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    Curable compositions
    1.
    发明授权
    Curable compositions 有权

    公开(公告)号：US10829588B2

    公开(公告)日：2020-11-10

    申请号：US15742675

    申请日：2016-06-22

    Applicant: BASF SE

    Inventor： Friederike Fleischhaker ,  Andrea Misske ,  Christoph Fleckenstein ,  Miran Yu ,  Martin Kaller ,  Uwe Meisenburg

    IPC: C08G59/56 ,  C08G59/58 ,  C08G59/50

    Abstract: A curable composition comprises a) at least one epoxide compound E having at least two epoxide groups; b) at least one amine A having at least two amine hydrogens; and c) at least one acrylic ester U; wherein the epoxide compound E comprises at least one epoxide compound E′, the amine A comprises at least one amine A′, and the acrylic ester U comprises at least one acrylic ester U′ whose Hansen solubility parameters for the dipole forces δp and for the specific interactions δh satisfy the following conditions: ( δ p ⁡ ( U ′ ) - δ p ⁡ ( E ′ ) ) 2 + ( δ h ⁡ ( U ′ ) - δ h ⁡ ( E ′ ) ) 2 ≥ 1.5 ⁢ ⁢ and ( δ p ⁡ ( U ′ ) 2 + δ h ⁡ ( U ′ ) 2 ) - ( δ p ⁡ ( A ′ ) 2 + δ h ⁡ ( A ′ ) 2 ) ≥ 0 . A suitable choice of the Hansen solubility parameters of the constituents ensures that the acrylic ester is incorporated covalently into the curing material, preventing subsequent evaporation of the diluent.

    Method for producing diesters of terephthalic acid with enrichment of recirculated alcohol
    2.
    发明授权
    Method for producing diesters of terephthalic acid with enrichment of recirculated alcohol 有权

    公开(公告)号：US10266477B2

    公开(公告)日：2019-04-23

    申请号：US15513775

    申请日：2015-09-21

    Applicant: BASF SE

    Inventor： Armin Schraut ,  Martin Kaller ,  Rob Bronneberg ,  Jasmin Stammer ,  Martin Das ,  Gerrit Harnischmacher

    IPC: C07C67/08 ,  B01D3/36 ,  B01J19/00 ,  C07C67/58

    Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is conducted through a column in which the organic phase is run counter to at least a portion of the vapor, and the organic phase is collected in the lower region of the column and at least partly passed into the dispersing tank.

    PREPARATION OF C8-C22 ALKYL (METH)ACRYLATES
    4.
    发明申请
    PREPARATION OF C8-C22 ALKYL (METH)ACRYLATES 审中-公开
    C8-C22烷基（甲基）丙烯酸酯的制备

    公开(公告)号：US20160122276A1

    公开(公告)日：2016-05-05

    申请号：US14883803

    申请日：2015-10-15

    Applicant: BASF SE

    Inventor： Andrea MISSKE ,  Hannelore Schirra ,  Christoph Fleckenstein ,  Martin Kaller ,  Ulrik Stengel ,  Mathieu Blanchot ,  Friederike Fleischhaker ,  Ritesh Nair

    IPC: C07C67/02

    CPC classification number: C07C67/58 ,  C07C67/03 ,  C07C69/54

    Abstract: The invention relates to a method of preparing a C8-C22 alkyl (meth)acrylate by transesterification of C1-C2 alkyl (meth)acrylate with a C8-C22 alkanol, said method comprising the steps of(i) reacting C1-C2 alkyl (meth)acrylate with the C8-C22 alkanol in the presence of a particulate potassium phosphate heterogeneous catalyst and a stabilizer thus releasing C1-C2 alkanol,(ii) continuously distilling off the azeotrope of C1-C2 alkyl (meth)acrylate and the C1-C2 alkanol,wherein steps (i) and (ii) are carried out simultaneously until substantially all of the C8-C22 alkanol has reacted,(iii) distilling off unconverted C1-C2 alkyl (meth)acrylate,(iv) washing the C8-C22 alkyl (meth)acrylate-comprising product mixture obtained in steps (i) through (iii) with an aqueous phase to separate off the catalyst and the stabilizer from the product mixture with the aqueous phase and optionally adding a stabilizer,(v) distilling off water from the product mixture,wherein step (iii) may also be effected after step (iv) and together with step (v) and step (v) affords a product having a purity of >98 wt %.

    Abstract translation: 本发明涉及通过C 1 -C 2烷基（甲基）丙烯酸酯与C 8 -C 22烷醇的酯交换反应制备C 8 -C 22烷基（甲基）丙烯酸酯的方法，所述方法包括以下步骤：（ⅰ）使C 1 -C 2烷基（ 甲基）丙烯酸酯与C8-C22烷醇在颗粒状磷酸钾多相催化剂和稳定剂存在下反应，从而释放C1-C2链烷醇，（ii）连续蒸馏出（甲基）丙烯酸C1-C2烷基酯和C1- C 2链烷醇，其中步骤（i）和（ii）同时进行，直到基本上所有的C 8 -C 22烷醇已反应，（iii）蒸馏未转化的（甲基）丙烯酸C 1 -C 2烷基酯，（iv）洗涤C8- 在步骤（i）至（iii）中获得的（甲基）丙烯酸C 22烷基酯产物混合物与水相分离催化剂和稳定剂与产物混合物与水相并任选地加入稳定剂，（v）蒸馏 来自产物混合物的脱水，其中步骤（iii）也可以是ef 在步骤（iv）之后并与步骤（v）和步骤（v）一起得到纯度> 98wt％的产物。

    Acrylate-based monomers for use as reactive diluents in printing formulations
    6.
    发明授权
    Acrylate-based monomers for use as reactive diluents in printing formulations 有权

    公开(公告)号：US10745576B2

    公开(公告)日：2020-08-18

    申请号：US16484896

    申请日：2018-02-09

    Applicant: BASF SE

    Inventor： Christoph Fleckenstein ,  Juergen Baro ,  Erich Beck ,  Martin Kaller ,  Andrea Misske ,  Friederike Fleischhaker

    IPC: C09D11/107 ,  C09D11/101 ,  C09D11/30 ,  B41J11/00 ,  C08L33/14 ,  C08L67/06 ,  C08L75/14

    Abstract: The invention relates to compositions, comprising. a) 1.00 to 65.00% by weight of at least one compound of formula (I), wherein R1, R2, R3, R4 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy-C1-C6-alkyl; R is H or C1-C6-alkyl; X is CR6R7, O, or NR8; R6R7 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy-C1-C6-alkyl; R8 is H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as component A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and having a molecular weight of no more than 500 Dalton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight of at least 700 Dalton, as component D; with the proviso that the amount of components A+B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks.

    Process for preparing isosorbide di(meth)acrylate
    7.
    发明授权
    Process for preparing isosorbide di(meth)acrylate 有权

    公开(公告)号：US10370383B2

    公开(公告)日：2019-08-06

    申请号：US15054506

    申请日：2016-02-26

    Applicant: BASF SE

    Inventor： Andrea Misske ,  Friederike Fleischhaker ,  Christoph Fleckenstein ,  Martin Kaller ,  Ritesh Nair ,  Ulrik Stengel ,  Mathieu Blanchot

    IPC: C07D493/04 ,  C09K8/42 ,  C09K8/44 ,  C08F22/20 ,  C09J4/00

    Abstract: A process for preparing isosorbide di(meth)acrylate by transesterifying alkyl (meth)acrylate with isosorbide, comprising the steps of: (i) reacting alkyl (meth)acrylate with isosorbide in the presence of a catalyst comprising titanium(IV) or zirconium(IV) and a stabilizer in the presence of an azeotroping agent which forms an azeotrope with the alcohol bound in the alkyl (meth)acrylate, (ii) continuously distilling off the azeotrope of azeotroping agent and alcohol, wherein steps (i) and (ii) are conducted simultaneously until the isosorbide has been essentially fully converted, (iii) adding water to the product mixture which comprises isosorbide (meth)acrylate and is obtained in steps (i) and (ii) and removing the hydrolyzate of the catalyst comprising titanium(IV) or zirconium(IV), (iv) distilling unconverted alkyl (meth)acrylate and azeotroping agent out of the product mixture, (v) distilling off water from the product mixture, wherein step (iv) can also be conducted before step (iii) and steps (iv) and (v) can also be conducted in one distillation step.

    Acrylate-based monomers for use as reactive diluents in printing formulations
    9.
    发明授权
    Acrylate-based monomers for use as reactive diluents in printing formulations 有权

    公开(公告)号：US11001723B2

    公开(公告)日：2021-05-11

    申请号：US16484914

    申请日：2018-02-09

    Applicant: BASF SE

    Inventor： Christoph Fleckenstein ,  Juergen Baro ,  Erich Beck ,  Martin Kaller ,  Andrea Misske ,  Friederike Fleischhaker

    IPC: C09D11/107 ,  B41J11/00 ,  B41M5/00 ,  C09D11/101 ,  C09D11/30

    Abstract: The invention relates to compositions, having a) 1.00 to 65.00% by weight of at least one compound of formula (I), wherein R1, R2 are each independently H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; R3, R4, R5 are each independently H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; R6 is H or C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as component A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and 1 having a molecular weight Mw of no more than 500 Dalton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight Mw of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight Mw of at least 700 Dalton, as component D; with the proviso that the amount of components A+B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks.

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