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    FCC catalysts for feeds containing nickel and vanadium
    3.
    发明申请
    FCC catalysts for feeds containing nickel and vanadium 审中-公开
    用于含镍和钒的饲料的FCC催化剂

    公开(公告)号：US20030089640A1

    公开(公告)日：2003-05-15

    申请号：US09978180

    申请日：2001-10-17

    发明人： Rostam Madon ,  David H. Harris ,  Mingting Xu ,  David Stockwell ,  Bruce Lerner ,  Glenn W. Dodwell

    IPC分类号： C10G011/02 ,  B01J029/04 ,  B01J029/06

    CPC分类号： B01J37/0045 ,  B01J29/084 ,  B01J29/088 ,  B01J2229/42 ,  B01J2229/64 ,  C10G2300/107

    摘要： A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina which contains a gamma alumina phase. The transitional alumina may contain a delta alumina phase as well. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

    摘要翻译： 由微球制成的流化催化裂化催化剂，其最初含有高岭土，可分散勃姆石氧化铝和硅酸钠或硅溶胶粘结剂。 高岭土部分含有水合高岭土和任选的通过其特征放热煅烧的高岭土。 通过用硅酸钠处理将含水粘土煅烧成偏高岭土和原位沸石形成产生含有Y型八面沸石的催化剂，并将可分散勃姆石转化为含有γ氧化铝相的过渡型氧化铝。 过渡氧化铝也可以含有δ氧化铝相。 该催化剂可用于裂解残渣或渣油进料，因为由可分散勃姆石形成的氧化铝相钝化镍和钒污染物。

    Fluid catalytic cracking process for heavy oil
    4.
    发明申请
    Fluid catalytic cracking process for heavy oil 有权
    重油流化催化裂化工艺

    公开(公告)号：US20030006168A1

    公开(公告)日：2003-01-09

    申请号：US09883464

    申请日：2001-06-07

    发明人： Takashi Ino ,  Toshiaki Okuhara ,  Mohammad Abul-Hamayel ,  Abdullah Aitani ,  Abdulgader Maghrabi

    IPC分类号： C10G011/05 ,  C10G011/02 ,  C10G011/00

    CPC分类号： C10G11/05 ,  C10G11/18

    摘要： A heavy fraction oil is catalytically cracked by contacting the oil with a catalyst mixture consisting of 60 to 95 wt % of a base cracking catalyst containing an ultra stable Y-type zeolite and less than 0.5 wt % of rare-earth metal oxide, and 5 to 40 wt % of an additive containing a shape-selective zeolite, in a fluid catalytic cracking apparatus having a regeneration zone, a down flow-type reaction zone, a separation zone, and a stripping zone, and under conditions that a reaction zone outlet temperature is in the range of 580 to 630null C., the catalyst/oil ratio is in the range of 15 to 40 wt/wt, and the contact time of hydrocarbons in the reaction zone is in the range of 0.1 to 1.0 seconds. According to the fluid catalytic cracking process, the yield of light-fraction olefins can be enhanced.

    摘要翻译： 通过使油与催化剂混合物催化裂解，该催化剂混合物由60至95重量％的含有超稳定Y型沸石和少于0.5重量％稀土金属氧化物的基础裂化催化剂组成，5重量％ 至40重量％的含有形状选择性沸石的添加剂，在具有再生区，下流式反应区，分离区和汽提区的流化催化裂化装置中，在反应区出口 温度在580〜630℃的范围内，催化剂/油比在15〜40重量/重量的范围内，烃在反应区中的接触时间为0.1〜1.0秒。 根据流化催化裂化方法，轻馏分烯烃的产率可以提高。

    GASOLINE SULFUR REDUCTION IN FLUID CATALYTIC CRACKING
    5.
    发明申请
    GASOLINE SULFUR REDUCTION IN FLUID CATALYTIC CRACKING 无效
    流体催化裂化中的汽油硫还原

    公开(公告)号：US20020153283A1

    公开(公告)日：2002-10-24

    申请号：US09221540

    申请日：1998-12-28

    发明人： ARTHUR W CHESTER ,  HYE KYUNG CHO TIMKEN ,  TERRY G ROBERIE ,  MICHAEL S ZIEBARTH

    IPC分类号： C10G011/02 ,  C10G011/04 ,  C10G029/16

    CPC分类号： C10G11/05 ,  B01J29/166 ,  B01J2229/42

    摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.

    摘要翻译： 通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属 筛子的结构以及提高催化剂的稳定性和硫还原活性的铈组分。 分子筛通常是诸如USY的八面沸石。 初级硫还原组分通常是元素周期3的金属，优选为钒。 硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

    Combined cracking and selective hydrogen combustion for catalytic cracking
    7.
    发明申请
    Combined cracking and selective hydrogen combustion for catalytic cracking 失效
    组合开裂和选择性氢燃烧用于催化裂化

    公开(公告)号：US20040152585A1

    公开(公告)日：2004-08-05

    申请号：US10358977

    申请日：2003-02-05

    发明人： John D. Y. Ou ,  Neeraj Sangar

    IPC分类号： C10G011/02

    CPC分类号： B01J23/835 ,  B01J23/002 ,  B01J23/08 ,  B01J23/34 ,  B01J23/825 ,  B01J29/06 ,  B01J35/0006 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18 ,  C10G11/182

    摘要： A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of two or more elements from Groups 4-15 of the Periodic Table of the Elements and at least one of oxygen and sulfur, wherein the elements from Groups 4-15 and the at least one of oxygen and sulfur are chemically bound both within and between the groups and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.

    摘要翻译： 公开了一种用于烃的组合裂化和选择性氢燃烧的催化剂体系和方法。 催化剂包含（1）至少一种固体酸组分，（2）由元素周期表第4-15族中的两种或多种元素组成的至少一种金属基组分和至少一种氧和硫， 其中来自组4-15的元素和氧和硫中的至少一种的元素在基团内和组之间化学键合，和（3）至少一种载体，至少一种填料和至少一种粘合剂中的至少一种。 该方法使得当将烃与单独的固体酸组分接触时，氢的产率小于氢的产率。

    Method for gas - solid contacting in a bubbling fluidized bed reactor
    9.
    发明申请
    Method for gas - solid contacting in a bubbling fluidized bed reactor 失效
    在鼓泡流化床反应器中气 - 固接触的方法

    公开(公告)号：US20020179489A1

    公开(公告)日：2002-12-05

    申请号：US09817744

    申请日：2001-03-26

    申请人： COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

    发明人： Vasant Ramchandra Choudhary ,  Tushar Vasant Choudhary

    IPC分类号： C10G047/02 ,  C10G011/02 ,  C10G035/04

    CPC分类号： B01J8/1809 ,  B01J8/0055 ,  B01J8/1818 ,  B01J2208/00548 ,  C10G2/332 ,  C10G2/344 ,  C10G9/32 ,  C10G11/18 ,  C10G35/14 ,  C10G47/18 ,  C10G47/30

    摘要： The present invention relates to a method for gas-solid contacting in a bubbling fluidized bed reactor by: (a) introducing into a reactor with bed length to bed diameter ratio below about 5.0, a primary gas consisting essentially of reactant(s) of the reaction to be carried out in the bed of solid particles through a primary gas distributor located at the reactor bottom at a superficial gas velocity Up, which is very close or equivalent to the minimum fluidization velocity Umf, required for achieving the incipient fluidization of the solid particles in the bed to obtain an emulsion phase consisting essentially of the solid particles and the primary gas with little or no formation of gas bubbles to achieve incipient fluidization or liquid-like behavior of fluidizable solid particles; (b) forming gas bubbles in the incipiently fluidized bed by introducing through a secondary gas distributor located immediately above the primary gas distributor a secondary gas, selected from one of the reactants which is used in excess of that required for the reaction stoichiometry, steam, an inert or a mixture of two or more thereof at a superficial gas velocity, Us, which is related to the superficial velocity of the primary gas such that a ratio of the superficial velocity of the secondary gas to the superficial velocity of the primary gas Us/Up, is in the range from about 0.5 to about 10.0, preferably from about 1 to about 5.

    摘要翻译： 本发明涉及通过以下步骤在鼓泡流化床反应器中气 - 固接触的方法：（a）将床长至床直径比低于约5.0引入反应器中，主要气体基本上由 在固体颗粒床上通过位于反应器底部的主气体分布器以表面气体速度Up进行反应，该气体速度Up非常接近或等于实现固体初始流化所需的最小流化速度Umf 以获得基本上由固体颗粒和初级气体组成的乳液相，其中很少或不形成气泡，以实现可流化固体颗粒的初始流化或液体状态; （b）在初始流化床中形成气泡，通过位于初级气体分配器正上方的二次气体分配器引入二次气体，二次气体选自使用超过反应化学计量所需反应物的一种反应物之一，蒸汽， 惰性或其两种或多种的混合物，其表面气体速度为Us，其与初级气体的表观速度相关，使得二次气体的表观速度与初级气体的表观速度Us /升，在约0.5至约10.0，优选约1至约5的范围内。

    NOx reduction compositions for use in FCC processes
    10.
    发明申请
    NOx reduction compositions for use in FCC processes 审中-公开
    用于FCC工艺的NOx还原组合物

    公开(公告)号：US20020092795A1

    公开(公告)日：2002-07-18

    申请号：US10084141

    申请日：2002-02-22

    发明人： Alan W. Peters ,  John A. Rudesill ,  Gordon Dean Weatherbee ,  Edward F. Rakiewicz ,  Mary Jane A. Barbato-Grauso

    IPC分类号： C10G011/02

    CPC分类号： B01J23/63 ,  B01D53/8628 ,  B01J23/66 ,  B01J23/83 ,  C10G11/05

    摘要： Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NOx control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

    摘要翻译： 包含含有（i）酸性氧化物载体，（ii）碱金属和/或碱土金属或其混合物的组分的组分，（iii）具有储氧能力的过渡金属氧化物，和（iv） 周期表的Ib和/或IIb组在FCC工艺中提供NOx控制性能。 酸性氧化物载体优选含有二氧化硅氧化铝。 二氧化铈是优选的氧储存氧化物。 Cu和Ag优选为I / IIb族过渡金属。 该组合物特别可用于具有高于平均氮含量的烃原料的裂化。