Abstract:
TO PRODUCE MELAMINE, UREA AND/OR ITS THERMAL DECOMPOSITION PRODUCTS ARE REACTED AT 220* TO 400*C. IN CONTACT WITH AN ALUMINUM OXIDE HAVING A LARGE SURFACE AREA IN THE PRESENCE OF AMMONIA. THE ALUMINUM OXIDE USED HAS BEEN OBTAINED BY TREATMENT OF HYDROXIDES OF ALUMINUM (WHICH HAVE NOT BEEN PREVIOUSLY CALCINED) WITH UREA AND/OR ITS THERMAL DECOMPOSITION PRODUCTS AT TEMPERATURES OF FROM 150* TO 400*C. THE AVERAGE OF ALUMINUM OXIDE ACTIVATED IN THIS MANNER OVER ALUMINUM OXIDE OBTAINED BY CALCINING ALUMINUM HYDROXIDE CONSIST IN INCREASED UREA CONVERSION AND GREATER ATTRITION RESISTANCE.
Abstract:
The compound Ni5MgAl2(OH)16.CO3.4H2O is precipitated from an aqueous solution containing salts of nickel, magnesium and aluminum with a carbonate or bicarbonate of an alkali metal. After this catalyst precursor has been dried, calcined and reduced with hydrogen a catalyst can be prepared which is suitable for the cracking of hydrocarbons in the presence of steam. In the steam cracking of hydrocarbons the hydrocarbon and the steam may be reacted to form a gas rich in methane in contact with this catalyst at a preheating temperature of less than 300* C.
Abstract:
Berylloaluminosilicates having faujasite structure are described. These beryllium zeolites (Y-zeolites) can have substantially higher Al2O3/SiO2 ratios than the berylliumfree aluminosilicates of similar structure; they can be obtained hydrothermally from aqueous mixtures of the components and can be used instead of the faujasites in industrial processes involving absorption or catalysts.
Abstract translation:描述了具有八面沸石结构的铍铝硅酸盐。 这些铍沸石(Y-沸石)可以具有比类似结构的无铍铝硅酸盐更高的Al 2 O 3 / SiO 2比率; 它们可以由组分的水混合物水热获得,并且可以用于涉及吸收或催化剂的工业过程中的八面沸石。
Abstract:
Catalytic manufacture of melamine from urea by thermal cracking of urea and converting the resulting cracked gases to melamine in the presence of catalysts. The thermal decomposition is carried out in a fluidized bed, the necessary heat being applied by heat exchangers located in the fluidized bed. Conversion of the cracked gases to melamine is effected either in the same fluidized bed, in which case the fluidized solid consists of conventional catalysts, or in a reaction zone remote from said fluidized bed. In the latter case, the solids fluidized consist of catalytically inactive particles, the conversion being carried out in the presence of catalysts in said reaction zone remote from the fluidized bed. In both cases, the urea is fed to the fluidized bed at a point above the heat exchangers.
Abstract:
Gases of various origins which contain carbon monoxide and dioxide and hydrogen, for example the gases obtained by steam reforming or the rich gas process, refinery gases or coal gasification gases are methanized on a nickel catalyst. The object of this reaction is to obtain methane or gases which can be substituted for natural gas. To produce the catalyst, the compound Ni6Al2(OH)16.CO3.4H2O is obtained from aqueous solution. The catalyst is obtained from this compound after drying, calcination and subsequent reduction in a stream of hydrogen, whilst maintaining very specific temperature gradients between the drying stage and the calcination stage.
Abstract:
The double salt Ni6Al2(OH)16 - CO3 - 4H2O is obtained from an aqueous solution containing nickel and aluminum salts by precipitation with alkali metal carbonate or bicarbonate. This double salt (catalyst precursor) is dried, calcined and reduced. There is thus obtained a catalyst which is suitable for the selective hydrogenation of fats and oils.