公开(公告)号：US06271169B1

公开(公告)日：2001-08-07

申请号：US09269211

申请日：1999-03-22

申请人： Kostantinos Kourtakis ,  John Donal Sullivan

发明人： Kostantinos Kourtakis ,  John Donal Sullivan

IPC分类号： B01J2328

CPC分类号： B01J23/8898 ,  B01J23/002 ,  B01J23/28 ,  B01J23/887 ,  B01J23/8872 ,  B01J23/8875 ,  B01J23/8877 ,  B01J23/8885 ,  B01J2523/00 ,  C07C51/215 ,  C07C57/145 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/32 ,  B01J2523/845 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/56 ,  B01J2523/69 ,  B01J2523/53 ,  B01J2523/31 ,  B01J2523/25 ,  B01J2523/11 ,  B01J2523/24 ,  B01J2523/54 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/72 ,  B01J2523/23 ,  B01J2523/67 ,  B01J2523/3743 ,  B01J2523/27 ,  B01J2523/3706

摘要： This invention concerns catalysts comprising a molybdenum compound of formula (I): VqMoAyOz, (II): NiMoxByOz′, (III): VNiwMoxCy′Oz″, (IV): CoNiwMoxDyOz′″, or (V): VNiwCOrMoxEyOz″″, wherein: A is at least one cation selected from the group consisting of cations of Cr, Sb, Co, Ce and Pb; B is at least one cation selected from the group consisting of cations of Sb, Al and W; C is at least one cation selected from the group consisting of cations of Fe, Zn, Al, Sb, Bi, W, Li, Ba, Nb and Sn; D is at least one cation selected from the group consisting of cations of Ba, Mn, Al, Sb, Sn and W; E is at least one cation selected from the group consisting of cations of Fe, Ca, Mn, Sr, Eu, La, Zr, Ga, Sn and Pb; q, r, w, x, y, y′, z, z′, z″, z′″ and z″″ are as defined in the disclosure. These catalysts can be used in C4 oxidation processes.

摘要翻译： 本发明涉及包含式（I）的钼化合物：VqMoAyOz，（II）：NiMoxByOz'，（III）：VNiwMoxCy'Oz“，（IV）：CoNiwMoxDyOz”“或（V）：VNiwCOrMoxEyOz” “，其中：A是选自Cr，Sb，Co，Ce和Pb的阳离子中的至少一种阳离子; B是选自Sb，Al和W的阳离子中的至少一种阳离子; C是选自Fe，Zn，Al，Sb，Bi，W，Li，Ba，Nb和Sn的阳离子中的至少一种阳离子; D是选自Ba，Mn，Al，Sb，Sn和W的阳离子中的至少一种阳离子; E是选自Fe，Ca，Mn，Sr，Eu，La，Zr，Ga，Sn和Pb的阳离子中的至少一种阳离子; q，r，w，x，y，y'，z，z'，z“，z”'和z“如本公开中所定义。 这些催化剂可用于C4氧化工艺。

公开(公告)号：US09433924B2

公开(公告)日：2016-09-06

申请号：US13508738

申请日：2010-11-08

申请人： Manhoe Kim ,  Steven O. Salley ,  K. Y. Simon Ng

发明人： Manhoe Kim ,  Steven O. Salley ,  K. Y. Simon Ng

IPC分类号： B01J21/06 ,  B01J21/08 ,  B01J23/00 ,  B01J23/06 ,  B01J23/10 ,  B01J23/80 ,  B01J37/03 ,  C11C3/00

CPC分类号： B01J21/066 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/10 ,  B01J23/80 ,  B01J37/031 ,  B01J37/036 ,  B01J2523/00 ,  C10G2300/1003 ,  C10G2300/1011 ,  C11C3/003 ,  Y02E50/13 ,  Y02P30/20 ,  B01J2523/27 ,  B01J2523/3725 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/48 ,  B01J2523/3743 ,  B01J2523/847 ,  B01J2523/3787

摘要： Mixed metal oxide catalysts (ZnO, CeO, La2O3, NiO, Al203, Si02, TiO2, Nd2O3, Yb2O3, or any combination of these) supported on zirconia (ZrO2) or hydrous zirconia are provided. These mixed metal oxide catalysts can be prepared via coprecipitation, impregnation, or sol-gel methods from metal salt precursors with/without a Zirconium salt precursor. Metal oxides/ZrO2 catalyzes both esterification and transesterification of oil containing free fatty acids in one batch or in single stage. In particular, these mixed metal oxides supported or added on zirconium oxide exhibit good activity and selectivity for esterification and transesterification. The low acid strength of this catalyst can avoid undesirable side reaction such as alcohol dehydration or cracking of fatty acids. Metal oxides/ZrO2 catalysts are not sensitive to any water generated from esterification. Thus, esterification does not require a water free condition or the presence of excess methanol to occur when using the mixed metal oxide catalyst. The FAME yield obtained with metal oxides/ZrO2 is higher than that obtained with homogeneous sulfuric acid catalyst. Metal oxides/ZrO2 catalasts can be prepared as strong pellets and in various shapes for use directly in a flow reactor. Furthermore, the pellet has a strong resistance toward dissolution to aqueous or oil phases.

摘要翻译： 提供负载在氧化锆（ZrO2）或含水氧化锆上的混合金属氧化物催化剂（ZnO，CeO，La2O3，NiO，Al2O3，SiO2，TiO2，Nd2O3，Yb2O3或它们的任意组合）。 这些混合金属氧化物催化剂可以通过共沉淀，浸渍或溶胶 - 凝胶法从具有/不具有锆盐前体的金属盐前体制备。 金属氧化物/ ZrO2催化一批或单一阶段含油游离脂肪酸的酯化和酯交换反应。 特别地，负载或添加到氧化锆上的这些混合金属氧化物表现出良好的酯化和酯交换活性和选择性。 该催化剂的低酸强度可以避免不希望的副反应，例如醇脱水或脂肪酸的裂解。 金属氧化物/ ZrO2催化剂对由酯化产生的任何水不敏感。 因此，当使用混合金属氧化物催化剂时，酯化不需要无水条件或过量甲醇的存在。 用金属氧化物/ ZrO2获得的FAME产率高于用均相硫酸催化剂获得的FAME产率。 金属氧化物/ ZrO 2催化剂可以制备成强颗粒，并且可以用于流动反应器中直接使用的各种形状。 此外，颗粒对水相或油相具有很强的溶解性。

公开(公告)号：US20080103325A1

公开(公告)日：2008-05-01

申请号：US11590153

申请日：2006-10-31

申请人： Claus Lugmair ,  Benjamin Mork ,  Jessica Zysk Fryer ,  Anthony F. Volpe ,  Joseph Peter Bartek ,  Hailian Li ,  Alakananda Bhattacharyya ,  James F. Brazdil ,  Bruce I. Rosen ,  Eric Moore

发明人： Claus Lugmair ,  Benjamin Mork ,  Jessica Zysk Fryer ,  Anthony F. Volpe ,  Joseph Peter Bartek ,  Hailian Li ,  Alakananda Bhattacharyya ,  James F. Brazdil ,  Bruce I. Rosen ,  Eric Moore

IPC分类号： C07C253/26

CPC分类号： C07C253/24 ,  B01J2523/00 ,  C07C255/08 ,  B01J2523/3756 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/68 ,  B01J2523/3725 ,  B01J2523/3737 ,  B01J2523/3706 ,  B01J2523/3718 ,  B01J2523/3743 ,  B01J2523/375 ,  B01J2523/3762 ,  B01J2523/3768 ,  B01J2523/3775 ,  B01J2523/3781 ,  B01J2523/3787 ,  B01J2523/3793 ,  B01J2523/3712 ,  B01J2523/11

摘要： A catalyst composition comprising molybdenum, vanadium, antimony niobium, at least one element select from the group consisting of titanium, tin, germanium, zirconium, and hafnium, and at least one lanthanide selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; with the proviso that catalyst contains germanium (in the absence of at last one of titanium, tin, zirconium, hafnium) only in combination with neodymium and/or praseodymium and no other lanthanides. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).

摘要翻译： 一种催化剂组合物，其包含钼，钒，锑铌，至少一种选自钛，锡，锗，锆和铪的元素，以及至少一种选自镧，镨，钕，钐的镧系元素 铕，钆，铽，镝，钬，铒，ium，镱和镥; 条件是催化剂仅与钕和/或镨组合而不与其他镧系元素结合使用锗（不存在钛，锡，锆，铪中的最后一种）。 这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。

公开(公告)号：US20030236432A1

公开(公告)日：2003-12-25

申请号：US10308900

申请日：2002-12-03

发明人： Kostantinos Kourtakis ,  John Donal Sullivan

IPC分类号： C07C051/16 ,  C07C029/48 ,  B01J021/12

CPC分类号： B01J23/8898 ,  B01J23/002 ,  B01J23/28 ,  B01J23/887 ,  B01J23/8872 ,  B01J23/8875 ,  B01J23/8877 ,  B01J23/8885 ,  B01J2523/00 ,  C07C51/215 ,  C07C57/145 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/32 ,  B01J2523/845 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/56 ,  B01J2523/69 ,  B01J2523/53 ,  B01J2523/31 ,  B01J2523/25 ,  B01J2523/11 ,  B01J2523/24 ,  B01J2523/54 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/72 ,  B01J2523/23 ,  B01J2523/67 ,  B01J2523/3743 ,  B01J2523/27 ,  B01J2523/3706

摘要： This invention concerns catalysts comprising a molybdenum compound of formula I, II, III, IV or VVqMoAyOznullnullINiMoxByOznullnullnullIIVNiwMoxCynullOznullnullnullIIICoNiwMoxDyOznullnullnullnullIVVNiwCorMoxEyOznullnullnullnullVwherein: A is at least one cation selected from the group consisting of cations of: Cr, Sb, Co, Ce and Pb; B is at least one cation selected from the group consisting of cations of: Sb, Al and W; C is at least one cation selected from the group consisting of cations of: Fe, Zn, Al, Sb, Bi, W, Li, Ba, Nb and Sn; D is at least one cation selected from the group consisting of cations of: Ba, Mn, Al, Sb, Sn, and W; E is at least one cation selected from the group consisting of cations of: Fe, Ca, Mn, Sr, Eu, La, Zr, Ga, Sn and Pb; q, r, w, x and y are each independently a number from 0.1 to 10 and ynull is a number from 0 to 10, z, znull, znull, znullnull, and znullnull are determined using the amounts and oxidation states of all cations present in each formula. These catalysts can be used in C4 oxidation processes, especially butane oxidation processes.

摘要翻译： 本发明涉及包含式I，II，III，IV的钼化合物或VVqMoAyOz INiMoxByOz'IIVNiwMoxCy'Oz“IIICoNiwMoxDyOz”IVVNiwCorMoxEyOz“'的催化剂，其中A是至少一种选自阳离子 ：Cr，Sb，Co，Ce和Pb; B是选自由Sb，Al和W的阳离子组成的组中的至少一种阳离子; C是选自Fe，Zn，Al，Sb，Bi，W，Li，Ba，Nb和Sn中的至少一种阳离子; D是选自Ba，Mn，Al，Sb，Sn和W的阳离子中的至少一种阳离子; E是选自Fe，Ca，Mn，Sr，Eu，La，Zr，Ga，Sn和Pb的阳离子中的至少一种阳离子; q，r，w，x和y各自独立地为0.1至10的数，y'为0至10的数，z，z'，z“，z”'和z“ 使用每种配方中存在的所有阳离子的量和氧化态确定。 这些催化剂可用于C4氧化工艺，特别是丁烷氧化工艺。

公开(公告)号：US09434659B2

公开(公告)日：2016-09-06

申请号：US14607871

申请日：2015-01-28

申请人： Battelle Memorial Institute

发明人： Michael A. Lilga ,  John G. Frye, Jr. ,  Suh-Jane Lee ,  Karl O. Albrecht

IPC分类号： C07C1/24 ,  C07C29/60 ,  B01J19/00 ,  C07C1/207 ,  C07C49/203 ,  C07C1/30

CPC分类号： C07C1/24 ,  B01J19/00 ,  B01J21/066 ,  B01J21/08 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J27/1806 ,  B01J37/031 ,  B01J37/04 ,  B01J37/086 ,  B01J37/088 ,  B01J2523/00 ,  B01J2523/33 ,  B01J2523/35 ,  B01J2523/3781 ,  B01J2523/48 ,  C07C1/2078 ,  C07C1/30 ,  C07C29/60 ,  C07C49/203 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2527/167 ,  C07C2529/40 ,  C07C2529/70 ,  C07C33/03 ,  C07C11/167 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/23 ,  B01J2523/3762 ,  B01J2523/3775 ,  B01J2523/3793 ,  B01J2523/27 ,  B01J2523/3743 ,  B01J2523/36 ,  B01J2523/25 ,  B01J2523/51 ,  B01J2523/11 ,  B01J2523/305 ,  B01J2523/22 ,  B01J2523/375 ,  B01J2523/3768 ,  B01J2523/3725 ,  B01J2523/3718 ,  B01J2523/3737 ,  B01J2523/3756 ,  B01J2523/3787 ,  B01J2523/3712 ,  B01J2523/68 ,  B01J2523/49 ,  B01J2523/69 ,  B01J2523/41

摘要： A composition comprising 2,3-butanediol is dehydrated to methyl vinyl carbinol and/or 1,3-butadiene by exposure to a catalyst comprising (a) MxOy wherein M is a rare earth metal, a group IIIA metal, Zr, or a combination thereof, and x and y are based upon an oxidation state of M, or (b) M3a(PO4)b where M3 is a group IA, a group IIA metal, a group IIIA metal, or a combination thereof, and a and b are based upon the oxidation state of M3. Embodiments of the catalyst comprising MxOy may further include M2, wherein M2 is a rare earth metal, a group IIA metal, Zr, Al, or a combination thereof. In some embodiments, 2,3-butanediol is dehydrated to methyl vinyl carbinol and/or 1,3-butadiene by a catalyst comprising MxOy, and the methyl vinyl carbinol is subsequently dehydrated to 1,3-butadiene by exposure to a solid acid catalyst.

摘要翻译： 将包含2,3-丁二醇的组合物通过暴露于包含（a）M x Oy的催化剂脱水成甲基乙烯基甲醇和/或1,3-丁二烯，其中M是稀土金属，IIIA族金属，Zr或组合 并且x和y基于M的氧化态，或（b）M3a（PO4）b，其中M3是IA族，IIA族金属，IIIA族金属或其组合，a和b 是基于M3的氧化态。 包含M x O y的催化剂的实施方案可以进一步包括M2，其中M2是稀土金属，IIA族金属，Zr，Al或它们的组合。 在一些实施方案中，通过包含M x O y的催化剂将2,3-丁二醇脱水成甲基乙烯基甲醇和/或1,3-丁二烯，然后通过暴露于固体酸催化剂将甲基乙烯基甲醇脱水为1,3-丁二烯 。

公开(公告)号：US20150218062A1

公开(公告)日：2015-08-06

申请号：US14607871

申请日：2015-01-28

申请人： Battelle Memorial Institute

发明人： Michael A. Lilga ,  John G. Frye, JR. ,  Suh-Jane Lee ,  Karl O. Albrecht

IPC分类号： C07C1/24 ,  C07C29/60

CPC分类号： C07C1/24 ,  B01J19/00 ,  B01J21/066 ,  B01J21/08 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J27/1806 ,  B01J37/031 ,  B01J37/04 ,  B01J37/086 ,  B01J37/088 ,  B01J2523/00 ,  B01J2523/33 ,  B01J2523/35 ,  B01J2523/3781 ,  B01J2523/48 ,  C07C1/2078 ,  C07C1/30 ,  C07C29/60 ,  C07C49/203 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2527/167 ,  C07C2529/40 ,  C07C2529/70 ,  C07C33/03 ,  C07C11/167 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/23 ,  B01J2523/3762 ,  B01J2523/3775 ,  B01J2523/3793 ,  B01J2523/27 ,  B01J2523/3743 ,  B01J2523/36 ,  B01J2523/25 ,  B01J2523/51 ,  B01J2523/11 ,  B01J2523/305 ,  B01J2523/22 ,  B01J2523/375 ,  B01J2523/3768 ,  B01J2523/3725 ,  B01J2523/3718 ,  B01J2523/3737 ,  B01J2523/3756 ,  B01J2523/3787 ,  B01J2523/3712 ,  B01J2523/68 ,  B01J2523/49 ,  B01J2523/69 ,  B01J2523/41

摘要： A composition comprising 2,3-butanediol is dehydrated to methyl vinyl carbinol and/or 1,3-butadiene by exposure to a catalyst comprising (a) MxOy wherein M is a rare earth metal, a group IIIA metal, Zr, or a combination thereof, and x and y are based upon an oxidation state of M, or (b) M3a(PO4)b where M3 is a group IA, a group IIA metal, a group IIIA metal, or a combination thereof, and a and b are based upon the oxidation state of M3. Embodiments of the catalyst comprising MxOy may further include M2, wherein M2 is a rare earth metal, a group IIA metal, Zr, Al, or a combination thereof. In some embodiments, 2,3-butanediol is dehydrated to methyl vinyl carbinol and/or 1,3-butadiene by a catalyst comprising MxOy, and the methyl vinyl carbinol is subsequently dehydrated to 1,3-butadiene by exposure to a solid acid catalyst.

摘要翻译： 将包含2,3-丁二醇的组合物通过暴露于包含（a）M x Oy的催化剂脱水成甲基乙烯基甲醇和/或1,3-丁二烯，其中M是稀土金属，IIIA族金属，Zr或组合 并且x和y基于M的氧化态，或（b）M3a（PO4）b，其中M3是IA族，IIA族金属，IIIA族金属或其组合，a和b 是基于M3的氧化态。 包含M x O y的催化剂的实施方案可以进一步包括M2，其中M2是稀土金属，IIA族金属，Zr，Al或它们的组合。 在一些实施方案中，通过包含M x O y的催化剂将2,3-丁二醇脱水成甲基乙烯基甲醇和/或1,3-丁二烯，然后通过暴露于固体酸催化剂将甲基乙烯基甲醇脱水为1,3-丁二烯 。

公开(公告)号：US20020049136A1

公开(公告)日：2002-04-25

申请号：US09878645

申请日：2001-06-11

发明人： Kostantinos Kourtakis ,  John Donal Sullivan

IPC分类号： B01J023/00 ,  C07D301/03

CPC分类号： B01J23/8898 ,  B01J23/002 ,  B01J23/28 ,  B01J23/887 ,  B01J23/8872 ,  B01J23/8875 ,  B01J23/8877 ,  B01J23/8885 ,  B01J2523/00 ,  C07C51/215 ,  C07C57/145 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/32 ,  B01J2523/845 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/56 ,  B01J2523/69 ,  B01J2523/53 ,  B01J2523/31 ,  B01J2523/25 ,  B01J2523/11 ,  B01J2523/24 ,  B01J2523/54 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/72 ,  B01J2523/23 ,  B01J2523/67 ,  B01J2523/3743 ,  B01J2523/27 ,  B01J2523/3706

摘要： This invention concerns catalysts comprising a molybdenum compound of formula I, II, III, IV or V I VqMoAyOz II NiMoxByOznullIII VNiwMoxCynullOznullIV CoNiwMoxDyOznullnullV VNiwCorMoxEyOznullnullwherein: A is at least one cation selected from the group consisting of cations of: Cr, Sb, Co, Ce and Pb; B is at least one cation selected from the group consisting of cations of: Sb, Al and W; C is at least one cation selected from the group consisting of cations of: Fe, Zn, Al, Sb, Bi, W, Li, Ba, Nb and Sn; D is at least one cation selected from the group consisting of cations of: Ba, Mn, Al, Sb, Sn, and W; E is at least one cation selected from the group consisting of cations of: Fe, Ca, Mn, Sr, Eu, La, Zr, Ga, Sn and Pb; q, r, w, x and y are each independently a number from 0.1 to 10 and ynull is a number from 0 to 10, z, znull, znull, znullnull, and znullnull are determined using the amounts and oxidation states of all cations present in each formula. These catalysts can be used in C4 oxidation processes, especially butane oxidation processes.

摘要翻译： 本发明涉及包含式I，II，III，IV或VI的钼化合物的催化剂，其中：A是至少一种选自以下的阳离子：阳离子，其选自 由Cr，Sb，Co，Ce和Pb阳离子组成的组; B是选自由Sb，Al和W的阳离子组成的组中的至少一种阳离子; C是选自Fe，Zn，Al，Sb，Bi，W，Li，Ba，Nb和Sn中的至少一种阳离子; D是选自Ba，Mn，Al，Sb，Sn和W的阳离子中的至少一种阳离子; E是选自Fe，Ca，Mn，Sr，Eu，La，Zr，Ga，Sn和Pb的阳离子中的至少一种阳离子; q，r，w，x和y各自独立地为0.1至10的数，y'为0至10的数，z，z'，z“，z”'和z“ 使用每种配方中存在的所有阳离子的量和氧化态确定。 这些催化剂可用于C4氧化工艺，特别是丁烷氧化工艺。

公开(公告)号：US20180021759A1

公开(公告)日：2018-01-25

申请号：US15546152

申请日：2016-01-26

申请人： GRIREM ADVANCED MATERIALS CO., LTD.

发明人： Xiaowei Huang ,  Qi Wang ,  Mei Yue ,  Qiang Zhong ,  Lei Wang ,  Yongke Hou ,  Meisheng Cui

IPC分类号： B01J23/83 ,  B01D53/86 ,  B01J23/10 ,  B01J23/34 ,  B01J35/08 ,  B01J37/02 ,  B01J35/00 ,  B01J35/10 ,  B01J37/04 ,  B01J37/03 ,  B01J37/00 ,  B01J37/10 ,  B01D53/94 ,  B01J35/06

CPC分类号： B01J23/83 ,  B01D53/86 ,  B01D53/94 ,  B01D2255/407 ,  B01J23/10 ,  B01J23/34 ,  B01J23/63 ,  B01J35/0013 ,  B01J35/026 ,  B01J35/06 ,  B01J35/08 ,  B01J35/1014 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/038 ,  B01J37/04 ,  B01J37/10 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/3725 ,  B01J2523/3706 ,  B01J2523/3718 ,  B01J2523/36 ,  B01J2523/72 ,  B01J2523/24 ,  B01J2523/17 ,  B01J2523/3756 ,  B01J2523/23 ,  B01J2523/3743 ,  B01J2523/847

摘要： Provided are a cerium-zirconium composite oxide, a preparation method therefor and application of a catalyst. The cerium-zirconium composite oxide has a composite phase structure, and comprises a cerium oxide phase and a cerium-zirconium solid solution phase, or consists of two or more cerium-zirconium solid solution phases with different crystal structures and different chemical compositions, wherein the chemical formula of the cerium-zirconium solid solution phase is CexZr1-x-yMyO2, where M is at least one selected from the group consisting of a rare earth element other than cerium, a transition metal element and an alkaline earth metal element, x is 15-85 mol %, and y is 0-20 mol %.

公开(公告)号：US20120283459A1

公开(公告)日：2012-11-08

申请号：US13508738

申请日：2010-11-08

申请人： Manhoe Kim ,  Steven O. Salley ,  K.Y. Simon Ng

发明人： Manhoe Kim ,  Steven O. Salley ,  K.Y. Simon Ng

IPC分类号： B01J21/06 ,  B01J21/08 ,  C11C3/10

CPC分类号： B01J21/066 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/10 ,  B01J23/80 ,  B01J37/031 ,  B01J37/036 ,  B01J2523/00 ,  C10G2300/1003 ,  C10G2300/1011 ,  C11C3/003 ,  Y02E50/13 ,  Y02P30/20 ,  B01J2523/27 ,  B01J2523/3725 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/48 ,  B01J2523/3743 ,  B01J2523/847 ,  B01J2523/3787

摘要： Mixed metal oxide catalysts (ZnO, CeO, La2O3, NiO, Al203, Si02, TiO2, Nd2O3, Yb2O3, or any combination of these) supported on zirconia (ZrO2) or hydrous zirconia are provided. These mixed metal oxide catalysts can be prepared via coprecipitation, impregnation, or sol-gel methods from metal salt precursors with/without a Zirconium salt precursor. Metal oxides/ZrO2 catalyzes both esterification and transesterification of oil containing free fatty acids in one batch or in single stage. In particular, these mixed metal oxides supported or added on zirconium oxide exhibit good activity and selectivity for esterification and transesterification. The low acid strength of this catalyst can avoid undesirable side reaction such as alcohol dehydration or cracking of fatty acids. Metal oxides/ZrO2 catalysts are not sensitive to any water generated from esterification. Thus, esterification does not require a water free condition or the presence of excess methanol to occur when using the mixed metal oxide catalyst. The FAME yield obtained with metal oxides/ZrO2 is higher than that obtained with homogeneous sulfuric acid catalyst. Metal oxides/ZrO2 catalasts can be prepared as strong pellets and in various shapes for use directly in a flow reactor. Furthermore, the pellet has a strong resistance toward dissolution to aqueous or oil phases.

摘要翻译： 提供负载在氧化锆（ZrO2）或含水氧化锆上的混合金属氧化物催化剂（ZnO，CeO，La2O3，NiO，Al2O3，SiO2，TiO2，Nd2O3，Yb2O3或它们的任意组合）。 这些混合金属氧化物催化剂可以通过共沉淀，浸渍或溶胶 - 凝胶法由具有/不具有锆盐前体的金属盐前体制备。 金属氧化物/ ZrO2催化一批或单一阶段含油游离脂肪酸的酯化和酯交换。 特别地，负载或添加到氧化锆上的这些混合金属氧化物显示出良好的酯化和酯交换活性和选择性。 该催化剂的低酸强度可以避免不希望的副反应，例如醇脱水或脂肪酸的裂解。 金属氧化物/ ZrO2催化剂对由酯化产生的任何水不敏感。 因此，当使用混合金属氧化物催化剂时，酯化不需要无水条件或过量甲醇的存在。 用金属氧化物/ ZrO2获得的FAME产率高于用均相硫酸催化剂获得的FAME产率。 金属氧化物/ ZrO 2催化剂可以制备成强颗粒，并且可以用于流动反应器中直接使用的各种形状。 此外，颗粒对水相或油相具有很强的溶解性。

公开(公告)号：US06841686B2

公开(公告)日：2005-01-11

申请号：US10308900

申请日：2002-12-03

申请人： Kostantinos Kourtakis ,  John Donal Sullivan

发明人： Kostantinos Kourtakis ,  John Donal Sullivan

IPC分类号： B01J23/00 ,  B01J23/28 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  C07C51/215 ,  C07D307/60

CPC分类号： B01J23/8898 ,  B01J23/002 ,  B01J23/28 ,  B01J23/887 ,  B01J23/8872 ,  B01J23/8875 ,  B01J23/8877 ,  B01J23/8885 ,  B01J2523/00 ,  C07C51/215 ,  C07C57/145 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/32 ,  B01J2523/845 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/56 ,  B01J2523/69 ,  B01J2523/53 ,  B01J2523/31 ,  B01J2523/25 ,  B01J2523/11 ,  B01J2523/24 ,  B01J2523/54 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/72 ,  B01J2523/23 ,  B01J2523/67 ,  B01J2523/3743 ,  B01J2523/27 ,  B01J2523/3706

摘要： This invention concerns catalysts comprising a molybdenum compound of formula I, II, III, IV or V VqMoAyOz  I NiMoxByOz′  II VNiwMoxCy′Oz″  III CoNiwMoxDyOz′″  IV VNiwCorMoxEyOz″″  V wherein: A is at least one cation selected from the group consisting of cations of: Cr, Sb, Co, Ce and Pb; B is at least one cation selected from the group consisting of cations of: Sb, Al and W; C is at least one cation selected from the group consisting of cations of: Fe, Zn, Al, Sb, Bi, W, Li, Ba, Nb and Sn; D is at least one cation selected from the group consisting of cations of: Ba, Mn, Al, Sb, Sn, and W; E is at least one cation selected from the group consisting of cations of: Fe, Ca, Mn, Sr, Eu, La, Zr, Ga, Sn and Pb; q, r, w, x and y are each independently a number from 0.1 to 10 and y′ is a number from 0 to 10, z, z′, z″, z′″, and z″″ are determined using the amounts and oxidation states of all cations present in each formula. These catalysts can be used in C4 oxidation processes, especially butane oxidation processes.

摘要翻译： 本发明涉及包含式I，II，III，IV或V的钼化合物的催化剂，其中：A是至少一种选自以下的阳离子：Cr，Sb，Co，Ce和Pb; B是选自由Sb，Al和W的阳离子组成的组中的至少一种阳离子; C是选自Fe，Zn，Al，Sb，Bi，W，Li，Ba，Nb和Sn中的至少一种阳离子; D是选自Ba，Mn，Al，Sb，Sn和W的阳离子中的至少一种阳离子; E是选自Fe，Ca，Mn，Sr，Eu，La，Zr，Ga，Sn和Pb的阳离子中的至少一种阳离子; q，r，w，x和y各自独立地为0.1至10的数，y'为0至10的数，z，z'，z“，z”'和z“ 使用每种配方中存在的所有阳离子的量和氧化态确定。 这些催化剂可用于C4氧化工艺，特别是丁烷氧化工艺。