utilizes a catalytic support structure suitable for high flow rates of combustible gas mixtures through it. The catalyst is situated on the support so that in the flowing gas stream a leading portion of the support has a higher combustion activity, such as by a higher concentration of catalytic metal, than has the trailing portion. The combination of graded catalyst and support provides a low "light off" temperature for the combustible gas (only a low preheat temperature is needed to cause the combustion reaction to begin) and yet does not cause "hot spots" to occur because of excess activity. The combustion gas produced by the catalytic process may be at a temperature below the adiabatic combustive temperature, may be used at that temperature, or fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.

    摘要翻译： 本发明是一种包含钯的分级催化剂，也是使用该催化剂将燃料部分燃烧的部分燃烧过程。 该催化剂使用适合于通过其的可燃气体混合物的高流速的催化支撑结构。 催化剂位于载体上，使得在流动的气流中，载体的引导部分具有比具有后部的更高的燃烧活性，例如通过较高浓度的催化金属。 分级催化剂和载体的组合为可燃气体提供低的“轻度关闭”温度（仅需要低预热温度才能使燃烧反应开始），并且不会由于过量活性而引起“热点” 。 通过催化过程产生的燃烧气体可能处于低于绝热燃烧温度的温度，可以在该温度下使用，或者进料到其它燃烧阶段，以进一步用于燃气轮机，炉，锅炉等。

    Two stage process for combusting fuel mixtures
    7.
    发明授权
    Two stage process for combusting fuel mixtures 失效
    燃料混合物燃烧的两阶段过程

    公开(公告)号：US5183401A

    公开(公告)日：1993-02-02

    申请号：US618301

    申请日：1990-11-26

    申请人： Ralph A. Dalla Betta ,  Nobuyasu Ezawa ,  Kazunori Tsurumi ,  James C. Schlatter ,  Sarento G. Nickolas

    发明人： Ralph A. Dalla Betta ,  Nobuyasu Ezawa ,  Kazunori Tsurumi ,  James C. Schlatter ,  Sarento G. Nickolas

    IPC分类号： F23C6/04 ,  F23C13/00

    CPC分类号： F23C13/00 ,  F23C6/045 ,  F23C2900/13002

    摘要： This invention is a comparatively high pressure combustion process having a two stages in which a fuel is stepwise combusted using specific catalysts and catalytic structures and, optionally, having a final homogeneous combustion zone. The choice of catalysts and the use of specific structures, including those employing integral heat exchange, results in an overall catalyst structure which is stable due to its comparatively low temperature. The product combustion gas is at a temperature suitable for use in a gas turbine, furnace, boiler, or the like, but has low NO.sub.x content.

    摘要翻译： 本发明是具有两个阶段的比较高压的燃烧过程，其中使用特定催化剂和催化结构逐步燃烧燃料，并且任选地具有最终均匀的燃烧区。 催化剂的选择和特定结构的使用，包括采用整体热交换的结构，导致总体催化剂结构由于其相对较低的温度而稳定。 产品燃烧气体处于适用于燃气轮机，炉，锅炉等的温度，但NOx含量低。

    Electrically-heated combustion catalyst structure and method for start-up of a gas turbine using same
    8.
    发明授权
    Electrically-heated combustion catalyst structure and method for start-up of a gas turbine using same 失效
    电加热燃烧催化剂结构及使用其的燃气轮机起动方法

    公开(公告)号：US6109018A

    公开(公告)日：2000-08-29

    申请号：US688075

    申请日：1996-07-26

    申请人： Thomas Rostrup-Nielsen ,  Ralph A. Dalla Betta ,  Toru Shoji ,  Scott A. Magno ,  David K. Yee

    发明人： Thomas Rostrup-Nielsen ,  Ralph A. Dalla Betta ,  Toru Shoji ,  Scott A. Magno ,  David K. Yee

    IPC分类号： F01N3/20 ,  F01N3/28 ,  F23C13/00 ,  F23R3/40 ,  F02C7/26

    CPC分类号： F23R3/40 ,  F01N3/2013 ,  F01N3/2026 ,  F01N3/281 ,  F02C7/26 ,  F23C13/00 ,  F23C13/02 ,  F01N2330/323 ,  F01N2610/03 ,  F05D2220/76 ,  F05D2260/85 ,  F23D2206/10 ,  Y02T10/26

    摘要： This invention relates to an electrically-heated catalyst (EHC) and a start-up method of a gas turbine engine for combusting a hydrocarbonaceous fuel/oxygen-containing gas mixture using this electrically-heated catalyst. The catalytic structure is electrically heated to a predetermined temperature prior to start up of the turbine so as to reduce emissions during the start-up of the system. The EHC unit is a stacked or spirally wound layering of flat and corrugated thin metal foils which forms a plurality of axially-extending, longitudinal channels. The channels are preferably coated on one surface with a catalytic material, leaving the other surface free from the reaction to act as a heat sink, making the design an IHE (integral heat exchange) catalytic unit. The preferred embodiment of the EHC has electrodes outside of the fuel/oxygen-containing mixture stream, and uses electrical power having a predetermined voltage in the range of 100 to 200 volts to heat the unit. A method for using the EHC in the start-up of a gas turbine is also disclosed wherein an electrical power is applied to heat the EHC a predetermined temperature prior to the fuel/oxygen-containing mixture being introduced and may be left on for a certain period of time after the introduction of the fuel/oxygen-containing mixture. The EHC may be maintained at the desired predetermined temperature by modulating the applied voltage. The electrical power is terminated when any one of several conditions are met including when the heat of the catalytic reaction is sufficient to maintain the catalyst at its steady-state condition or when a certain period of time has elapsed.

    摘要翻译： 本发明涉及使用该电加热催化剂燃烧含烃燃料/含氧气体混合物的燃气涡轮发动机的电加热催化剂（EHC）和起动方法。 催化结构在涡轮启动之前被电加热至预定温度，以便在系统启动期间减少排放。 EHC单元是形成多个沿轴向延伸的纵向通道的平坦且波浪形的薄金属箔的层叠或螺旋卷绕的层。 通道优选在一个表面上用催化材料涂布，使另一个表面没有反应作为散热器，使得设计成为IHE（整体式热交换）催化单元。 EHC的优选实施例具有位于燃料/含氧混合物流之外的电极，并且使用具有在100至200伏特范围内的预定电压的电力来加热该单元。 还公开了在燃气轮机起动中使用EHC的方法，其中在引入燃料/含氧混合物之前施加电功率以将EHC加热到预定温度，并且可以保持一定的 在引入燃料/含氧混合物之后的时间段。 可以通过调制所施加的电压将EHC保持在所需的预定温度。 当满足几个条件中的任何一个时，电力终止，包括当催化反应的热量足以使催化剂保持在其稳定状态或当经过一定时间段时。

    Catalytic system for olefin oxidation to carbonyl products
    9.
    发明授权
    Catalytic system for olefin oxidation to carbonyl products 失效
    用于烯烃氧化成羰基产物的催化体系

    公开(公告)号：US5557014A

    公开(公告)日：1996-09-17

    申请号：US558202

    申请日：1995-11-16

    申请人： John H. Grate ,  David R. Hamm ,  Kenneth A. Klingman ,  Robert J. Saxton ,  Shannan J. Downey

    发明人： John H. Grate ,  David R. Hamm ,  Kenneth A. Klingman ,  Robert J. Saxton ,  Shannan J. Downey

    IPC分类号： B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07C29/141 ,  C07C45/28 ,  C07C45/30 ,  C07C45/35

    CPC分类号： B01J23/002 ,  B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07C45/28 ,  C07C45/30 ,  C12C11/02 ,  B01J2523/00

    摘要： The present invention provides aqueous catalyst solutions useful for oxidation of olefins to carbonyl products, comprising a palladium catalyst and a polyoxoacid or polyoxoanion oxidant comprising vanadium. It also provides processes for oxidation of olefins to carbonyl products, comprising contacting olefin with the aqueous catalyst solutions of the present invention. It also provides processes for oxidation of olefins to carbonyl products by dioxygen, comprising contacting olefin with the aqueous catalyst solutions of the present invention, and further comprising contacting dioxygen with the aqueous catalyst solutions. In certain aqueous catalyst solutions and related processes of the present invention, the solution has a hydrogen ion concentration greater than 0.10 mole per liter when essentially all of the oxidant is in its oxidized state. In other aqueous catalyst solution and related processes of the present invention, the solution is essentially free of sulfuric acid and sulfate ions.

    摘要翻译： 本发明提供了用于将烯烃氧化成羰基产物的含水催化剂溶液，其包含钯催化剂和包含钒的多氧酸或多氧阴离子氧化剂。 它还提供了将烯烃氧化成羰基产物的方法，包括使烯烃与本发明的含水催化剂溶液接触。 它还提供了通过双氧将烯烃氧化成羰基产物的方法，包括使烯烃与本发明的含水催化剂溶液接触，并且还包括使二氧化铈与含水催化剂溶液接触。 在本发明的某些水性催化剂溶液和相关方法中，当基本上所有的氧化剂都处于其氧化态时，溶液的氢离子浓度大于0.10摩尔/升。 在本发明的其它含水催化剂溶液和相关方法中，溶液基本上不含硫酸和硫酸根离子。

    Process and catalyst structure employing intergal heat exchange with optional downstream flameholder
    10.
    发明授权
    Process and catalyst structure employing intergal heat exchange with optional downstream flameholder 失效
    使用与可选择的下游阻燃器进行间隔热交换的工艺和催化剂结构

    公开(公告)号：US5518697A

    公开(公告)日：1996-05-21

    申请号：US378206

    申请日：1995-01-25

    申请人： Ralph A. Dalla Betta ,  David K. Yee ,  Scott A. Magno ,  Toru Shoji

    发明人： Ralph A. Dalla Betta ,  David K. Yee ,  Scott A. Magno ,  Toru Shoji

    IPC分类号： F01N3/10 ,  B01J23/40 ,  B01J35/04 ,  F01N3/28 ,  F23C6/04 ,  F23C9/00 ,  F23C13/00 ,  F23D11/40 ,  F23D14/18 ,  F23R3/40 ,  F23D3/40

    CPC分类号： F23C13/00 ,  F01N3/28 ,  F01N3/281 ,  F01N3/2814 ,  F01N3/2821 ,  F01N3/2882 ,  F23C6/045 ,  F23C9/006 ,  F23R3/40 ,  F01N2240/02 ,  F01N2330/321 ,  F01N2330/323 ,  F01N2330/42 ,  F23C2900/13002 ,  F23R2900/00002

    摘要： This invention is an improved catalyst structure and its use in highly exothermic processes like catalytic combustion. This improved catalyst structure employs integral heat exchange in an array of longitudinally disposed adjacent reaction passage-ways or channels, which are either catalyst-coated or catalyst-free, wherein the configuration of the catalyst-coated channels differs from the non-catalyst channels such that, when applied in exothermic reaction processes, such as catalytic combustion, the desired reaction is promoted in the catalytic channels and substantially limited in the non-catalyst channels. The invention further comprises an improved reaction system and process for combustion of a fuel wherein catalytic combustion using a catalyst structure employing integral heat exchange, preferably the improved structures of the invention, affords a partially-combusted, gaseous product which is passed to a homogeneous combustion zone where complete combustion is promoted by means of a flameholder.

    摘要翻译： 本发明是改进的催化剂结构及其在高度放热过程如催化燃烧中的应用。 这种改进的催化剂结构在纵向设置的相邻反应通道或通道的阵列中采用整体热交换，其是催化剂涂覆的或不含催化剂的，其中催化剂涂覆的通道的构型与非催化剂通道的构型不同， 当用于放热反应过程如催化燃烧时，在催化通道中促进所需的反应，并且在非催化剂通道中基本上受限制。 本发明还包括改进的燃料燃烧反应系统和方法，其中使用采用整体热交换的催化剂结构，优选本发明的改进结构的催化燃烧提供了部分燃烧的气态产物，其被传递到均匀燃烧 通过火焰稳定器促进完全燃烧的区域。