Flexible ceramic coatings for metals and methods of making same

    公开(公告)号:US12202769B2

    公开(公告)日:2025-01-21

    申请号:US18124231

    申请日:2023-03-21

    Abstract: Bulk paint and ceramic powder systems, methods of forming same, and methods of forming a flexible ceramic coating on a metal substrate are disclosed. The systems may include a ceramic composition having between 2 to 30 weight percent of an alkali metal oxide, such as K2O, Na2O, and Li2O or mixtures thereof, between 10 to 74 weight percent SiO2, and between 23 to 79 weight percent B2O3. Additives that are nonwetting with molten metals, such as boron nitride, provide durable coatings for metal processing operations. The ceramic composition may include less than 5 weight percent additional metal oxides. The bulk paint system further may include water and a cellulosic suspension agent to form a bulk paint. The ceramic powder system may be processed to form a uniform powder. The bulk paint or uniform powder may be applied to a metal substrate, such as a ferrous metal substrate, dried, and heated to form a flexible coating on the metal substrate.

    ENAMEL COMPOSITION, METHOD FOR PREPARING ENAMEL COMPOSITION, AND COOKING APPLIANCE

    公开(公告)号:US20200270170A1

    公开(公告)日:2020-08-27

    申请号:US16796066

    申请日:2020-02-20

    Abstract: An enamel composition, a method for preparing an enamel composition, and a cooking appliance are provided. The enamel composition may include 15 to 50 wt % of phosphorus pentoxide (P2O5); 1 to 20 wt % of silicon dioxide (SiO2); 1 to 20 wt % of boron oxide (B2O3); 5 to 20 wt % of one or more of lithium superoxide (Li2O), sodium oxide (Na2O), or potassium oxide (K2O); 1 to 5 wt % of one or more of sodium fluoride (NaF), calcium fluoride (CaF2), or aluminum fluoride (AlF3); 1 to 35 wt % of one or more of magnesium oxide (MgO), barium oxide (BaO), or calcium oxide (CaO); and 5 to 30 wt % of one or more of titanium dioxide (TiO2), vanadium pentoxide (V2O5), molybdenum trioxide (MoO3), or iron oxide (Fe2O3). With such an enamel composition, cleaning may be performed at a low temperature for thermal decomposition, and contaminants, such as fat, may be more completely removed.

    FLEXIBLE CERAMIC COATINGS FOR METALS AND METHODS OF MAKING SAME

    公开(公告)号:US20190263714A1

    公开(公告)日:2019-08-29

    申请号:US15906361

    申请日:2018-02-27

    Abstract: Bulk paint and ceramic powder systems, methods of forming same, and methods of forming a flexible ceramic coating on a metal substrate are disclosed. The systems may include a ceramic composition having between 2 to 30 weight percent of an alkali metal oxide, such as K2O, Na2O, and Li2O or mixtures thereof, between 10 to 74 weight percent SiO2, and between 23 to 79 weight percent B2O3. Additives that are nonwetting with molten metals, such as boron nitride, provide durable coatings for metal processing operations. The ceramic composition may include less than 5 weight percent additional metal oxides. The bulk paint system further may include water and a cellulosic suspension agent to form a bulk paint. The ceramic powder system may be processed to form a uniform powder. The bulk paint or uniform powder may be applied to a metal substrate, such as a ferrous metal substrate, dried, and heated to form a flexible coating on the metal substrate.

    DOUBLE GLASS COATED TANK FOR HIGH TEMPERATURE WATER HEATERS

    公开(公告)号:US20190093921A1

    公开(公告)日:2019-03-28

    申请号:US15732140

    申请日:2017-09-25

    Inventor: Claude Lesage

    Abstract: A double glass coated steel tank for a high temperature water heater and its method of fabrication is described. The tank is constructed of steel welded parts and fittings are secured to the tank without the presence of sharp edges being formed on the inner surface of the tank not to form any weakness in the composite glass coating to be applied. A first water resistant base coat of cobalt glass enriched with ZIRCON (trademark) is applied to the inner surface and the tank is heat fired at a high temperature in the order of about 1600 degrees F. A second high temperature water resistant glass coat, having a fine gas bubble size not exceeding 10 microns, is applied over the first coat and the tank is heat fired a second time. The composite glass coating thus formed is highly water and corrosion resistant in a water environment of up to at least 190 degrees F.

    Roll member having glass surface and method for manufacturing same
    7.
    发明授权
    Roll member having glass surface and method for manufacturing same 失效
    具有玻璃表面的辊组件及其制造方法

    公开(公告)号:US5237747A

    公开(公告)日:1993-08-24

    申请号:US732874

    申请日:1991-07-19

    Inventor: Mikio Nakashima

    CPC classification number: F16C13/00 Y10T29/4956 Y10T29/49563

    Abstract: A roll member of metal body is coated with a smooth glass layer sprayed thereon. The invention is also directed to a method for manufacturing a roll member of metal body having a glass surface, including preheating the surface of the metal body which is subject to a blast treatment to 200.degree..about.600.degree. C. with or without a stainless undercoat layer on the blast-treatment surface, spraying a glass material onto the surface of the metal body, and grinding the sprayed glass surface to form a smooth surface.

    Enamel frits for sheet steel with improved bonding
    8.
    发明授权
    Enamel frits for sheet steel with improved bonding 失效
    用于具有改善粘合的钢板的搪瓷玻璃料

    公开(公告)号:US4847218A

    公开(公告)日:1989-07-11

    申请号:US167222

    申请日:1988-03-11

    CPC classification number: C03C8/08 C03C8/06 C23D5/04

    Abstract: An enamel frit which provides improved bonding at stoving temperatures below 800.degree. C. after the frit has been stoved on unalloyed steel which is capable of being enamelled, the frit containing 1 to 6% by weight, based on the total quantity of the frit, of bonding oxides and the other constituents so chosen that the following equation is fulfilled: ##EQU1## in which the deviation from the ratio 1:1:1 is at most .+-.8% for each of the monovalent atoms, divalent atoms and pentavalent atoms.The enamel frits according to the invention being useful for electrostatic powder application.

    Abstract translation: 一种搪瓷玻璃料,其在烘烤温度低于800℃时,在玻璃料已经被烧结在能够被搪瓷的非合金钢上,其提供了基于玻璃料总量的1至6重量%的玻璃料, 键合氧化物和其他成分如此选择,使得满足以下等式:SIGMA单价原子+2个SIGMA二价原子 - SIGMA氟原子 - SIGMA五价原子= SIGMA三价原子= SIGMA四价原子,其中偏离比例1: 对于每个一价原子,二价原子和五价原子,1:1为至多+/- 8%。 根据本发明的釉料玻璃料可用于静电粉末涂覆。

    Process for electrostatically spraying inorganic powders
    9.
    发明授权
    Process for electrostatically spraying inorganic powders 失效
    无机粉末静电喷涂工艺

    公开(公告)号:US4659586A

    公开(公告)日:1987-04-21

    申请号:US787834

    申请日:1985-10-16

    CPC classification number: B05D1/06 C23D5/04 B05D2202/00

    Abstract: In the electrostatic spraying on metal substrates of mixtures of different inorganic powders which differ in density, particle size and electrical resistance, the improvement which comprises first forming uniform agglomerates as the different powders, and then spraying the uniform agglomerates. This prevents color variation due to separation of different powders.

    Abstract translation: 在对密度,粒度和电阻不同的不同无机粉末的混合物的金属基材上进行静电喷涂,其改进包括首先形成作为不同粉末的均匀凝聚体,然后喷涂均匀的附聚物。 这可以防止由于不同粉末的分离引起的颜色变化。

    Apparatus for applying internal coatings in hot vessels
    10.
    发明授权
    Apparatus for applying internal coatings in hot vessels 失效
    用于在热容器中涂覆内部涂层的装置

    公开(公告)号:US4538543A

    公开(公告)日:1985-09-03

    申请号:US668594

    申请日:1984-11-05

    Inventor: Erwin J. Nunlist

    CPC classification number: C23D5/04 B05B13/0627 C23D11/00

    Abstract: The present apparatus facilitates feeding a particulate vitreous material, such as glass or enamel, into a horizontally rotating tubular article, such as a tank or vessel, heated to the fusion point of the vitreous material, usually temperatures of 1500.degree. F. or above, to coat the article with a fused coating. The present boom is comprised of a rigid elongated outer tube having a downstream end and an upstream end, the downstream end is adapted to be directed into the interior of the article that is to be coated. The elongated outer tube encloses an elongated, rigid feed tube, suitably concentrically positioned therein. The feed tube has a means of receiving and transporting a supply of finely divided vitreous material, e.g., glass frit, therethrough. A distributing means such as a nozzle or spray head, is positioned in the downstream end of the outer tube and internally connected to the feed tube. The apparatus has internal cooling ducts, formed by an elongated, rigid tube positioned intermediate to the feed tube and the outer tube, preferably aligned concentrically with each. The ducts facilitate circulation of a supply of cooling medium, such as air, through the boom. The outer portion of the boom is covered with a layer of low mass insulation. The outside of the insulation may suitably be covered with a reflective surface, such as particulate magnesium oxide.

    Abstract translation: 本发明的装置有助于将诸如玻璃或搪瓷之类的颗粒状玻璃质材料进料到经过加热到玻璃质材料的熔点的水平旋转的管状物品(例如罐或容器)中,通常为1500°F或更高的温度, 用熔敷涂层涂上物品。 本吊臂包括具有下游端和上游端的刚性细长外管,下游端适于被引导到待涂覆物品的内部。 细长的外管包围细长的刚性进料管,适当地同心地定位在其中。 进料管具有从其中接收和输送细碎的玻璃质材料例如玻璃料的装置。 诸如喷嘴或喷头的分配装置定位在外管的下游端并且内部连接到进料管。 该设备具有内部冷却管道,其由位于进料管和外管中间的细长刚性管形成,优选与每个管同心对准。 导管促进冷却介质(例如空气)供应通过悬臂的循环。 起重臂的外部部分覆盖有一层低质量的绝缘层。 绝缘体的外部可以适当地被反射表面覆盖,例如颗粒状氧化镁。

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