炭化水素系化合物の製造方法および製造装置

    公开(公告)号:WO2019098227A1

    公开(公告)日:2019-05-23

    申请号:PCT/JP2018/042105

    申请日:2018-11-14

    摘要: 炭化水素系化合物を効率的に製造することが可能な新規な炭化水素系化合物の製造方法を提供する。炭化水素系化合物の製造方法であって、(a)酸素を含むガスを水中に供給し、該水中に存在する酸素に光触媒の存在下にて光を照射して活性酸素を生成させ、これにより活性酸素含有水を準備すること、および(b)該活性酸素含有水と、炭素数1~4のアルコールと、炭化水素系化合物を含む液状物とを混合して、二酸化炭素を含む雰囲気中で衝撃力を加えることを含み、該衝撃力が加えられた混合物における炭化水素系化合物の量が、前記炭化水素系化合物を含む液状物における炭化水素系化合物の量より増加している、製造方法。

    HYDROCARBON PRODUCTION PROCESS
    34.
    发明申请
    HYDROCARBON PRODUCTION PROCESS 审中-公开
    石油生产工艺

    公开(公告)号:WO2016067025A1

    公开(公告)日:2016-05-06

    申请号:PCT/GB2015/053232

    申请日:2015-10-28

    摘要: The invention provides a process for producing a hydrocarbon, which process comprises contacting an organic compound comprising at least one heteroatom with hydrogen in the presence of a solid catalyst, which catalyst comprises: (a) a metal which is palladium, platinum, rhodium, iridium, ruthenium, silver, gold, nickel or copper; and (b) a compound comprising: (i) niobium, tantalum, molybdenum or tungsten; and (ii) oxygen. Further provided is a composition, and a catalyst. Both the compositionand the catalyst comprise (a) a metal which is palladium, platinum, rhodium, iridium, ruthenium, silver, gold, nickel or copper; and (b) a compound comprising: (i) niobium, tantalum, molybdenum or tungsten;and (ii) oxygen. The catalyst is typically a hydrogenolysis catalyst. Itmay for instance be employed as a hydrodeoxygenation (HDO), hydrodesulfurization (HDS) or hydrodenitrogenation(HDN) catalyst, and is usually employed as an HDO catalyst.

    摘要翻译: 本发明提供一种生产烃的方法,该方法包括在固体催化剂存在下使包含至少一个杂原子的有机化合物与氢气接触,该催化剂包括:(a)金属,其为钯,铂,铑,铱 ,钌,银,金,镍或铜; 和(b)化合物,其包含:(i)铌,钽,钼或钨; 和(ii)氧气。 还提供了一种组合物和一种催化剂。 组合物和催化剂都包含(a)钯,铂,铑,铱,钌,银,金,镍或铜的金属; 和(b)包含:(i)铌,钽,钼或钨的化合物;和(ii)氧气。 催化剂通常是氢解催化剂。 例如可用作加氢脱氧(HDO),加氢脱硫(HDS)或加氢脱氮(HDN)催化剂,通常用作HDO催化剂。

    USE OF A METALLOCENE CATALYST TO PRODUCE A POLYALPHA-OLEFIN
    35.
    发明申请
    USE OF A METALLOCENE CATALYST TO PRODUCE A POLYALPHA-OLEFIN 审中-公开
    使用金属催化剂生产聚氨酯烯烃

    公开(公告)号:WO2015181280A1

    公开(公告)日:2015-12-03

    申请号:PCT/EP2015/061815

    申请日:2015-05-28

    IPC分类号: C07C2/30 C08F4/659 C08F10/14

    摘要: The invention relates to the use in an oligomerization reaction performed in the presence of hydrogen and at high temperature of a racemic bridged metallocene catalyst a metallocene compound (A) is represented by the formula R(Cp1)(Cp2) M X1 X2 wherein R is a C1-C20 alkylene bridging group; Cp1 and Cp2 are the same or different substituted or unsubstitued tetrahydroindenyl rings, wherein if substituted, the substitutions may be independent and/or linked to form multicyclic structures; M is a transition metal selected from the group consisting of titanium, zirconium and hafnium; X1 and X2 are independently hydrogen, halogen, hydride radicals, hydrocarbyl radicals, substituted hydrocarbyl radicals, halocarbyl radicals, substituted halocarbyl radicals, silylcarbyl radicals, substituted silylcarbyl radicals, germylcarbyl radicals, substituted germylcarbyl radicals; or both X1 and X2 are joined and bound to the metal atom to form a metallacycle ring containing from 3 to 20 carbon atoms; for the production of polyalpha-olefins.

    摘要翻译: 本发明涉及在氢气存在下和高温下在外消旋桥联金属茂催化剂下进行的低聚反应中的用途,茂金属化合物(A)由式R(Cp1)(Cp2)M X1 X2表示,其中R为 C1-C20亚烷基桥连基团; Cp1和Cp2是相同或不同的取代或未取代的四氢茚基环,其中如果被取代,取代可以是独立的和/或连接形成多环结构; M是选自钛,锆和铪的过渡金属; X 1和X 2独立地是氢,卤素,氢原子,烃基,取代的烃基,卤代烃基,取代的卤代烃基,甲硅烷基,取代的甲硅烷基,锗烷基,取代的环己基羰基; 或者X1和X2两者连接并结合到金属原子上以形成含有3至20个碳原子的金属环; 用于生产聚α-烯烃。

    INTEGRATED BUTANE ISOMERIZATION AND IONIC LIQUID CATALYZED ALKYLATION PROCESSES
    39.
    发明申请
    INTEGRATED BUTANE ISOMERIZATION AND IONIC LIQUID CATALYZED ALKYLATION PROCESSES 审中-公开
    集成的丁烷异构化和离子液体催化的烷基化方法

    公开(公告)号:WO2013039566A1

    公开(公告)日:2013-03-21

    申请号:PCT/US2012/031165

    申请日:2012-03-29

    摘要: Integrated isomerization and ionic liquid catalyzed alkylation processes may comprise integrating ionic liquid alkylation and n-butane isomerization using a common distillation unit for separating an n-butane containing fraction from at least one of an alkylation hydrocarbon phase from an ionic liquid alkylation reactor and an isomerization hydrocarbon stream from an isomerization unit. The n-butane containing fraction may undergo isomerization to provide an isomerization reactor effluent comprising the isomerization hydrocarbon stream. An isobutane containing fraction, separated from at least one of the alkylation hydrocarbon phase and the isomerization hydrocarbon stream, may be recycled from the distillation unit to the ionic liquid alkylation reactor.

    摘要翻译: 综合异构化和离子液体催化的烷基化方法可以包括使用公共蒸馏单元来整合离子液体烷基化和正丁烷异构化,用于从离子液体烷基化反应器的烷基化烃相中至少一个分离含有正丁烷的馏分和异构化 来自异构化单元的烃流。 含有正丁烷的级分可以进行异构化以提供包含异构化烃流的异构化反应器流出物。 与烷基化烃相和异构化烃物流中的至少一个分离的含有异丁烷的级分可以从蒸馏单元再循环到离子液体烷基化反应器中。