Process and Apparatus for Optimized Combination of Purification and Separation of MTO Reaction Gas Containing Catalyst Fine Powder
    3.
    发明申请
    Process and Apparatus for Optimized Combination of Purification and Separation of MTO Reaction Gas Containing Catalyst Fine Powder 审中-公开
    用于优化组合含有催化剂细粉末的MTO反应气体的净化和分离的方法和装置

    公开(公告)号:US20130239810A1

    公开(公告)日:2013-09-19

    申请号:US13496286

    申请日:2011-04-13

    Abstract: The invention relates to a process and an apparatus for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder. In particular, the invention provides a process for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder, comprising (a) scrubbing, purifying and cooling the MTO reaction gas containing catalyst fine powder, and separating and recovering the mist entrained in the scrubbed reaction gas and the catalyst fine powder that is not scrubbed off; (b) subjecting the scrubbing liquid containing catalyst fine powder to solid-liquid separation, and the purified scrubbing liquid after separation to repeated use after subsequent heat exchange and stripping treatment; and (c) subjecting the scrubbing liquid containing catalyst fine powder to solid-liquid separation, and further concentrating the scrubbing liquid containing catalyst fine powder after separation before the catalyst fine powder is finally recovered in solid form by centrifugal dewatering or drying. The invention also provides an apparatus for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder.

    Abstract translation: 本发明涉及一种用于优化组合含有催化剂细粉末的MTO反应气体的净化和分离的方法和装置。 特别地,本发明提供了一种用于优化组合含有催化剂细粉末的MTO反应气体的组合的方法,其包括(a)洗涤,纯化和冷却含有催化剂细粉末的MTO反应气体,以及分离和回收夹带在 洗涤反应气体和未被洗涤的催化剂细粉末; (b)使含有催化剂细粉末的洗涤液进行固液分离,然后在后续的热交换和汽提处理之后分离后重复使用的纯化洗涤液; 和(c)将含有催化剂细粉末的洗涤液进行固液分离,并在分离后进一步浓缩含有催化剂细粉末的洗涤液,然后通过离心脱水或干燥最终以固体形式回收催化剂细粉末。 本发明还提供了用于优化组合含有催化剂细粉末的MTO反应气体的净化和分离的装置。

    ENANTIOSELECTIVE CYCLOPROPENATION OF ALKYNES
    4.
    发明申请
    ENANTIOSELECTIVE CYCLOPROPENATION OF ALKYNES 审中-公开
    烷基的选择性环丙基

    公开(公告)号:US20130030170A1

    公开(公告)日:2013-01-31

    申请号:US13364570

    申请日:2012-02-02

    Abstract: The cobalt(II) complex of new D2-symmetric chiral porphyrin 3,5-DiMes-ChenPhyrin, [Co(P2)], has been shown to be a highly effective chiral metalloradical catalyst for enantioselective cyclopropenation of alkynes with acceptor/acceptor-substituted diazo reagents such as α-cyanodiazoacetamides and α-cyanodiazoacetates. The [Co(P2)]-mediated metalloradical cyclopropenation is suitable to a wide range of terminal aromatic and related conjugated alkynes with varied steric and electronic properties, providing the corresponding tri-substituted cyclopropenes in high yields with excellent enantiocontrol of the all-carbon quaternary stereogenic centers. In addition to mild reaction conditions, the Co(II)-based metalloradical catalysis for cyclopropenation features a high degree of functional group tolerance.

    Abstract translation: 新型D2对称手性卟啉3,5-DiMes-ChenPhyrin [Co(P2)]的钴(II)配合物已被证明是一种高效的手性金相催化剂,用于对炔诺酮与对映体/受体取代的对映选择性环丙化 重氮试剂如α-氰基二异氰酸乙酰胺和α-氰基二异氰酸酯。 [Co(P2)]介导的金属偶联环化适用于具有不同空间和电子性质的多种末端芳族和相关的共轭炔,以高产率提供相应的三取代环丙烯,具有优异的全碳季铵化对映体 立体中心。 除了温和的反应条件外,用于环丙烯化的Co(II)基金属离子催化具有高度的官能团耐受性。

    Method and apparatus for micro-hydrocyclone purification for flue gas carbon dioxide capture system
    9.
    发明授权
    Method and apparatus for micro-hydrocyclone purification for flue gas carbon dioxide capture system 有权
    用于烟气二氧化碳捕集系统的微水力旋流器净化方法和装置

    公开(公告)号:US09533247B2

    公开(公告)日:2017-01-03

    申请号:US13984406

    申请日:2011-08-25

    Abstract: Provided are a method and an apparatus for micro-hydrocyclone purification for a flue gas carbon dioxide capture system. The method comprises: performing gas-liquid micro-hydrocylone separation with ultralow pressure drop on scrubbed flue gas, to remove aerosol particulates entrained in the flue gas; performing gas-liquid micro hydrocyclone separation with ultralow pressure drop on off-gas vented from the top of an absorption column, to remove entrained aerosol particulates; performing gas-liquid micro hydrocyclone separation with ultralow pressure drop on cooled regeneration gas, to remove entrained aerosol particulates; and performing liquid-solid and liquid-liquid two-stage micro-hydrocyclone separation on a mixed amine solution lean for carbon dioxide discharged from regeneration column, to remove entrained solid particulates and machine oil. The apparatus comprises: a water scrubbing column, rotation flow separators, liquid-solid micro-hydrocyclone separator sets, a water scrubbing tank, a absorption column, a regeneration column, liquid-solid micro-hydrocyclones and liquid-liquid micro-hydrocyclones.

    Abstract translation: 提供了用于烟道气二氧化碳捕获系统的微水力旋流器净化的方法和装置。 该方法包括:在经过洗涤的烟道气上进行超低压降的气 - 液微水龙胆分离,除去夹带在烟气中的气溶胶微粒; 在从吸收塔顶部排出的废气上进行超低压降的气液微型水力旋流分离器,以除去夹带的气溶胶颗粒物; 在冷再生气体上进行超低压气滴分离,清除夹带的气溶胶微粒; 并在从再生塔排出的稀二氧化碳的混合胺溶液中进行液固两液微旋流分离,除去夹带的固体微粒和机油。 该装置包括:水洗柱,旋转流分离器,液固微型水力旋流分离器组,水洗涤槽,吸收塔,再生塔,液固微流体旋流器和液 - 液微水力旋流器。

    Method and Apparatus for Micro-Hydrocyclone Purification For Flue Gas Carbon Dioxide Capture System
    10.
    发明申请
    Method and Apparatus for Micro-Hydrocyclone Purification For Flue Gas Carbon Dioxide Capture System 有权
    用于烟道气二氧化碳捕集系统的微水力旋流器净化方法和装置

    公开(公告)号:US20140026752A1

    公开(公告)日:2014-01-30

    申请号:US13984406

    申请日:2011-08-25

    Abstract: Provided are a method and an apparatus for micro-hydrocyclone purification for a flue gas carbon dioxide capture system. The method comprises: performing gas-liquid micro-hydrocylone separation with ultralow pressure drop on scrubbed flue gas, to remove aerosol particulates entrained in the flue gas; performing gas-liquid micro hydrocyclone separation with ultralowpressure drop on off-gas vented from the top of an absorption column, to remove entrained aerosol particulates; performing gas-liquid micro hydrocyclone separation with ultralow pressure drop on cooled regeneration gas, to remove entrained aerosol particulates; and performing liquid-solid and liquid-liquid two-stage micro-hydrocyclone separation on a mixed amine solution lean for carbon dioxide discharged from regeneration column, to remove entrained solid particulates and machine oil. The apparatus comprises: a water scrubbing column, rotation flow separators, liquid-solid micro-hydrocyclone separator sets, a water scrubbing tank, a absorption column, a regeneration column, liquid-solid micro-hydrocyclones and liquid-liquid micro-hydrocyclones.

    Abstract translation: 提供了用于烟道气二氧化碳捕获系统的微水力旋流器净化的方法和装置。 该方法包括:在经过洗涤的烟道气上进行超低压降的气 - 液微水龙胆分离,除去夹带在烟气中的气溶胶微粒; 在从吸收塔顶部排出的废气中进行超液压滴下的气液微型水力旋流器分离,以除去夹带的气溶胶颗粒物; 在冷再生气体上进行超低压气滴分离,清除夹带的气溶胶微粒; 并在从再生塔排出的稀二氧化碳的混合胺溶液中进行液固两液微旋流分离,除去夹带的固体微粒和机油。 该装置包括:水洗柱,旋转流分离器,液固微型水力旋流分离器组,水洗涤槽,吸收塔,再生塔,液固微流体旋流器和液 - 液微水力旋流器。

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