Continuous slurry polymerization process and appparatus
    2.
    发明授权
    Continuous slurry polymerization process and appparatus 有权
    连续淤浆聚合工艺和设备

    公开(公告)号:US06833415B2

    公开(公告)日:2004-12-21

    申请号:US10079226

    申请日:2002-02-19

    IPC分类号: C08F200

    摘要: A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of the first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.

    摘要翻译: 公开了一种用于从包含稀释剂,未反应单体和聚合物固体的聚合流出物连续分离包含稀释剂和未反应单体的液体介质的方法/装置,其包括通过排放阀将淤浆反应器的聚合流出物连续排出并将传输导管 具有锥形底部的第一中间压力闪蒸罐,该锥形底部由基本上直的侧面倾斜的水平面倾斜,该水平面等于或大于浆料/聚合物固体的滑动角度以及直径(d)的出口密封室, 长度(l)以在出口密封室中保持所需体积的浓缩聚合物固体/浆料,以形成压力密封,同时连续地将第一闪蒸罐的浓缩聚合物固体/浆料底部产物的塞流从出口 密封室通过密封室出口减速器,斜面大致直线形成 以等于或大于在较低压力下将约50至100%的惰性稀释剂从其中除去至第二闪蒸罐后残留的聚合物固体的滑动角度等于或大于水平的角度。

    Continuous slurry polymerization volatile removal
    4.
    发明授权
    Continuous slurry polymerization volatile removal 有权
    连续淤浆聚合挥发性去除

    公开(公告)号:US06204344B1

    公开(公告)日:2001-03-20

    申请号:US09313818

    申请日:1999-05-18

    IPC分类号: C08F200

    摘要: A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of said first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.

    摘要翻译: 公开了一种用于从包含稀释剂,未反应单体和聚合物固体的聚合流出物连续分离包含稀释剂和未反应单体的液体介质的方法/装置,其包括通过排放阀将淤浆反应器的聚合流出物连续排出并将传输导管 具有锥形底部的第一中间压力闪蒸罐,该锥形底部由基本上直的侧面倾斜的水平面倾斜,该水平面等于或大于浆料/聚合物固体的滑动角度以及直径(d)的出口密封室, 长度(l),以便在出口密封室中保持所需体积的浓缩的聚合物固体/浆料,以便形成压力密封,同时连续地将所述第一闪蒸罐的浓缩聚合物固体/浆料底部产物的塞流从出口 密封室通过密封室出口减速器,斜面由基本上直的侧面i定义 以等于或大于在约50至100%的惰性稀释剂从其中移除至较低压力的第二闪蒸罐后保留的聚合物固体的滑动角度等于或大于水平角的角度倾斜。

    Method And Apparatus For Reducing Fouling
    5.
    发明申请
    Method And Apparatus For Reducing Fouling 有权
    减少结垢的方法和装置

    公开(公告)号:US20100317812A1

    公开(公告)日:2010-12-16

    申请号:US12483057

    申请日:2009-06-11

    申请人: Thomas W. Towles

    发明人: Thomas W. Towles

    IPC分类号: C08F2/04 B01J19/00

    摘要: Provided herein is a method for operating a slurry polymerization reaction system to reduce, inhibit, and/or prevent fouling in the polymer recovery and separation apparatus, including one or more portions of a high pressure flash tank. The method generally comprises polymerizing a monomer feed in a slurry polymerization reactor in the presence of catalyst and diluent to produce a polymerization effluent; continuously discharging at least a portion of said polymerization effluent from the reactor through a discharge valve; combining a catalyst poison stream with the polymerization effluent downstream of said discharge valve, wherein the catalyst poison stream comprises a catalyst poison that is a gas at standard conditions; and flashing the combination of polymerization effluent and catalyst poison stream in a first flash tank.

    摘要翻译: 本文提供了一种操作淤浆聚合反应系统以减少,抑制和/或防止聚合物回收和分离设备(包括高压闪蒸罐的一个或多个部分)中的结垢的方法。 该方法通常包括在催化剂和稀释剂的存在下在淤浆聚合反应器中聚合单体进料以产生聚合流出物; 连续地将来自反应器的至少一部分聚合流出物排出排出阀; 将催化剂毒物流与所述排放阀下游的聚合流出物混合,其中所述催化剂毒物流包含在标准条件下为气体的催化剂毒物; 并在第一个闪蒸罐中闪烁聚合流出物和催化剂毒物流的组合。

    Continuous slurry polymerization volatile removal
    7.
    发明授权
    Continuous slurry polymerization volatile removal 有权
    连续淤浆聚合挥发性去除

    公开(公告)号:US06800698B2

    公开(公告)日:2004-10-05

    申请号:US10260011

    申请日:2003-03-11

    IPC分类号: C08F200

    摘要: A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of the first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.

    摘要翻译: 公开了一种用于从包含稀释剂,未反应单体和聚合物固体的聚合流出物连续分离包含稀释剂和未反应单体的液体介质的方法/装置,其包括通过排放阀将淤浆反应器的聚合流出物连续排出并将传输导管 具有锥形底部的第一中间压力闪蒸罐,该锥形底部由基本上直的侧面倾斜的水平面倾斜,该水平面等于或大于浆料/聚合物固体的滑动角度以及直径(d)的出口密封室, 长度(l)以在出口密封室中保持所需体积的浓缩聚合物固体/浆料,以形成压力密封,同时连续地将第一闪蒸罐的浓缩聚合物固体/浆料底部产物的塞流从出口 密封室通过密封室出口减速器,斜面大致直线形成 以等于或大于在较低压力下将约50至100%的惰性稀释剂从其中除去至第二闪蒸罐后残留的聚合物固体的滑动角度等于或大于水平的角度。