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    Organic polyisocyanates and method of making them
    1.
    发明授权
    Organic polyisocyanates and method of making them 失效
    有机多异氰酸酯及其制备方法

    公开(公告)号：US3912754A

    公开(公告)日：1975-10-14

    申请号：US47612174

    申请日：1974-06-03

    Applicant: BAYER AG

    Inventor： FINDEISEN KURT ,  WAGNER KUNO

    IPC: C07D233/96 ,  C08G18/00 ,  C08G18/78 ,  C08G18/79 ,  C07D49/34

    CPC classification number: C07D233/96 ,  C08G18/7887

    Abstract: Organic polyisocyanates which are a reaction product of an excess of an organic polyisocyanate and hydrocyanic acid have the formula

    in which R represents an aliphatic C2 to C12 cycloaliphatic C4 to C15, aromatic C6 to C15 or araliphatic C7 to C15 hydrocarbon radical, and X represents hydrogen or a group of the formula

    wherein R has the same meaning as above. The compounds are useful in the production of polyurethanes.

    Abstract translation: 作为过量的有机多异氰酸酯和氢氰酸的反应产物的有机多异氰酸酯具有下式：其中R代表脂族基团，其中R代表脂族基团 C 2 -C 12脂环族C 4至C 15，芳族C 6至C 15或芳脂族C 7至C 15烃基，X表示氢或式-C-NH-R-NCO PARALLEL O基团，其中R具有与上述相同的含义。

    Polymers containing alkoxysilyl-substituted biuret groups and processes for their preparation
    3.
    发明授权
    Polymers containing alkoxysilyl-substituted biuret groups and processes for their preparation 失效
    含有烷氧基甲硅烷基取代的缩二脲基团的聚合物及其制备方法

    公开(公告)号：US3903052A

    公开(公告)日：1975-09-02

    申请号：US38929973

    申请日：1973-08-17

    Applicant: BAYER AG

    Inventor： WAGNER KUNO ,  MULLER HANS JURGEN

    IPC: C08G18/00 ,  C08G18/61 ,  C08G18/79 ,  C08G18/83 ,  C09D175/00 ,  C14C11/00 ,  C08G22/06 ,  C08G22/18

    CPC classification number: C08G18/837 ,  C08G18/798 ,  Y10S528/901

    Abstract: New polyurethanes which contain silyl-substituted biuret groups in side chains are described. These polyurethanes have high storage stability, high reactivity and can be crosslinked by moisture with the formation of siloxane segments to form high quality end products. The products can be used for the production of high elastic films and temperature resistant and chemically resistant lacquers which can be applied to a wide variety of substrates.

    Abstract translation: 描述了在侧链中含有甲硅烷基取代的缩二脲基团的新型聚氨酯。 这些聚氨酯具有高储存稳定性，高反应性，并且可通过水分与硅氧烷链段的形成交联以形成高质量的最终产品。 该产品可用于生产可应用于各种基材的高弹性膜和耐温和耐化学腐蚀的漆。

    Process for the production of synthetic plastics comprising urethane groups and biuret groups
    4.
    发明授权
    Process for the production of synthetic plastics comprising urethane groups and biuret groups 失效
    用于生产包含氨基甲酸酯基和缩二脲基的合成塑料的方法

    公开(公告)号：US3899454A

    公开(公告)日：1975-08-12

    申请号：US36088373

    申请日：1973-05-16

    Applicant: BAYER AG

    Inventor： WAGNER KUNO ,  DIETRICH WERNER ,  KRAFT KARL-JOSEF ,  CONRAD HORST

    IPC: C08G18/72 ,  C08G18/78 ,  C08G18/79 ,  C08G18/14

    CPC classification number: C08G18/725 ,  C08G18/7831

    Abstract: A process is provided for the production of synthetic polyurethane plastics, particularly foam plastics, containing biuret groups by reacting polyisocyanates, polyhydroxyl and/or polycarboxyl compounds, flame inhibitors and, if desired, blowing agents, emulsifiers, activators and other additives which is characterized by using as the polyisocyanate solutions in monomeric polyisocyanates of from about 1 per cent to 85 per cent of polyisocyanates containing biuret groups and having the formula:

    in which R is an aromatic, araliphatic or cycloaliphatic radical which may, if desired, be substituted and N IS AN INTEGER FROM 0 TO 5, WHEREIN THE PROPORTION OF BIURETPOLYISOCYANATES HAVING MORE THAN THREE ISOCYANATE GROUPS IS AT LEAST 20 PER CENT BY WEIGHT BASED ON THE TOTAL QUANTITY OF BIURET-POLYISOCYANATES, AND THE SOLUTIONS CONTAIN FROM ABOUT 0.03 PER CENT TO ABOUT 5 PER CENT BY WEIGHT OF CHEMICALLY COMBINED EMULSIFIERS.

    Abstract translation: 提供了一种通过使多异氰酸酯，多羟基和/或多羧基化合物，阻燃剂以及如果需要的话发泡剂，乳化剂，活化剂和其它添加剂反应生成含有缩二脲基团的合成聚氨酯塑料，特别是泡沫塑料的方法。 在单体多异氰酸酯中使用约1％至85％的含有缩二脲基团的多异氰酸酯并具有下式的多异氰酸酯溶液：O PARALLEL OCN-RNCNR-NCO || O = C（CO-N-nH || H - N-CO）n-NR-NCO || R-NCOR | NCO，其中R是芳族，芳脂族或脂环族基团，如果需要，其可以被取代，并且N是整数，从0到5，在比例 具有超过三个异氰酸酯基团的多元醇 - 聚异氰酸酯基于基于多元醇 - 聚异氰酸酯的总量的重量至少为20个百分点，以及从化学合金重量的约0.03个百分点至约5个百分点的解决方案 INED EMULSIFIERS。

    Alkoxysilyl-substituted epoxidized urea derivatives
    8.
    发明授权
    Alkoxysilyl-substituted epoxidized urea derivatives 失效
    烷氧基甲硅烷基取代的环氧化脲衍生物

    公开(公告)号：US3927042A

    公开(公告)日：1975-12-16

    申请号：US36477673

    申请日：1973-05-29

    Applicant: BAYER AG

    Inventor： GOLITZ HANS DIETRICH ,  WAGNER KUNO ,  QUIRING BERND ,  NOLL WALTER

    IPC: C07F7/18 ,  C08L83/04 ,  C07D303/46

    CPC classification number: C07F7/1804 ,  C08L83/04 ,  C08L2666/44

    Abstract: New carbofunctional organosilanes which may be regarded as alkoxysilyl- and glycidyl ether-substituted carbamate-modified urea derivatives having the formula

    are obtained by reacting an aminomethyl-alkoxysilane of the formula

    with an epoxy-organo-isocyanate of the formula

    at a temperature below 50*C. In these formulae R is alkyl; R'' is alkyl, cyclohexyl or phenyl; R'''' is alkylene or cycloalkylene; n is 1, 2 or 3. The products are utilizable for priming silicious surfaces and for cross-linking convertible organopolysiloxanes.

    Abstract translation: 可以被认为是具有式R'OOCH 3的烷氧基甲硅烷基和缩水甘油醚取代的氨基甲酸酯改性的脲衍生物的新的官能团有机硅烷|平行平行|（RO-）nSi（CH 3）3-n-CH 2 -NC-NH-R' 通过使式（RO-）nSi（CH3）3-n-CH2-NH | R'的氨基甲基 - 烷氧基硅烷反应获得“-NH-CO-CH-CH 2 -CH 2 | CH 2 -CH-CH 2 -O 在低于50℃的温度下与式OCN-R“-NH-CO-CH-CH 2 -CH 2 -O-CH 2 -CH-CH 2 PARALLEL | ANGLE OCH 3 O的环氧有机异氰酸酯反应。在这些式中，R是 烷基; R'是烷基，环己基或苯基; R“是亚烷基或亚环烷基; n为1,2或3。

    Process for cross-linkable pulverulent coating compositions based on uretdione polyisocyanates
    9.
    发明授权
    Process for cross-linkable pulverulent coating compositions based on uretdione polyisocyanates 失效
    基于脲二酮多异氰酸酯的可交联粉末涂料组合物的方法

    公开(公告)号：US3923743A

    公开(公告)日：1975-12-02

    申请号：US44685774

    申请日：1974-02-28

    Applicant: BAYER AG

    Inventor： QUIRING BERND ,  WAGNER KUNO ,  MULLER RICHARD ,  MULLER PETER

    IPC: C09D5/03 ,  C08G18/00 ,  C08G18/79 ,  C09D5/46 ,  C09D175/00 ,  C08G18/06 ,  B05B5/02

    CPC classification number: C09D175/00 ,  C08G18/798 ,  C08G2150/20

    Abstract: A pulverulent coating composition adapted to be applied to a substrate by spraying as a powder is prepared by a process which comprises reacting an organic polyisocyanate containing a uretdione group with an organic compound containing groups which contain reactive hydrogen atoms determinable by the Zerewitinoff method wherein the functionality of the reactants and the proportions thereof are chosen to provide an average functionality between about 2.05 and 10, the ratio of reactive hydrogen groups to -NCO groups is between about 1.07 to 1 and about 2.5 to 1 and the amount of polyisocyanate containing uretdione groups is sufficient to provide from about 0.6 percent to about 25 percent by weight uretdione groups.

    Abstract translation: 通过包括使含有脲二酮基团的有机多异氰酸酯与含有可通过Zerewitinoff法测定的反应性氢原子的有机化合物反应的方法制备适于通过喷雾作为粉末施加到基材上的粉末涂料组合物，其中官能度 选择反应物及其比例以提供约2.05至10的平均官能度，反应性氢基团与-NCO基团的比例在约1.07至约2.5至1之间，并且含有脲二酮基团的多异氰酸酯的量为 足以提供约0.6重量％至约25重量％的脲二酮基团。

    Silyl-substituted urea derivatives and a process for their preparation
    10.
    发明授权
    Silyl-substituted urea derivatives and a process for their preparation 失效
    甲硅烷基取代的脲衍生物及其制备方法

    公开(公告)号：US3895043A

    公开(公告)日：1975-07-15

    申请号：US30319272

    申请日：1972-11-02

    Applicant: BAYER AG

    Inventor： WAGNER KUNO ,  OERTEL GUNTER ,  GOLITZ HANS DIETRICH ,  QUIRING BERND

    IPC: C08G18/00 ,  C07F7/18 ,  C08G18/10 ,  C08G18/32 ,  C08G18/78 ,  C09D175/00

    CPC classification number: C07F7/182 ,  C08G18/10 ,  C08G18/289

    Abstract: This invention discloses a silyl-substituted urea derivative of controlled reactivity, high storage stability and which improve the properties of the cross-linked end products obtained by the prior art. The silyl-substituted urea comprises the general formula:

    WHEREIN R represents a C1-C18 alkyl, C4-C14 cycloalkyl or a phenyl radical, R'' represents a C1-C10 alkyl, C4-C10 cycloalkyl or C6-C10 aryl radical which may be halogenated or cyano-substituted, R'''' represents a hydrogen atom or a methyl or phenyl radical; R'''''' represents a hydrogen atom or a C1-C18 alkyl, C4-C14 cycloalkyl or C6-C14 aryl radical which may be halogenated or cyano-substituted; Q'' represents an alkyl radical containing from 4 to 12 carbon atoms with a valency of (b + 1) or a C4-C14 cycloalkyl, C7-C15 arylalkyl, C6-C14 aryl or C8 alkylaryl radical, all of which radicals have a valency of (b + 1); Q represents a c-valent radical which has been obtained by the removal of C HX groups from a compound with a molecular weight of 200 to 150,000, preferably from 4000 to 80,000, which contains ester, amide, urethane, thioether, acetal, urea, hydrazodicarbonamide, hydrazide and/or carbonate groups and may also contain additional ether groups; A 0, 1 OR 2; B 1 TO 7, PREFERABLY 1 OR 2; C 1 TO 8, PREFERABLY 2 OR 3 AND X O, S, NH or N-Y- (Y C1-C8 alkyl radicals).

    Abstract translation: 本发明公开了具有受控反应性，高储存稳定性和改进现有技术获得的交联终产物性能的甲硅烷基取代的脲衍生物。

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