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    SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES
    1.
    发明申请
    SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 审中-公开
    硫化有机磷化合物及其在氢化方法中的应用

    公开(公告)号：WO2009091670A1

    公开(公告)日：2009-07-23

    申请号：PCT/US2009/030556

    申请日：2009-01-09

    Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  HEFNER, Robert, E., Jr. ,  TULCHINSKY, Michael, L.

    Inventor： HEFNER, Robert, E., Jr. ,  TULCHINSKY, Michael, L.

    IPC: C07F9/50

    CPC classification number: B01J31/2404 ,  B01J31/2447 ,  B01J31/4046 ,  B01J31/4053 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845 ,  B01J2531/96 ,  B01J2540/32 ,  B01J2540/64 ,  C07F9/5004 ,  C07F9/5018 ,  Y02P20/584

    Abstract: A compound comprising a class of sulfonated triorganophosphine compounds of formula R 1 R 2 P-R 3 [-O-(CH 2 ) n -(SO 3 M)] m , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R 3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R 3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.

    Abstract translation: 包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示 通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。 该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一种或多种相应的醛产物。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少，并改善配体和铑的回收和再循环。

    SYNTHESIS OF CYCLOALKYLDIARYLPHOSPHINES
    5.
    发明申请
    SYNTHESIS OF CYCLOALKYLDIARYLPHOSPHINES 审中-公开
    环己基二磷酸的合成

    公开(公告)号：WO1997041131A1

    公开(公告)日：1997-11-06

    申请号：PCT/US1997007086

    申请日：1997-04-28

    Applicant: ALBEMARLE CORPORATION

    Inventor： ALBEMARLE CORPORATION ,  SENARATNE, K., Pushpananda, A.

    IPC: C07F09/50

    CPC classification number: C07F9/5077 ,  C07F9/5018

    Abstract: Phosphines having two aryl groups and one alkyl-substituted cycloalkyl group bonded to a phosphorus atom are formed by reacting an alkali metal diarylphosphide with a monoalkyl- or polyalkyl-substituted cycloalkyl mesylate or tosylate in which an alkyl group is in the 2-position, in a liquid reaction medium in which these reactants are soluble. This process avoids complications associated with prior known process technology for producing such phosphines. The phosphines are useful as ligands for making noble metal catalysts.

    Abstract translation: 具有两个芳基和一个与磷原子键合的烷基取代的环烷基的膦通过使碱金属二芳基磷化物与单烷基或多烷基取代的环烷基甲磺酸酯或甲苯磺酸酯反应形成，其中烷基在2-位， 这些反应物可溶于其中的液体反应介质。 该方法避免了与用于生产这种膦的现有已知工艺技术相关的并发症。 膦可用作制备贵金属催化剂的配体。

    PROCESS FOR THE HYDROGENATION OF ARYL PHOSPHINES AND PRODUCTS OBTTAINED THEREFROM
    6.
    发明申请
    PROCESS FOR THE HYDROGENATION OF ARYL PHOSPHINES AND PRODUCTS OBTTAINED THEREFROM 审中-公开
    芳烃磷酸氢盐加氢处理方法

    公开(公告)号：WO1993021192A1

    公开(公告)日：1993-10-28

    申请号：PCT/US1993003453

    申请日：1993-04-13

    Applicant: RESEARCH CORPORATION TECHNOLOGIES, INC. ,  ROTHWELL, Ian, Paul ,  YU, S., Joyce

    Inventor： RESEARCH CORPORATION TECHNOLOGIES, INC.

    IPC: C07F09/50

    CPC classification number: C08F8/04 ,  C07F9/5018 ,  C07F9/5027 ,  C07F9/5045 ,  C07F9/5054

    Abstract: A process for making a cycloalkyl phosphine comprising hydrogenating an aryl phosphine in the presence of an effective amount of an aryloxide of a metal selected from the group consisting of niobium and tantalum is disclosed. Cycloalkyl phosphine products of this process, useful as ligands in a complex of a transition metal which acts as a catalyst in the formation of stereoisomers, are also set forth. Furthermore, niobium or tantalum organometallic compounds, generated in this process, useful in the catalytic hydrogenation of aryl phosphines and arene-containing polymers, is also described.

    Abstract translation: 公开了一种制备环烷基膦的方法，包括在有效量的选自铌和钽的金属的芳氧化物存在下氢化芳基膦。 还阐述了该方法的环烷基膦产物，其可用作在形成立体异构体中起催化剂作用的过渡金属络合物中的配体。 此外，还描述了在该方法中产生的用于芳基膦和含芳烃聚合物的催化氢化的铌或钽有机金属化合物。

    CYCLOPROPENYLIDENE-STABILISED PHOSPHENIUM CATIONS
    8.
    发明申请
    CYCLOPROPENYLIDENE-STABILISED PHOSPHENIUM CATIONS 审中-公开
    CYCLOPROPENYL-YLIDENES稳定的磷阳离子

    公开(公告)号：WO2012113393A3

    公开(公告)日：2012-10-18

    申请号：PCT/DE2012100046

    申请日：2012-02-23

    Applicant: STUDIENGESELLSCHAFT KOHLE MBH ,  ALCARAZO MANUEL ,  BRUNS HANS ,  PETUSKOVA JEKATERINA

    Inventor： ALCARAZO MANUEL ,  BRUNS HANS ,  PETUSKOVA JEKATERINA

    IPC: C07F9/02

    CPC classification number: C07F9/5018 ,  B01J31/2404 ,  B01J2231/4211 ,  B01J2231/52 ,  B01J2531/18 ,  B01J2531/822 ,  B01J2531/847 ,  C07D311/94 ,  C07F1/12 ,  C07F9/02 ,  C07F9/50 ,  C07F9/5022 ,  C07F15/00 ,  C07F15/0073 ,  C07F15/0093

    Abstract: The invention relates to phosphenium compounds of general formula (I), where R, R1, R2, R3 and R4 are identical or different and stand for a linear or branched C1-C6 alkyl radical that may optionally be substituted, or R1 and R2 and/or R3 and R4 are bonded to each other, forming a ring, R5 and R6 stand for a saturated or unsaturated branched or linear alkyl group, alkenyl group or aryl group that may have suitable substituents, including hetero atoms from substituents, a hetero atom-containing hydrocarbon group that may have suitable substituents, and the radicals R5 and R6 may form a ring that may be 4-20-membered, saturated or unsaturated, alicyclic or heteroalicyclic and may have suitable substituents, and X­¯ stands for an anion. The invention also relates to a method for preparing said compounds, and to the use of said compounds in metal complexes that can be used as catalysts in organic synthesis.

    Abstract translation: 存在具有（I）中的R1要求保护的通式phosphenium化合物，R2，R3和R4是可任选被取代的相同或不同，表示直链或支链的C1-C6烷基，或R1和R2，和 或者R3和R4形成环的/相互连接的，R5和R6可以代表饱和或不饱和，支链或直链烷基，链烯基，芳基合适的取代基，包括从取代基的杂原子具有一个烃基杂原子包含的，所述 可具有合适的取代基，并且所述基团可以形成环R5和R6，其可以4-至20元饱和或不饱和的，脂环族或杂脂环基，并且可以具有适当的取代基，X表示阴离子，它们的制备方法 ，以及这些化合物在可用作有机合成中催化剂的金属配合物中的用途 可以。

    BICYCLIC MONOPHOSPHINES
    10.
    发明申请
    BICYCLIC MONOPHOSPHINES 审中-公开
    双相单磷酸二氢

    公开(公告)号：WO2009138708A1

    公开(公告)日：2009-11-19

    申请号：PCT/GB2008/001680

    申请日：2008-05-15

    Applicant: UNIVERSITY OF NEWCASTLE UPON TYNE ,  DOHERTY, Simon ,  SMYTH, Catherine ,  KNIGHT, Julian

    Inventor： DOHERTY, Simon ,  SMYTH, Catherine ,  KNIGHT, Julian

    IPC: C07F9/50 ,  C07F9/53 ,  C07F15/00 ,  C07B37/04 ,  C07B43/04

    CPC classification number: C07F9/5018 ,  C07B37/04 ,  C07B43/04 ,  C07F9/532 ,  C07F15/006 ,  C07F15/0066

    Abstract: A compound of formula (I): wherein: R P1 and R P2 are independently selected from C 3-12 alkyl groups; R C is a C 5-6 aryl group, optionally substituted by one or more groups selected from: C 1-7 alkyl, C 1-7 alkoxy, halo, NH 2 , C 1-7 alkylamino, di-C 1-7 alkylamino, and C 5-6 aryl; R A1 and R A2 are independently selected from H, Cl, and an optionally substituted group selected from: C 1-7 alkyl, C 1-7 alkoxy, C 1-7 alkylthio and C 5-6 aryl, wherein the optional substituents are selected from: C 1-7 alkyl, C 1-7 alkoxy, halo, NH 2 , C 1-7 alkylamino, di-C 1-7 alkylamino, and C 5-6 aryl.

    Abstract translation: 式（I）的化合物：其中：RP1和RP2独立地选自C 3-12烷基; RC是任选被一个或多个选自以下的基团取代的C 5-6芳基：C 1-7烷基，C 1-7烷氧基，卤素，NH 2，C 1-7烷基氨基，二-C 1-7烷基氨基和C 5-6芳基; RA1和RA2独立地选自H，Cl和任选取代的基团，其选自：C 1-7烷基，C 1-7烷氧基，C 1-7烷硫基和C 5-6芳基，其中任选取代基选自：C 1-7 烷基，C 1-7烷氧基，卤素，NH 2，C 1-7烷基氨基，二-C 1-7烷基氨基和C 5-6芳基。

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