Process and mixture for forming a coherent Refractory mass on a surface
    2.
    发明授权
    Process and mixture for forming a coherent Refractory mass on a surface 失效
    在表面形成相干的耐火材料的工艺和混合物

    公开(公告)号:US5866049A

    公开(公告)日:1999-02-02

    申请号:US788466

    申请日:1997-01-29

    IPC分类号: C04B35/16 C04B35/65 F27D1/16

    摘要: A ceramic welding process for forming a coherent refractory mass on a surface of a refractory which is hot and which is comprised of at least one silicon compound includes providing a mixture composed of combustible particles including silicon particles, refractory particles which are silicon carbide particles and which constitute a major portion by weight of the mixture, and particles of one of (a) another substance selected from the group consisting of CaO, MgO, FeO, and mixtures thereof or (b) particles of a nonmetallic precursor of the another substance, which another substance causes incorporation of silica, formed by combustion of the silicon particles, into a crystalline lattice of a compound formed between the silica and the another substance within the coherent refractory mass being formed; and projecting the mixture against the surface of the refractory, simultaneously with substantially pure oxygen, so that the combustible particles react in an exothermic manner by combusting with the projected oxygen and release sufficient heat to form the coherent refractory mass under action of heat of combustion, and so that silica, formed by combustion of the silicon particles, is incorporated into the crystalline lattice of a compound formed between the silica and the another substance.

    摘要翻译: 一种用于在耐热材料表面上形成粘结性耐火材料的陶瓷焊接工艺,该耐火材料是热的并且由至少一种硅化合物组成,包括提供由可燃颗粒组成的混合物,包括硅颗粒,耐火颗粒,其是碳化硅颗粒, 构成混合物的主要部分重量,和(a)选自CaO,MgO,FeO及其混合物的另一种物质的颗粒,或(b)另一种物质的非金属前体颗粒,其中 另一物质导致由硅颗粒的燃烧形成的二氧化硅结晶成形成在形成的相干耐火材料块内的二氧化硅和另一物质之间形成的化合物的晶格中; 并且将混合物与基本上纯的氧气同时地投射在耐火材料的表面上,使得可燃颗粒以放热的方式通过与投射的氧气一起燃烧并释放足够的热量以在燃烧热的作用下形成粘结的耐火材料块, 并且使得通过硅颗粒的燃烧形成的二氧化硅被并入形成在二氧化硅和另一物质之间的化合物的晶格中。

    Production of a siliceous refractory mass
    4.
    发明授权
    Production of a siliceous refractory mass 失效
    生产硅质耐火材料

    公开(公告)号:US5780114A

    公开(公告)日:1998-07-14

    申请号:US849305

    申请日:1997-05-27

    摘要: A process for producing a crystalline siliceous refractory mass includes providing particulate constituents to be projected comprised of (1) solid refractory particles comprising silica in the form of vitreous silica, and (2) solid combustible particles comprising silicon particles; projecting the particulate constituents with gaseous oxygen against a surface under ceramic welding conditions effective to cause a reaction between the solid combustible particles and the gaseous oxygen to occur against the surface, thereby releasing the heat of reaction against the surface so that a coherent refractory mass comprising cristobalite is formed, wherein the surface against which the solid refractory particles are projected is at a temperature of at least 1000.degree. C. The process can be used to manufacture refractory bricks or blocks, to repair furnaces, or to repair worn surfaces of a siliceous refractory material.

    摘要翻译: PCT No.PCT / BE95 / 00108 Sec。 371日期:1997年5月27日 102(e)日期1997年5月27日PCT提交1995年11月23日PCT公布。 第WO96 / 16917号公报 日本1996年6月6日制造结晶硅质耐火材料的方法包括提供待投影的颗粒组分,其包括(1)包含二氧化硅形式的二氧化硅的固体耐火颗粒,和(2)包含硅颗粒的固体可燃颗粒; 在有效地引起固体可燃性颗粒和气态氧之间的反应的陶瓷焊接条件下将颗粒成分用气态氧气投射到表面上,从而释放反对表面的反应热,从而包括 形成方英石,其中固体耐火颗粒投射的表面处于至少1000℃的温度。该方法可用于制造耐火砖或块,修复炉或修复硅质的磨损表面 耐火材料。

    Forming metal-intermetallic or metal-ceramic composites by
self-propagating high-temperature reactions
    6.
    发明授权
    Forming metal-intermetallic or metal-ceramic composites by self-propagating high-temperature reactions 失效
    通过自蔓延的高温反应形成金属 - 金属间化合物或金属 - 陶瓷复合材料

    公开(公告)号:US5564620A

    公开(公告)日:1996-10-15

    申请号:US139688

    申请日:1993-10-22

    CPC分类号: C04B35/651 C22C1/0491

    摘要: Industrial applications of composites often require that the final product have a complex shape. In this invention intermetallic or ceramic phases are formed from sheets of unreacted elemental metals. The process described in this invention allows the final product shape be formed prior to the formation of the composite. This saves energy and allows formation of shaped articles of metal-intermetallic composites composed of brittle materials that cannot be deformed without breaking.

    摘要翻译: 复合材料的工业应用通常要求最终产品具有复杂的形状。 在本发明中,由未反应的元素金属片形成金属间化合物或陶瓷相。 本发明描述的方法允许在形成复合材料之前形成最终产品形状。 这样可以节省能源,并且可以形成由脆性材料组成的金属 - 金属间复合材料的成形制品,不会变形而不破裂。

    Production of carbon-based composite materials as components of aluminum
production cells
    7.
    发明授权
    Production of carbon-based composite materials as components of aluminum production cells 失效
    生产碳基复合材料作为铝生产电池的组成部分

    公开(公告)号:US5409589A

    公开(公告)日:1995-04-25

    申请号:US142818

    申请日:1993-10-26

    摘要: A method of producing a component of an aluminium production cell made of a carbon-based composite material containing a refractory hard metal boride, carbide, oxide, nitride or combinations or mixtures thereof and aluminium as metal, alloy or as an aluminium compound, comprises firstly providing a reaction mixture of aluminium and precursors which react to form the refractory hard metal compound, and optional fillers and additives. The reaction mixture is mixed with particulate carbon in an amount of from 1 to 20 parts by weight of carbon for 1 part by weight of the reaction mixture; and with a colloidal binder containing at least one of colloidal silica, alumina, yttria, ceria, thoria, zirconia, magnesia, lithia, in an amount to fully wet the carbon particles. The resulting mixture is compacted and dried and heated to initiate reaction of the reaction mixture by self-propagating micropyretic reaction.

    摘要翻译: 一种由包含难熔硬金属硼化物,碳化物,氧化物,氮化物或其组合或混合物的碳基复合材料制成的铝生产电池的组分的方法,以及作为金属,合金或铝化合物的铝包括: 提供铝和前体的反应混合物,其反应形成耐火硬金属化合物,以及任选的填料和添加剂。 反应混合物与1重量份反应混合物的1至20重量份碳的量的颗粒碳混合; 并且含有胶态二氧化硅,氧化铝,氧化钇,二氧化铈,氧化钍,氧化锆,氧化镁,锂二者中的至少一种的胶态粘合剂,其量使得碳颗粒完全润湿。 将所得混合物压实并干燥并加热以引发反应混合物通过自蔓延微量反应的反应。

    Ceramic welding process
    8.
    发明授权
    Ceramic welding process 失效
    陶瓷焊接工艺

    公开(公告)号:US5242639A

    公开(公告)日:1993-09-07

    申请号:US896908

    申请日:1992-06-11

    IPC分类号: C04B35/65 F27D1/16

    CPC分类号: C04B35/651 F27D1/1647

    摘要: In ceramic welding processes, oxidising gas and a mixture of refractory and fuel powders are projected against a surface and the fuel is burnt to generate sufficient heat that the refractory powder becomes at least partially melted or softened and a cohesive refractory mass is progressively built up against that surface. In order to reduce any tendency for the weld mass to include a low-grade refractory phase and thus promote the refractoriness of that weld mass, the fuel powder is present in a proportion of not more than 15% by weight of the total mixture and includes at least two metals selected from aluminium, magnesium, chromium and zirconium, and in that at least the major part by weight of the refractory powder consists of one or more of magnesia, alumina and chromic oxide, and in that the molar proportions of silica and calcium oxide present in the refractory powder (if any) satisfy the following expression: molar concentration of SiO.sub.2 in % .ltoreq.0.2+molar concentration of CaO in %

    摘要翻译: 在陶瓷焊接工艺中,氧化气体和耐火材料和燃料粉末的混合物投射在表面上,并且燃料被燃烧以产生足够的热量,使得耐火材料粉末至少部分地熔融或软化,并且内聚的耐火材料块逐渐建立成抵抗 那个表面。 为了减少焊接质量包括低等级耐火相的倾向,从而促进该焊接质量的不耐受性,燃料粉末以不超过总混合物的15重量%的比例存在,并且包括 选自铝,镁,铬和锆中的至少两种金属,并且至少大部分重量的耐火材料粉末由一种或多种氧化镁,氧化铝和氧化铬组成,其中二氧化硅和 存在于耐火材料粉末(如果有的话)中的氧化钙满足以下表达式:SiO 2的摩尔浓度%≤0.2+ CaO的摩尔浓度%

    Combustion synthesis method and products
    9.
    发明授权
    Combustion synthesis method and products 失效
    燃烧合成方法和产品

    公开(公告)号:US5198188A

    公开(公告)日:1993-03-30

    申请号:US641977

    申请日:1991-01-16

    摘要: Disclosed is a method of producing dense refractory products, comprising:(a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction;(b) removing absorbed water vapor therefrom;(c) cold-pressing said material into a formed body;(d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and(e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis.Also disclosed are products produced by the method.

    摘要翻译: 公开了一种生产致密耐火产品的方法,包括:(a)获得能够维持燃烧合成反应的粉末形式的散热材料的量; (b)从其中除去吸收的水蒸汽; (c)将所述材料冷压成成形体; (d)用熔融的放热材料等离子体喷涂所述成形体以在其上形成涂层; 和(e)在惰性气体气氛和压力下点燃所述耐热涂层的成形体以产生自持燃烧合成。 还公开了通过该方法生产的产品。

    Exothermic compositions
    10.
    发明授权
    Exothermic compositions 失效
    放热组成

    公开(公告)号:US5180759A

    公开(公告)日:1993-01-19

    申请号:US185997

    申请日:1988-04-25

    摘要: An exothermic composition comprises a particulate readily oxidizable metal such as aluminum, magnesium or silicon and an organic fluorine-containing compound, and usually an oxidizing agent for the readily oxidizable metal. The preferred organic fluorine-containing compound is polytetrafluoroethylene. The composition may also contain a binder, a particulate refractory material, refractory fibres and/or organic fibres. The composition may be used in the casting of molten metal, either in particulate form or as a preformed shape such as a sleeve or board, to cover or surround molten metal in the feeder of a casting mould or in the head or head box of an ingot mould.

    摘要翻译: 放热组合物包含微粒容易氧化的金属如铝,镁或硅和有机含氟化合物,通常是易氧化金属的氧化剂。 优选的有机含氟化合物是聚四氟乙烯。 组合物还可以含有粘合剂,颗粒耐火材料,耐火纤维和/或有机纤维。 组合物可以用于铸造熔融金属,以颗粒形式或作为预成型的形状例如套筒或板,以覆盖或围绕铸模的进料器中的熔融金属或在头模或头箱中的熔融金属 锭模具。