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    Process for making phenol and/or cyclohexanone
    3.
    发明授权
    Process for making phenol and/or cyclohexanone 有权
    制备苯酚和/或环己酮的方法

    公开(公告)号：US09334218B2

    公开(公告)日：2016-05-10

    申请号：US14443175

    申请日：2013-12-06

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Kun Wang ,  Roberto Garcia ,  Terry E. Helton ,  Hari Nair ,  Charles Morris Smith

    IPC: C07C45/53 ,  C07C37/08 ,  C07C2/74

    CPC classification number: C07C45/53 ,  C07C37/08 ,  C07C2601/14 ,  Y02P20/52 ,  C07C39/04 ,  C07C49/403

    Abstract: A cleavage process for making phenol and/or cyclohexanone, the process comprising: (A) providing a feed comprising cyclohexylbenzene hydroperoxide; (B) contacting the feed with a catalyst under cleavage reaction conditions effective to produce a cleavage effluent comprising phenol and cyclohexanone, the catalyst having a collidine uptake of at least 20 μmol per gram of the catalyst and comprising an aluminosilicate molecular sieve of the FAU-type, an oxide binder, and a clay.

    Abstract translation: 一种用于制备苯酚和/或环己酮的裂解方法，该方法包括：（A）提供包含环己基苯氢过氧化物的进料; （B）在有效产生包含苯酚和环己酮的裂解流出物的裂解反应条件下，使进料与催化剂接触，所述催化剂具有至少20微摩尔/克催化剂的可力丁吸收，并且包含FAU- 类型，氧化物粘合剂和粘土。

    Method for measuring acid strength in reaction medium using trimethylphosphine oxide and 31P NMR
    6.
    发明授权
    Method for measuring acid strength in reaction medium using trimethylphosphine oxide and 31P NMR 有权
    使用三甲基氧化膦和31 P NMR测定反应介质中酸强度的方法

    公开(公告)号：US09335285B2

    公开(公告)日：2016-05-10

    申请号：US14498332

    申请日：2014-09-26

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Kun Wang ,  Roberto Garcia

    IPC: G01N31/22 ,  G01N24/08 ,  C07C37/08 ,  G01R33/46 ,  C07C45/53

    CPC classification number: G01N24/088 ,  C07C37/08 ,  C07C45/53 ,  C07C2601/14 ,  G01N24/085 ,  G01N31/221 ,  G01R33/46 ,  Y10T436/163333 ,  C07C39/04 ,  C07C49/403

    Abstract: A method to determine the strength of an acid in a medium is disclosed. The method includes (I) providing multiple samples comprising trimethylphosphine oxide (TMPO), the acid, and the medium, wherein the multiple samples have different [H+]/[TMPO] ratios, [H+] is the concentration of hydrons in the sample in mole·liter−1, and [TMPO] is the concentration of TMPO in the sample in mole·liter−1. (II) The 31P chemical shifts of the multiple samples are measured by 31P NMR and compared to standardized samples to determine the acid strength of the medium.

    Abstract translation: 公开了确定介质中酸的强度的方法。 该方法包括（I）提供包含三甲基氧化膦（TMPO），酸和介质的多个样品，其中多个样品具有不同的[H +] / [TMPO]比，[H +]是样品中氢化物的浓度 摩尔·升-1，[TMPO]是样品中TMPO的浓度，摩尔·升-1。 （II）通过31P NMR测量多个样品的31P化学位移，并与标准样品进行比较，以确定培养基的酸强度。

    Processes for Producing Phenol
    7.
    发明申请
    Processes for Producing Phenol 有权
    生产苯酚的方法

    公开(公告)号：US20150315111A1

    公开(公告)日：2015-11-05

    申请号：US14800042

    申请日：2015-07-15

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Keith H. Kuechler ,  Francisco M. Benitez ,  Kun Wang ,  James R. Lattner ,  Christopher L. Becker

    IPC: C07C37/08 ,  C07C37/82 ,  C07C407/00

    CPC classification number: C07C49/403 ,  C07C37/08 ,  C07C37/82 ,  C07C37/86 ,  C07C39/04 ,  C07C45/85 ,  C07C407/00 ,  C07C2601/14 ,  Y02P20/52

    Abstract: Disclosed herein is a process for producing phenol. The process includes oxidizing at least a portion of a feed comprising cyclohexylbenzene to produce an oxidation composition comprising cyclohexyl-1-phenyl-1-hydroperoxide. The oxidation composition may then be cleaved in the presence of an acid catalyst to produce a cleavage reaction mixture comprising the acid catalyst, phenol and cyclohexanone. At least a portion of the cleavage reaction mixture may be neutralized with a basic material to form a treated cleavage reaction mixture. In various embodiments, the treated cleavage reaction mixture contains no greater than 50 wppm of the acid catalyst or no greater than 50 wppm of the basic material.

    Abstract translation: 本文公开了一种生产苯酚的方法。 该方法包括氧化至少一部分包含环己基苯的进料以产生包含环己基-1-苯基-1-氢过氧化物的氧化组合物。 然后可以在酸催化剂的存在下将氧化组合物切割，以产生包含酸催化剂，苯酚和环己酮的裂解反应混合物。 裂解反应混合物的至少一部分可以用碱性物质中和以形成经处理的裂解反应混合物。 在各种实施方案中，处理的裂解反应混合物含有不大于50wppm的酸催化剂或不大于50wppm的碱性物质。

    Process for Producing Phenol
    8.
    发明申请
    Process for Producing Phenol 有权
    生产苯酚的方法

    公开(公告)号：US20150251986A1

    公开(公告)日：2015-09-10

    申请号：US14433211

    申请日：2013-11-13

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Keith H. Kuechler ,  Charles Morris Smith ,  Francisco M. Benitez ,  Kun Wang ,  Hari Nair ,  Travis A. Reine ,  Gabor Kiss ,  Roberto Garcia ,  Christopher L. Becker

    IPC: C07C45/53 ,  C07C37/08

    CPC classification number: C07C45/53 ,  C07C2/74 ,  C07C37/08 ,  C07C407/00 ,  C07C2601/14 ,  C07C49/403 ,  C07C13/28 ,  C07C39/04 ,  C07C409/14

    Abstract: In a process for producing phenol and cyclohexanone, a cleavage feed containing greater than 40 wt % and no greater than 95 wt % cyclohexyl-1-phenyl-1-hydroperoxide, and at least 5 wt % and less than 60 wt % cyclohexylbenzene is mixed with at least phenol, cyclohexanone, water, and sulfuric acid to produce a cleavage reaction mixture containing from 15 wt % to 50 wt % phenol, from 15 wt % to 50 wt % cyclohexanone, from 1 wt % to 10 wt % cyclohexyl-1-phenyl-1-hydroperoxide, from 5 wt % to 60 wt % cyclohexylbenzene, from 0.1 wt % to 4 wt % water, and from 10 wppm to 1000 wppm sulfuric acid. The cleavage reaction mixture is then reacted at a temperature from 30° C. and to 70° C., and a pressure of at least 1 atmosphere for a time sufficient to convert at least 50% of said cyclohexyl-1-phenyl-1-hydroperoxide in said cleavage reaction mixture and produce a cleavage effluent containing phenol and cyclohexanone.

    Abstract translation: 在生产苯酚和环己酮的方法中，混合含有大于40重量％且不大于95重量％环己基-1-苯基-1-氢过氧化物和至少5重量％且小于60重量％环己基苯的裂解原料混合 至少含有苯酚，环己酮，水和硫酸，以产生裂解反应混合物，其含有15重量％至50重量％的苯酚，15重量％至50重量％的环己酮，1重量％至10重量％的环己基-1 苯基-1-氢过氧化物，5重量％至60重量％的环己基苯，0.1重量％至4重量％的水，以及10wppm至1000wppm的硫酸。 然后将裂解反应混合物在30℃至70℃的温度和至少1个大气压的压力下反应足以将至少50％的所述环己基-1-苯基-1- 所述裂解反应混合物中的氢过氧化物，并产生含有苯酚和环己酮的裂解流出液。

    Process for Producing Phenol and Method for Regenerating Catalyst Deactivated in the Process
    9.
    发明申请
    Process for Producing Phenol and Method for Regenerating Catalyst Deactivated in the Process 有权
    生产苯酚的方法和再生催化剂在过程中失活的方法

    公开(公告)号：US20140163259A1

    公开(公告)日：2014-06-12

    申请号：US14094243

    申请日：2013-12-02

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Jihad Mohammed Dakka ,  Kun Wang

    IPC: B01J29/90 ,  C07C45/51 ,  C07C37/08

    CPC classification number: B01J29/90 ,  B01J38/48 ,  C07C37/08 ,  C07C45/53 ,  C07C2601/14 ,  Y02P20/52 ,  Y02P20/584 ,  C07C39/04 ,  C07C49/403

    Abstract: A process for producing phenol is described in which a feed comprising alkylbenzene hydroperoxide is contacted with a cleavage catalyst under cleavage conditions effective to convert at least part of the hydroperoxide into phenol, the process is characterized in that at least a part of the deactivated catalyst is regenerated using a oxidizing material comprising hydrogen peroxide and then return to the process. A method of regenerating the cleavage catalyst is also described.

    Abstract translation: 描述了一种生产苯酚的方法，其中包含烷基苯氢过氧化物的进料在切割条件下与切割催化剂接触，在有效地将至少部分氢过氧化物转化成苯酚的切割条件下，该方法的特征在于至少一部分失活催化剂是 使用包含过氧化氢的氧化材料再生，然后返回该过程。 还描述了再生裂解催化剂的方法。

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