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公开(公告)号:US09295945B2
公开(公告)日:2016-03-29
申请号:US13356203
申请日:2012-01-23
申请人: Satoshi Matsueda , Akimasa Hirai , Kenichi Taki , Keiichi Narita , Asuka Hori , Masahiro Kusaka
发明人: Satoshi Matsueda , Akimasa Hirai , Kenichi Taki , Keiichi Narita , Asuka Hori , Masahiro Kusaka
IPC分类号: B01J23/00 , B01J25/00 , B01J21/00 , B01J29/00 , B01J31/00 , B01J23/10 , B01D53/94 , B01J23/63 , B01J35/00 , B01J37/00 , B01J37/03 , F01N3/08 , F01N3/10
CPC分类号: B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/2068 , B01D2255/407 , B01D2255/908 , B01J23/002 , B01J23/63 , B01J35/002 , B01J37/0009 , B01J37/031 , B01J2523/00 , F01N3/0864 , F01N3/10 , F01N2370/02 , Y02T10/20 , Y02T10/22 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/822 , B01J2523/47 , B01J2523/824 , B01J2523/828 , B01J2523/3725 , B01J2523/69 , B01J2523/41
摘要: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more rare-earth elements other than cerium and/or compounds thereof interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles, wherein a spectrum of a characteristic X-ray intensity for one of the rare-earth element(s) and a spectrum of a characteristic X-ray intensity for one of the precious metal element(s) that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient of 0.68 or more.
摘要翻译: 废气净化催化剂包括第一颗粒的储氧材料,一个或多个除铈之外的稀土元素的第二颗粒和/或介于第一颗粒之间的化合物,以及介于第一颗粒之间的一种或多种贵金属元素的第三颗粒 第一颗粒,其中稀土元素之一的特征X射线强度的光谱和贵金属元素之一的特征X射线强度的光谱是通过执行 使用沿着500nm长度的能量色散X射线光谱法的线分析具有0.68以上的相关系数。
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公开(公告)号:US08741799B2
公开(公告)日:2014-06-03
申请号:US13305255
申请日:2011-11-28
申请人: Satoshi Matsueda , Akimasa Hirai , Kenichi Taki , Yuji Yabuzaki
发明人: Satoshi Matsueda , Akimasa Hirai , Kenichi Taki , Yuji Yabuzaki
CPC分类号: B01D53/944 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/2042 , B01D2255/2092 , B01D2255/407 , B01D2255/9022 , B01D2255/908 , B01D2255/9202 , B01J23/58 , B01J27/053 , B01J31/26 , B01J35/023 , B01J37/0215 , B01J37/0219 , B01J37/0244 , F01N2370/02 , F01N2510/06 , F01N2510/0684 , Y02T10/22
摘要: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer facing the substrate and including a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope. Another exhaust gas-purifying catalyst includes a substrate, and a catalytic layer formed on the substrate using slurry containing a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope.
摘要翻译: 废气净化催化剂包括基材和面向基材的催化剂层,并且包含贵金属,氧化铝,储氧材料和平均粒径在0.01以下的碱土金属的硫酸盐 通过使用扫描型电子显微镜观察得到的平均粒径为0.70μm。 另一种废气净化催化剂包括基材和使用含有贵金属,氧化铝,储氧材料和平均粒径落在一定范围内的碱土金属硫酸盐的浆料在基材上形成的催化剂层 为0.01〜0.70μm,通过使用扫描型电子显微镜观察得到的平均粒径。
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公开(公告)号:US08680004B2
公开(公告)日:2014-03-25
申请号:US13006352
申请日:2011-01-13
申请人: Ichiro Kitamura , Akimasa Hirai , Kenichi Taki
发明人: Ichiro Kitamura , Akimasa Hirai , Kenichi Taki
CPC分类号: B01J23/63 , B01D53/945 , B01D2255/1023 , B01D2255/1025 , B01D2255/2042 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/2068 , B01D2255/20715 , B01D2255/2092 , B01D2255/407 , B01D2255/50 , B01D2255/9022 , B01J23/002 , B01J37/0234 , B01J37/0244 , B01J37/0246 , B01J2523/00 , F01N2510/063 , F01N2510/0682 , Y02T10/22 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/36 , B01J2523/3718 , B01J2523/3725
摘要: Provided is an exhaust gas-purifying catalyst excelling in an exhaust gas-purifying performance. The exhaust gas-purifying catalyst contains a substrate, and a catalyst layer formed on the substrate and containing a precious metal and praseodymium.
摘要翻译: 提供了排气净化性能优异的废气净化用催化剂。 废气净化催化剂含有基材和形成在基材上并含有贵金属和镨的催化剂层。
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公开(公告)号:US08569198B2
公开(公告)日:2013-10-29
申请号:US13402770
申请日:2012-02-22
申请人: Sho Hoshino , Akimasa Hirai , Kenichi Taki , Keiichi Narita , Satoshi Matsueda , Asuka Hori , Masahiro Kusaka
发明人: Sho Hoshino , Akimasa Hirai , Kenichi Taki , Keiichi Narita , Satoshi Matsueda , Asuka Hori , Masahiro Kusaka
IPC分类号: B01J27/053
CPC分类号: B01D53/9422 , B01D2255/10 , B01D2255/1021 , B01D2255/1023 , B01D2255/2042 , B01D2255/2063 , B01D2255/2065 , B01D2255/908 , B01D2257/404 , B01J23/002 , B01J23/58 , B01J23/63 , B01J35/002 , B01J35/023 , B01J35/04 , B01J37/0009 , B01J37/031 , B01J2523/00 , F01N3/10 , B01J2523/36 , B01J2523/3712 , B01J2523/48
摘要: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more alkaline-earth metal elements and/or compounds thereof interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles. A spectrum of a first characteristic X-ray intensity for one of the one or more alkaline-earth metal elements and a spectrum of a second characteristic X-ray intensity for one of the one or more precious metal elements that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient σ(AE,PM) of 0.70 or more.
摘要翻译: 废气净化催化剂包括第一颗粒的储氧材料,介于第一颗粒之间的一种或多种碱土金属元素和/或其化合物的第二颗粒和介于第一颗粒之间的一种或多种贵金属元素的第三颗粒 粒子。 一种或多种碱土金属元素之一的第一特征X射线强度的光谱和通过执行线获得的一种或多种贵金属元素之一的第二特征X射线强度的光谱 使用能量色散X射线光谱分析法,沿着500nm的长度,相关系数σ(AE,PM)为0.70以上。
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公开(公告)号:US07998896B2
公开(公告)日:2011-08-16
申请号:US11997430
申请日:2006-07-24
申请人: Ichiro Kitamura , Kenichi Taki , Akimasa Hirai
发明人: Ichiro Kitamura , Kenichi Taki , Akimasa Hirai
CPC分类号: B01D53/945 , B01D2255/102 , B01D2255/407 , B01J23/63 , B01J35/0006 , B01J37/0244 , F01N3/28 , F01N2510/065 , Y02T10/22
摘要: An exhaust gas purifying catalyst having a good ignition performance is provided. The exhaust gas purifying catalyst 1 includes a catalyst substrate 3 and a catalyst coating layer 5 which contains a noble metal and a refractory inorganic oxide and is formed on the catalyst substrate. The exhaust gas purifying catalyst is characterized in that the catalyst coating layer 5 includes an upstream portion 11 located upstream and a downstream portion 13 located downstream in a flow direction of an exhaust gas. The upstream portion 11 has a layered structure including an upstream portion inside layer 17 and an upstream portion outside layer 15. The upstream portion inside layer contains a cerium-zirconium composite oxide in which a relative proportion of CeO2 is 50 to 95 wt %, as the refractory inorganic oxide, and the upstream portion outside layer 15 and the downstream portion 13 contain a cerium-zirconium composite oxide in which a relative proportion of ZrO2 is 50 to 95 wt %, as the refractory inorganic oxide.
摘要翻译: 提供具有良好点火性能的废气净化催化剂。 废气净化催化剂1包括催化剂基板3和含有贵金属和耐火无机氧化物并形成在催化剂基板上的催化剂涂层5。 废气净化催化剂的特征在于,催化剂涂层5包括位于上游的上游部分11和位于排气流动方向下游的下游部分13。 上游部分11具有包括上游部分内层17和上游部分外侧层15的层状结构。上游部分内层含有CeO 2的相对比例为50〜95重量%的铈锆复合氧化物,如 耐火无机氧化物,上游侧外层15和下游部13含有ZrO 2的相对比例为50〜95重量%的铈 - 锆复合氧化物作为耐火无机氧化物。
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公开(公告)号:US20090275468A1
公开(公告)日:2009-11-05
申请号:US12067837
申请日:2006-10-04
申请人: Kenichi Taki , Akimasa Hirai , Ichiro Kitamura
发明人: Kenichi Taki , Akimasa Hirai , Ichiro Kitamura
CPC分类号: B01J37/0244 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/20715 , B01D2255/2092 , B01J23/40 , B01J23/464 , B01J23/63
摘要: An exhaust gas purifying catalyst is provided which includes a catalyst substrate and a catalyst coating layer. The catalyst coating layer is formed on the catalyst substrate and contains a noble metal and a refractory inorganic oxide. The catalyst coating layer has a layered structure including an A-layer and a B-layer. The A-layer contains Pd and Pt as the noble metal in a weight ratio of 3:1 to 20:1. The B-layer includes Rh as the noble metal.
摘要翻译: 提供了一种废气净化催化剂,其包括催化剂基质和催化剂涂层。 催化剂涂层形成在催化剂基材上并含有贵金属和耐火无机氧化物。 催化剂涂层具有包括A层和B层的层状结构。 A层含有Pd和Pt作为贵金属,重量比为3:1至20:1。 B层包括Rh作为贵金属。
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公开(公告)号:US20090209408A1
公开(公告)日:2009-08-20
申请号:US12426050
申请日:2009-04-17
申请人: Ichiro KITAMURA , Akimasa Hirai , Kenichi Taki
发明人: Ichiro KITAMURA , Akimasa Hirai , Kenichi Taki
CPC分类号: B01D53/945 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/2042 , B01D2255/206 , B01D2255/407 , B01D2255/50 , B01D2255/902 , B01D2255/9022 , B01D2255/908 , B01D2255/912 , B01J23/002 , B01J23/63 , B01J27/053 , B01J37/0244 , B01J37/0246 , B01J2523/00 , Y02T10/22 , B01J2523/25 , B01J2523/31 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/822 , B01J2523/824
摘要: A high exhaust gas-purifying efficiency is achieved. An exhaust gas-purifying catalyst includes a substrate, an oxygen storage layer covering the substrate and including an oxygen storage material, and a catalytic layer covering the oxygen storage layer and including palladium, rhodium and a carrier supporting them, the catalytic layer having a precious metal concentration higher than that of the oxygen storage layer.
摘要翻译: 实现了高废气净化效率。 一种废气净化用催化剂,具备:基材,覆盖该基材的氧储存层和含有储氧材料的催化剂层,以及覆盖该氧储存层的催化剂层,其包含钯,铑和负载有载体的催化剂层, 金属浓度高于储氧层。
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公开(公告)号:US20090181847A1
公开(公告)日:2009-07-16
申请号:US12402419
申请日:2009-03-11
申请人: Yuji YABUZAKI , Akimasa HIRAI , Kenichi TAKI
发明人: Yuji YABUZAKI , Akimasa HIRAI , Kenichi TAKI
CPC分类号: B01J37/0244 , B01D53/945 , B01D2255/1023 , B01D2255/1025 , B01D2255/9022 , B01D2255/912 , B01D2257/702 , B01J23/40 , B01J23/63 , B01J29/068 , B01J37/0234 , B01J37/0246 , F01N3/28 , F01N2510/06 , Y02T10/22
摘要: Decreasing HC emission is made possible. An exhaust gas-purifying catalyst includes a substrate, a hydrocarbon-adsorbing layer covering the substrate, and a catalytic layer covering the hydrocarbcn-adsorbing layer. The catalytic layer includes a layered structure of a first catalytic layer including a precious metal and a carrier supporting it, and a second catalytic layer including the same precious metal as the precious metal of the first catalytic layer and a carrier supporting it and having a concentration of the precious metal higher than that in the first catalytic layer.
摘要翻译: 降低HC排放成为可能。 废气净化催化剂包括基材,覆盖基材的烃吸附层和覆盖烃吸附层的催化剂层。 催化剂层包括含有贵金属和负载载体的载体的第一催化剂层和包含与第一催化剂层的贵金属相同的贵金属的第二催化剂层和载体,并具有浓度 的贵金属比第一催化剂层高。
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公开(公告)号:US20080081762A1
公开(公告)日:2008-04-03
申请号:US11791141
申请日:2004-11-25
申请人: Ichiro Kitamura , Akimasa Hirai , Kenichi Taki
发明人: Ichiro Kitamura , Akimasa Hirai , Kenichi Taki
IPC分类号: B01J23/46
CPC分类号: B01J23/63 , B01D53/945 , B01J23/40 , B01J23/464 , B01J35/0006 , B01J37/0242 , B01J37/0244 , Y02T10/22
摘要: This is to provide a catalyst for purifying exhaust gases, catalyst which are good in terms of the purifying performance. A catalyst according to the present invention for purifying exhaust gases comprises: a catalytic support substrate (1); a first catalytic layer (2) having a first loading layer formed on an upstream side of the catalytic support substrate (1) and made of a fire-resistant inorganic oxide, and Rh loaded in the first loading layer; a second catalytic layer (3) having a second loading layer formed on a surface of the catalytic support substrate (1) on an downstream side of the first catalytic layer (2) and made of a fire-resistant inorganic oxide, and Pd and/or Pt loaded in the second loading layer; and a third catalytic layer (4) having a third loading layer formed on a surface of the second catalytic layer (3) and made of a fire-resistant inorganic oxide, and Rh loaded in the third loading layer; and is characterized in that: the first catalytic layer (2) is such that, when taking Rh loaded in the first catalytic layer as 100% by weight, Rh is loaded in an amount of 70% by weight or more within such a range that the distance from the surface is 20 μm; and the loading amount of Rh loaded in the first catalytic layer (2) is from 1.5 to 15 times as much as the loading amount of Rh loaded in the third loading layer. Because of the fact that Rh is loaded in a great loading amount in the superficial layer portion on an upstream side of exhaust-gas flow, it turns into a catalyst for purifying exhaust gases, catalyst which is good in terms of the purifying characteristics.
摘要翻译: 这是为了提供净化废气的催化剂,在净化性能方面优异的催化剂。 根据本发明的用于净化废气的催化剂包括:催化支撑基材(1); 第一催化剂层(2),其具有形成在所述催化剂载体基材(1)的上游侧并由耐火无机氧化物制成的第一载体层,以及负载在所述第一载体层中的Rh; 第二催化剂层(3),其在第一催化剂层(2)的下游侧上形成有由耐火无机氧化物制成的催化支撑基材(1)的表面上的第二载体层,以及Pd和/ 或Pt装载在第二加载层中; 以及第三催化剂层(4),其具有形成在所述第二催化剂层(3)的表面上并由耐火无机氧化物制成的第三负载层,以及负载在所述第三负载层中的Rh; 其特征在于:第一催化剂层(2)使得当将负载在第一催化剂层中的Rh作为100重量%时,Rh的负载量为70重量%以上, 表面距离为20 mum; 并且负载在第一催化剂层(2)中的负载量为负载在第三装载层中的负载量的1.5〜15倍。 由于Rh在排气流的上游侧的表层部中负载量大,所以成为净化特性良好的废气净化用催化剂。
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公开(公告)号:US20060142151A1
公开(公告)日:2006-06-29
申请号:US11318190
申请日:2005-12-23
申请人: Kenichi Taki , Akimasa Hirai , Hiromasa Suzuki
发明人: Kenichi Taki , Akimasa Hirai , Hiromasa Suzuki
IPC分类号: B01J23/10
CPC分类号: B01J23/63 , B01D53/945 , B01D2255/102 , B01D2255/2042 , B01D2255/2063 , B01D2255/407 , B01D2255/9032 , B01D2255/908 , B01J35/0006 , B01J35/04 , B01J37/0248 , Y02T10/22
摘要: An exhaust gas purifying catalyst comprises a substrate having a through hole serving as a passage for exhaust gas; and a catalyst coating layer formed on an internal surface of the through hole. The catalyst coating layer contains: a component (i): a precious metal; and a component (ii): at least one of a Zr oxide, a Ce oxide and a ZrCe mixed oxide. On an upstream portion of the passage, an oxide equivalent weight of Zr is within a range of 51-100 wt % of an oxide equivalent weight of Zr and Ce contained in the component (ii). On a downstream portion of the passage, the component (ii) includes at least one of a Ce oxide and a ZrCe mixed oxide in which an oxide equivalent weight of Ce is within a range of 58-100 wt % of an oxide equivalent weight of Zr and Ce contained in the ZrCe mixed oxide.
摘要翻译: 废气净化催化剂包括具有用作废气通道的通孔的基板; 以及形成在通孔的内表面上的催化剂涂层。 催化剂涂层含有:(i)成分:贵金属; 和组分(ii):Zr氧化物,Ce氧化物和ZrCe混合氧化物中的至少一种。 在通道的上游部分,Zr的氧化物当量在组分(ii)中所含的Zr和Ce的氧化物当量重量的51-100重量%的范围内。 在通道的下游部分,组分(ii)包括Ce氧化物和ZrCe混合氧化物中的至少一种,其中氧化物当量的Ce的氧化物当量为58-100重量% 包含在ZrCe混合氧化物中的Zr和Ce。
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