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公开(公告)号：US20130184397A1
公开(公告)日：2013-07-18
申请号：US13822651
申请日：2011-08-17
IPC分类号： C08L47/00
摘要： An elastomeric composition incorporating a hydrocarbon polymer modifier including piperylene, cyclic pentadiene and aromatic components, and having a softening point from 80° C. to 160° C., z-average molecular weight greater than 10,000, and at least 1 mole percent aromatic hydrogen, based on the total moles of hydrogen in the modifier. In a method, the elastomeric composition is processed with a cure package into a composition in the desired shape, which is cured to form the article. The modifier may optionally be immiscible with an elastomer in the composition and/or co-cured with the elastomer or filler in the composition. A tire or tire component may include the elastomeric composition.
摘要翻译： 一种包含烃聚合物改性剂的弹性体组合物，包括戊间二烯，环戊二烯和芳族组分，软化点为80℃至160℃，z平均分子量大于10,000，至少1摩尔％芳族氢 ，基于改性剂中氢的总摩尔数。 在一种方法中，将弹性体组合物用固化包装处理成期望形状的组合物，其被固化以形成制品。 改性剂可以任选地与组合物中的弹性体不混溶和/或在组合物中与弹性体或填料共固化。 轮胎或轮胎部件可以包括弹性体组合物。
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公开(公告)号：US08653195B2
公开(公告)日：2014-02-18
申请号：US13822651
申请日：2011-08-17
摘要： An elastomeric composition incorporating a hydrocarbon polymer modifier including piperylene, cyclic pentadiene and aromatic components, and having a softening point from 80° C. to 160° C., z-average molecular weight greater than 10,000, and at least 1 mole percent aromatic hydrogen, based on the total moles of hydrogen in the modifier. In a method, the elastomeric composition is processed with a cure package into a composition in the desired shape, which is cured to form the article. The modifier may optionally be immiscible with an elastomer in the composition and/or co-cured with the elastomer or filler in the composition. A tire or tire component may include the elastomeric composition.
摘要翻译： 一种包含烃聚合物改性剂的弹性体组合物，包括戊间二烯，环戊二烯和芳族组分，软化点为80℃至160℃，z平均分子量大于10,000，至少1摩尔％芳族氢 ，基于改性剂中氢的总摩尔数。 在一种方法中，将弹性体组合物用固化包装处理成期望形状的组合物，其被固化以形成制品。 改性剂可以任选地与组合物中的弹性体不混溶和/或在组合物中与弹性体或填料共固化。 轮胎或轮胎部件可以包括弹性体组合物。
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公开(公告)号：US08809455B2
公开(公告)日：2014-08-19
申请号：US12548797
申请日：2009-08-27
申请人： Maria D. Ellul , Anthony Jay Dias , Rodney May
发明人： Maria D. Ellul , Anthony Jay Dias , Rodney May
IPC分类号： C08L29/04 , C08L55/02 , C08L67/00 , C08L77/00 , C08L79/00 , C08L81/04 , C08L81/06 , C08L23/22 , C08L23/28 , C08L23/02 , B60C1/00 , C08L79/08
CPC分类号： C08L23/283 , B60C1/00 , C08K3/34 , C08K5/0016 , C08L23/02 , C08L23/0869 , C08L23/22 , C08L77/00 , C08L79/08 , C08L2205/08 , C08L2666/02
摘要： A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.
摘要翻译： 动态硫化合金含有至少一种含异丁烯的弹性体和至少一种热塑性树脂，其中弹性体以热塑性树脂的连续相中的小硫化或部分硫化的颗粒的分散相存在。 动态硫化合金还含有酸酐官能化的低聚物。 该合金保持高的肖氏A硬度值，同时获得改进的流动性用于加工。
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4.发明授权Elastomer nanocomposites comprising isobutylene and multifunctional oligomers 有权包含异丁烯和多官能低聚物的弹性体纳米复合材料公开(公告)号：US07632886B2
公开(公告)日：2009-12-15
申请号：US11293561
申请日：2005-12-02
申请人： Weiqing Weng , Anthony Jay Dias , Kriss Randall Karp , Molly Westermann Johnston , Caiguo Gong , Carmen Neagu , Beverly Jean Poole
发明人： Weiqing Weng , Anthony Jay Dias , Kriss Randall Karp , Molly Westermann Johnston , Caiguo Gong , Carmen Neagu , Beverly Jean Poole
IPC分类号： C08K9/04
CPC分类号： C08L23/00 , C08L23/286 , C08L51/06 , C08L2666/04 , C08L2666/24
摘要： The present invention provides a nanocomposite of an elastomer, a polymer or oligomer functionalized with a polar group, and a clay. The nanocomposite can be a mixture of a halogenated elastomer, an acid or acid anhydride modified polymer, and a clay, desirably an exfoliated clay, suitable for use as an air barrier. Also disclosed is a nanocomposite that can be a mixture of a halogenated elastomer, a polymer modified with a carboxylic acid, and an organoclay.
摘要翻译： 本发明提供弹性体，用极性基团官能化的聚合物或低聚物和粘土的纳米复合材料。 纳米复合材料可以是卤化弹性体，酸或酸酐改性聚合物和粘土，理想地是适合用作空气屏障的剥离粘土的混合物。 还公开了可以是卤化弹性体，用羧酸改性的聚合物和有机粘土的混合物的纳米复合材料。
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公开(公告)号：US07605205B2
公开(公告)日：2009-10-20
申请号：US11267981
申请日：2005-11-07
申请人： Caiguo Gong , Anthony Jay Dias , Weiqing Weng , Ramanan Krishnamoorti , Carmen Neagu , Molly Westermann Johnston , Beverly Jean Poole , Kriss Randall Karp
发明人： Caiguo Gong , Anthony Jay Dias , Weiqing Weng , Ramanan Krishnamoorti , Carmen Neagu , Molly Westermann Johnston , Beverly Jean Poole , Kriss Randall Karp
IPC分类号： C08K3/34
CPC分类号： B60C1/0008 , B82Y30/00 , C08J5/005 , C08J2323/22 , C08J2325/18 , C08K9/08 , C08L21/00
摘要： The invention provides for processes for preparing a nanocomposite compositions including the steps of: contacting a multifunctional intercalant including a cationic moiety separated from an anionic moiety by at least 1 carbon, with a clay at a temperature and for a period of time sufficient to produce an at least partially intercalated clay; and contacting the at least partially intercalated clay with a functionalized interpolymer including one or more functional groups, at a temperature, and for a period of time sufficient to produce the nanocomposite compositions. Cured nanocomposite compositions, and articles including such nanocomposite compositions are also provided.
摘要翻译： 本发明提供了制备纳米复合材料组合物的方法，其包括以下步骤：将包含从阴离子部分分离至少1个碳的阳离子部分的多官能插层剂与粘土在一定温度和足以产生 至少部分插层粘土; 以及在足以产生所述纳米复合组合物的温度和一段时间内使所述至少部分插层的粘土与包含一个或多个官能团的官能化互聚物接触。 还提供了固化的纳米复合组合物和包括这种纳米复合组合物的制品。
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公开(公告)号：US08980978B2
公开(公告)日：2015-03-17
申请号：US11630083
申请日：2005-06-28
申请人： Weiqing Weng , Anthony Jay Dias , Caiguo Gong , Beverly Jean Poole , Carmen Neagu , Kriss Randall Karp , Molly Westermann Johnston , James Richard Ayers
发明人： Weiqing Weng , Anthony Jay Dias , Caiguo Gong , Beverly Jean Poole , Carmen Neagu , Kriss Randall Karp , Molly Westermann Johnston , James Richard Ayers
CPC分类号： C08K3/346 , B82Y30/00 , C08K2201/011 , C08L21/00 , C08L23/16
摘要： The present invention relates to processes to produce nanocomposites. In particular, the invention relates to solution processes using organic solvents and mixtures of solvents to produce polymeric nanocomposites.
摘要翻译： 本发明涉及制备纳米复合材料的方法。 特别地，本发明涉及使用有机溶剂和溶剂混合物来生产聚合物纳米复合材料的溶液方法。
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公开(公告)号：US07491764B2
公开(公告)日：2009-02-17
申请号：US10478606
申请日：2002-05-29
IPC分类号： C08K5/01
CPC分类号： B60C1/0008 , C08K3/04 , C08K3/346 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/283 , C08L23/28 , C08L2666/04
摘要： The present invention includes blends of a halogenated elastomer such as a butyl rubber or an interpolymer of, on one embodiment, a C4 to C7 isomonoolefin, a para-methylstyrene and a para-(halomethylstyrene), the interpolymer having been pre-mixed with an exfoliating compound and clay, the entire blend forming a nanocomposite in one embodiment. The clay may or may not have undergone an additional exfoliating treatment prior to blending with the halogenated elastomer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an air barrier.
摘要翻译： 本发明包括卤化弹性体如丁基橡胶或在一个实施方案中为C4至C7异单烯烃，对甲基苯乙烯和对 - （卤代甲基苯乙烯）的互聚物的共混体，该互聚物已经与 去角质化合物和粘土，在一个实施方案中，整个共混物形成纳米复合材料。 在与卤化弹性体共混之前，粘土可以或可以不经历额外的去角质处理。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为空气屏障。
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公开(公告)号：US06528589B2
公开(公告)日：2003-03-04
申请号：US09925699
申请日：2001-08-09
申请人： Anthony Jay Dias
发明人： Anthony Jay Dias
IPC分类号： C08L2322
CPC分类号： C08L21/00 , C08L23/283 , C08L2205/08 , C08L2312/00 , C08L2666/06 , C08L2666/04
摘要： A process for forming a compatibilized blend of general purpose rubbers (GPR) and a halogenated poly(isobutylene-co-4-methylstyrene) through solventless reactions utilizing a multifunctional agent containing a diene reactive group and a benzylic halo reactive group.
摘要翻译： 通过使用含有二烯反应性基团和苄基卤代反应性基团的多官能试剂通过无溶剂反应形成通用橡胶（GPR）和卤化聚（异丁烯 - 共-4-甲基苯乙烯）的相容化共混物的方法。
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9.发明授权Peroxide and radiation curable compositions containing isobutylenene copolymers having acrylate functionality 失效含有具有丙烯酸酯官能度的异丁烯共聚物的过氧化物和可辐射固化组合物
公开(公告)号：US5824717A
公开(公告)日：1998-10-20
申请号：US476754
申请日：1995-06-07
IPC分类号： C08F8/00 , C08F8/20 , C08F210/08 , C08F210/10 , C08F210/14 , C08F212/12 , C08G81/02 , C08L23/02 , C08L23/22 , C08L23/28 , C08L71/12 , C09D123/22 , C09D125/16 , C09J7/02 , G03F7/038
CPC分类号： C08L71/123 , C08F210/08 , C08F210/10 , C08F210/14 , C08F212/12 , C08F8/20 , C08G81/021 , C08L23/02 , C08L23/22 , C08L23/283 , C09D123/22 , C09D125/16 , C09J7/021 , G03F7/038 , G03F7/0388 , C08F2800/10 , C08F2800/20 , C08F2810/30 , C08F2810/50 , Y10S522/904
摘要： The invention relates to peroxide- or radiation-curable copolymer containing compositions and to the resulting radiation- or peroxide- cured compositions. The compositions may optionally contain a reinforcing filler. Copolymers employed in the compositions are acrylate modified copolymers of an isoolefin of 4 to 7 carbon atoms and para-alkylstyrene comonomers. Since the percentage of extractables from the cured composition is negligible, the cured compositions are suitable for use in the manufacture of a variety of high purity rubber goods used in the pharmaceutical and health care industries. In addition, the compositions may be employed as condenser packings and as food contact materials or wire cable insulation materials. Further, the cured composition may be employed in the manufacture of high purity hoses.
摘要翻译： 本发明涉及含有组合物的过氧化物或可辐射固化的共聚物和所得的辐射 - 或过氧化物固化的组合物。 组合物可以任选地含有增强填料。 在组合物中使用的共聚物是具有4至7个碳原子的异烯烃和对 - 烷基苯乙烯共聚单体的丙烯酸酯改性的共聚物。 由于来自固化组合物的可萃取物的百分比可以忽略不计，所以固化的组合物适用于制造用于制药和保健行业的各种高纯度橡胶制品。 此外，组合物可以用作冷凝器填料和作为食品接触材料或电线电缆绝缘材料。 此外，固化的组合物可用于制造高纯度软管。
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公开(公告)号：US08399551B2
公开(公告)日：2013-03-19
申请号：US10518193
申请日：2003-05-30
IPC分类号： C08K3/34 , C08F222/08 , C08F210/00
CPC分类号： B82Y30/00 , C08F8/00 , C08K3/346 , C08K9/04 , C08K2201/011 , C08F10/00 , C08L15/00 , C08L19/006 , C08L19/00
摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C2 to C10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene-co-p-alkylstyrene) elastomers and poly(isobutylene-co-isoprene) elastomers, which are functionalized by reacting free radical generating agents and unsaturated carboxylic acids, unsaturated esters, unsaturated imides, and the like, with the elastomer. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.
摘要翻译： 本发明的一个实施方案是纳米复合材料，其包含粘土和包含至少C2至C10烯烃衍生单元的弹性体; 其中弹性体还包括垂直于弹性体的官能化单体单元。 弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过使自由基产生剂和不饱和羧酸，不饱和酯，不饱和酰亚胺和 像弹性体一样。 粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。 组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。 本发明的纳米复合材料具有改善的空气阻隔性能，例如可用于轮胎内衬和内管。
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