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    Vapor phase aromatics alkylation process
    1.
    发明申请
    Vapor phase aromatics alkylation process 有权

    公开(公告)号：US20060194997A1

    公开(公告)日：2006-08-31

    申请号：US11362255

    申请日：2006-02-27

    申请人： Benjamin Umansky ,  Michael Clark ,  Ajit Dandekar ,  Christine Elia

    发明人： Benjamin Umansky ,  Michael Clark ,  Ajit Dandekar ,  Christine Elia

    IPC分类号： C07C2/68

    CPC分类号： C10G29/205

    摘要： A process for the production of high octane number gasoline from light refinery olefins and benzene-containing aromatic streams such as reformate. The process achieves good utilization of both the ethylene and the propylene present in the mixed olefin feed from the unsaturated gas plant while reducing gasoline benzene levels. The light olefins including ethylene and propylene are reacted with the light aromatic stream containing benzene and other single ring aromatic compounds to form a gasoline boiling range product containing akylaromatics. The reaction is carried out with a two-catalyst system which comprises a member of the MWW family of zeolites and an intermediate pore size zeolite such as ZSM-5 using a fixed catalyst bed in both stages. Use of the two catalyst system enables the conversion of the ethylene and propylene components of the olefin feed to be converted to alkylaromatics under favorable conditions.

    Synthesis of Sterically Hindered Secondary Aminoether Alcohols
    5.
    发明申请
    Synthesis of Sterically Hindered Secondary Aminoether Alcohols 有权
    合成阻燃的次级氨基醚醇

    公开(公告)号：US20070293705A1

    公开(公告)日：2007-12-20

    申请号：US10587207

    申请日：2005-02-01

    申请人： Michael Siskin ,  Alan Katrizky ,  Kostyantyn Kirichenko ,  Adeana Bishop ,  Christine Elia

    发明人： Michael Siskin ,  Alan Katrizky ,  Kostyantyn Kirichenko ,  Adeana Bishop ,  Christine Elia

    IPC分类号： C07C215/08

    CPC分类号： C07C213/02 ,  C07C45/89 ,  C07C49/88 ,  C07C217/08

    摘要： Severely sterically hindered secondary aminoether alcohols are prepared by reacting organic carboxylic, organic carboxylic acid halides, acid anhydrides or a ketene with an alkyl, alkaryl or alkylhalo sulfonate to yield a sulfonic-carboxylic anhydride compound which is then reacted with a dioxane to cleave the ring of the dioxane, yielding a cleavage product which cleavage product is then animated with an alkylamine and hydrolyzed with base to yield the severely sterically hindered secondary aminoether alcohol.

    摘要翻译： 通过使有机羧酸，有机羧酸卤化物，酸酐或烯酮与烷基，烷基芳基或烷基卤代磺酸反应制得极度空间位阻的仲氨基醚醇，得到磺酸羧酸酐化合物，然后与二恶烷反应以切割环 的二恶烷，产生​​裂解产物，然后将裂解产物用烷基胺进行动画化，并用碱水解，得到严重位阻的仲氨基醚醇。

    Enhanced crystal acidity exechange method
    6.
    发明申请
    Enhanced crystal acidity exechange method 失效
    增强晶体酸度测试方法

    公开(公告)号：US20060122053A1

    公开(公告)日：2006-06-08

    申请号：US11258440

    申请日：2005-10-25

    申请人： Jean Beeckman ,  Glenn Sweeten ,  Daria Lissy ,  David Stern ,  Stephen McCarthy ,  Dominick Mazzone ,  Christine Elia

    发明人： Jean Beeckman ,  Glenn Sweeten ,  Daria Lissy ,  David Stern ,  Stephen McCarthy ,  Dominick Mazzone ,  Christine Elia

    IPC分类号： B01J29/06

    CPC分类号： B01J29/40 ,  B01J2229/42

    摘要： The present invention describes a method to increase the activity of a catalyst by first performing an ion exchange step with a potassium ion, followed by performing an ion-exchange step with an ammonium ion. Specifically, the present invention describes a method to increase the acidity of a zeolite by incorporating a potassium salt ion-exchange prior to an ammonium salt ion-exchange step. Even more specifically, the present invention is drawn to a method of increasing the activity of a zeolite by employing more than one potassium ion exchanges followed by at least one ammonium ion exchange. The present invention also describes a method to reduce the amount of sodium normally found in commercially produced zeolite by employing any of these methods. The present invention is also drawn to the catalysts produced by any of these methods.

    摘要翻译： 本发明描述了通过首先用钾离子进行离子交换步骤，然后用铵离子进行离子交换步骤来提高催化剂活性的方法。 具体地，本发明描述了通过在铵盐离子交换步骤之前引入钾盐离子交换来提高沸石的酸度的方法。 更具体地说，本发明涉及通过使用多于一种的钾离子交换，然后进行至少一种铵离子交换来提高沸石的活性的方法。 本发明还描述了一种通过使用任何这些方法来减少通常在商业生产的沸石中发现的钠的量的方法。 本发明还涉及通过任何这些方法制备的催化剂。