Method of making synthetic hydrophilic polymers and products resulting therefrom
    1.
    发明申请
    Method of making synthetic hydrophilic polymers and products resulting therefrom 有权
    制备合成亲水性聚合物的方法及由此产生的产物

    公开(公告)号:US20010044502A1

    公开(公告)日:2001-11-22

    申请号:US09838020

    申请日:2001-04-19

    IPC分类号: C08F008/12

    摘要: The present invention involves a method of making a multiblock copolymer containing two or more types of sequences of derivatives of acrylic acid with at least one derivative being acrylic acid salt and at least one being acrylamide. The method includes: (e) in sequence, a first step being a catalytic reaction of nitrile groups in polyacrylonitrile dissolved in an inorganic aqueous solvent of polyacrylonitrile; and, (f) at least one subsequent step being at least one catalytic reaction of nitrile groups in absence of polyacrylonitrile solvents.The present invention also pertains to the products resulting from the method.

    摘要翻译: 本发明涉及一种制备含有丙烯酸衍生物的两种或更多种类型的多嵌段共聚物的方法,至少一种衍生物是丙烯酸盐,至少一种是丙烯酰胺。 该方法包括:(e)顺序地,第一步是溶解在聚丙烯腈的无机水性溶剂中的聚丙烯腈中的腈基的催化反应; 和(f)至少一个后续步骤是在不存在聚丙烯腈溶剂的情况下进行至少一个腈基的催化反应。本发明还涉及由该方法得到的产物。

    Grafted and crosslinkable pulverulent thermoplastic polyolefin composition which has elasticity and flexibility properties
    2.
    发明申请
    Grafted and crosslinkable pulverulent thermoplastic polyolefin composition which has elasticity and flexibility properties 失效
    接枝和交联的粉状热塑性聚烯烃组合物,具有弹性和柔软性

    公开(公告)号:US20010011784A1

    公开(公告)日:2001-08-09

    申请号:US09816134

    申请日:2001-03-26

    摘要: A bulk polymerized grafted and crosslinkable thermoplastic polyolefin powder composition having elasticity and flexibility properties, which is in the form of a powder intended for the production of flexible coatings by free flow over a hot mold, characterized in that it contains: a) from 100 to 5% by weight and preferably from 80 to 20% by weight of at least one homopolymer of ethylene and/or at least one copolymer containing at least 50 molar % of ethylene; b) from 0 to 95% by weight and preferably from 20 to 80% by weight of at least one thermoplastic elastomer; c) from 0.1 to 15 parts by weight and preferably from 0.5 to 10 parts by weight of a grafting agent, per 100 parts by weight of the accumulated components nullanull and nullbnull. This powder composition is suitable for the production of flexible coatings by its free flow over a hot mold.

    摘要翻译: 一种具有弹性和柔软性的本体聚合接枝和可交联热塑性聚烯烃粉末组合物,其为粉末形式,用于通过自由流过热模具生产柔性涂层,其特征在于其包含:a)100至 5重量%,优选80至20重量%的至少一种乙烯均聚物和/或至少一种含至少50摩尔%乙烯的共聚物; b)0至95重量%,优选20至80重量%的至少一种热塑性弹性体; c)相对于100重量份的累积成分“a”和“b”,为0.1〜15重量份,优选为0.5〜10重量份的接枝剂。 该粉末组合物适用于通过热模具的自由流动来生产柔性涂层。

    Curable coating compositions and methods of forming coating films
    4.
    发明申请
    Curable coating compositions and methods of forming coating films 审中-公开
    可固化涂料组合物和形成涂膜的方法

    公开(公告)号:US20020016418A1

    公开(公告)日:2002-02-07

    申请号:US09809817

    申请日:2001-03-16

    摘要: A coating composition curable by actinic radiation, heat or both comprising a polymer containing an alkoxysilyl group having a weight average molecular weight of from about 500 to more than 10,000, a Radical reactivity compound, a cationic polymerization initiator, and an optional radical polymerization initiator and cationic reactivity compound.

    摘要翻译: 通过光化辐射,热或两者可固化的涂料组合物,其包含含有重均分子量为约500至10,000的烷氧基甲硅烷基的聚合物,自由基反应性化合物,阳离子聚合引发剂和任选的自由基聚合引发剂,以及 阳离子反应性化合物。

    Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coating containing the same
    5.
    发明申请
    Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coating containing the same 有权
    一元多氟氧杂环丁烷低聚物,聚合物和共聚物以及含有它们的涂层

    公开(公告)号:US20030149186A1

    公开(公告)日:2003-08-07

    申请号:US10316412

    申请日:2002-12-11

    IPC分类号: C08F008/12

    摘要: Monofunctional polyfluorooxetane oligomers, polymers, and copolymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.

    摘要翻译: 单官能聚氟乙烯低聚物,聚合物和共聚物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 除了作为引发剂外,一元醇还可以用作氟氧杂环丁烷或其它单体的溶剂,以制备具有低循环含量的低聚物,聚合物或共聚物。 合适的共聚单体通常包括各种环醚。 具有单个羟基端基的多氟全息聚氧乙烯低聚物,聚合物或共聚物可以用各种化合物进行官能化,以产生官能化的端基如丙烯酸酯,甲基丙烯酸酯,烯丙基,胺等,其官能化 低聚物或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化以提供润湿和表面性能的改进。

    Ethylene-vinyl alcohol copolymer resin composition of improved long-run workability, and its shaped articles
    6.
    发明申请
    Ethylene-vinyl alcohol copolymer resin composition of improved long-run workability, and its shaped articles 有权
    乙烯 - 乙烯醇共聚物树脂组合物具有改善的长期加工性能及其成型制品

    公开(公告)号:US20010025087A1

    公开(公告)日:2001-09-27

    申请号:US09734200

    申请日:2000-12-12

    申请人: Kuraray Co., Ltd.

    IPC分类号: C08F008/12

    CPC分类号: C08K5/098 C08L29/04

    摘要: Disclosed are a resin composition comprising an ethylene-vinyl alcohol copolymer, and a multi-layered structure comprising the resin composition. Adhering little to dies while worked, the resin composition ensures good long-run workability and self-purgeability; and its shaped articles have good appearance with few voids and are yellowed little. The resin composition is characterized in that the profile of its intrinsic viscosity nullnullnull in heat treatment at 220null C. in a nitrogen atmosphere satisfies the following formulae (1) to (3), and that it contains from 0.05 to 5 nullmol/g of a carboxylic acid (A) and from 2 to 25 nullmol/g, in terms of the metal element, of an alkaline earth metal salt (B), and satisfies the following formula (4): 0.05nullnullnullnull0null0.2nullnull(1) 0.12nullnullnullnull10/nullnullnull0null0.6nullnull(2) 0.1nullnullnullnull60/nullnullnull0null0.8nullnull(3) 0.1null(a1)/(A)null1.0nullnull(4) wherein; nullnullnull0 indicates the intrinsic viscosity of the non-heated resin composition, nullnullnull10 indicates the intrinsic viscosity of the resin composition heated for 10 hours, nullnullnull60 indicates the intrinsic viscosity of the resin composition heated for 60 hours, (A) indicates the total content (nullmol/g) of the carboxylic acid (A) and its salt in the resin composition, (a1) indicates the content (nullmol/g) of a carboxylic acid (a1) having a molecular weight of at least 75 and its salt in the resin composition.

    摘要翻译: 公开了包含乙烯 - 乙烯醇共聚物的树脂组合物和包含该树脂组合物的多层结构。 树脂组合物在加工时几乎不致死,确保了长期的可操作性和自清洗性能; 其成型制品外观美观,空隙少,黄色少。 树脂组合物的特征在于,其在氮气气氛中220℃下的热处理中的特性粘度η的曲线满足下式(1)〜(3),其含有0.05〜5μmol/ g的羧酸(A),以及金属元素为2〜25μmol/ g的碱土金属盐(B),满足下式(4):&lt;第lvl =“0” > 0.05 <= 0 <= 0.2(1) <段落lvl =“0”> 0.12 <=η 10 /η0 <= 0.6(2) <段落lvl =“0”>在线公式>0.1≤60/η0 <= 0.8 (3) 0.1 <=(a1)/(A)<= 1.0(4) 其中; η0表示非加热树脂组合物的特性粘度,η10表示加热了10小时的树脂组合物的特性粘度,η60表示加热了60小时的树脂组合物的特性粘度, (A)表示树脂组合物中羧酸(A)及其盐的总含量(mumol / g),(a1)表示分子量为(A)的羧酸(a1)的含量(mumol / g) 至少75及其盐在树脂组合物中。

    Oxyfunctionalization of polyolefins
    7.
    发明申请
    Oxyfunctionalization of polyolefins 有权
    聚烯烃的氧官能化

    公开(公告)号:US20040249086A1

    公开(公告)日:2004-12-09

    申请号:US10831869

    申请日:2004-04-26

    CPC分类号: C08C19/02 C08F8/06 C08F210/16

    摘要: The present invention is a method for oxyfunctionalizing, that is, introducing oxygen functionality to, a polyolefin such as polypropylene and poly(ethylene-alt-propylene). The polyolefin is contacted with an oxygen source such as a persulfate and catalytic amounts of a metal porphyrin complex under mild conditions to yield an oxyfunctionalized polymer that has a polydispersity that is very similar to that of the starting polymer.

    摘要翻译: 本发明是一种氧化官能化方法,即将聚氧乙烯(聚丙烯)和聚(亚乙基 - 高级 - 丙烯)等聚烯烃引入氧官能度。 聚烯烃在温和条件下与氧源如过硫酸盐和催化量的金属卟啉络合物接触,得到具有与起始聚合物非常相似的多分散性的氧化官能化聚合物。

    Highly water-absorptive ophthalmic lens and method of producing the same
    8.
    发明申请
    Highly water-absorptive ophthalmic lens and method of producing the same 审中-公开
    高吸水性眼科镜片及其制造方法

    公开(公告)号:US20030218717A1

    公开(公告)日:2003-11-27

    申请号:US10443540

    申请日:2003-05-21

    申请人: MENICON CO., LTD.

    发明人: Masuji Ichihara

    摘要: A highly water-absorptive ophthalmic lens which is formed of a macromolecular material including vinyl alcohol unit as a major component and whose water content is in a range of 50-90%, wherein: the macromolecular material is a cross-linked vinyl alcohol-allyl alcohol/halogenated-alkyl ethylene copolymer which includes allyl alcohol unit and/or halogenated-alkyl ethylene unit, together with the vinyl alcohol unit; and the ophthalmic lens has a ratio of a dimensional change of less than null2% and being free from whitening after (A) the ophthalmic lens has been subjected to three cycles of a freezing-thawing operation wherein the ophthalmic lens formed of the macromolecular material is left at a temperature of not higher than null10null C. for not less than twelve hours, and is subsequently left at a temperature in a range from 15null C. to 30null C. for not less than six hours, and/or (B) the ophthalmic lens has been kept at a temperature in a range from 1null C. to 9null C. for three months.

    摘要翻译: 一种高吸水性眼科镜片,其由包含乙烯醇单元作为主要成分并且水含量在50-90%范围内的高分子材料形成,其中:高分子材料是交联的乙烯醇 - 烯丙基 包括烯丙醇单元和/或卤代烷基乙烯单元的醇/卤代烷基乙烯共聚物与乙烯醇单元一起; 并且眼用透镜在(A)眼用透镜已进行三次冷冻操作循环之后具有小于±2%的尺寸变化比率且不变白,其中由高分子材料形成的眼镜片 在不高于-10℃的温度下放置不少于12小时,然后在15℃至30℃的温度下放置不少于6小时,和/ 或(B)将眼科镜片保持在1℃至9℃的温度下三个月。

    Method of making synthetic hydrophilic polymers and products resulting therefrom
    9.
    发明申请
    Method of making synthetic hydrophilic polymers and products resulting therefrom 有权
    制备合成亲水性聚合物的方法及由此产生的产物

    公开(公告)号:US20020193531A1

    公开(公告)日:2002-12-19

    申请号:US10193578

    申请日:2002-07-11

    IPC分类号: C08F008/12

    摘要: The present invention involves a method of making a multiblock copolymer containing two or more types of sequences of derivatives of acrylic acid with at least one derivative being acrylic acid salt and at least one being acrylamide. The method includes: (e) in sequence, a first step being a catalytic reaction of nitrile groups in polyacrylonitrile dissolved in an inorganic aqueous solvent of polyacrylonitrile; and, (f) at least one subsequent step being at least one catalytic reaction of nitrile groups in absence of polyacrylonitrile solvents. The present invention also pertains to the products resulting from the method.

    摘要翻译: 本发明涉及制备含有丙烯酸衍生物的两种或更多种类型的多嵌段共聚物的方法,至少一种衍生物是丙烯酸盐,至少一种是丙烯酰胺。 该方法包括:(e)顺序地,第一步是溶解在聚丙烯腈的无机水性溶剂中的聚丙烯腈中的腈基的催化反应; 和(f)至少一个后续步骤是在不存在聚丙烯腈溶剂的情况下进行至少一个腈基的催化反应。 本发明还涉及由该方法得到的产品。

    Production and use of novel alkoxylated monoesters
    10.
    发明申请
    Production and use of novel alkoxylated monoesters 有权
    新型烷氧基化单酯的生产和使用

    公开(公告)号:US20030181600A1

    公开(公告)日:2003-09-25

    申请号:US10104723

    申请日:2002-03-21

    IPC分类号: C08F008/12

    摘要: Described is an alkoxylated composition that comprises a family of trans carbon-carbon double bond free compositions that generally have melting points that range from 30-80 null C., preferably with melting points between 55-58null C. and with a solubility profile compatible with a broad range of cosmetic and industrial chemical bases. At room temperature (null20 null C.), this family of compositions varies from pourable liquids, to soft creams, to pasty waxes, to a brittle hard material. The composition may be blended with different melting point components within the family to form other products with selected melting points and specific physical properties or feel. These compounds, whether used pure or when combined with other carrier and vehicle components (including other additives, thickeners or binders) can form excellent carrier and vehicles for delivery of compositions for use in the cosmetic, personal care and/or pharmaceutical field, including the cosmeceutical field where cosmetic compositions also provide pharmaceutical or other therapeutic benefits.

    摘要翻译: 描述了一种烷氧基化组合物,其包含通常具有范围为30-80℃,优选熔点在55-58℃之间的熔点并具有相溶性的溶解度曲线的反式碳 - 碳双键组合族 拥有广泛的化妆品和化工基地。 在室温(〜20℃)下,这种组合物从倾倒液体到柔软的乳膏,糊状蜡,脆性硬质材料都不同。 组合物可以与家族内的不同熔点组分混合以形成具有选定熔点和特定物理性质或感觉的其它产物。 这些化合物无论是纯粹使用还是与其他载体和载体组分(包括其它添加剂,增稠剂或粘合剂)组合都可以形成用于递送用于化妆品,个人护理和/或制药领域的组合物的优良载体和载体,包括 化妆品组合物还提供药物或其它治疗益处的药妆领域。