Abstract:
A curable composition includes a condensation product having a weight average molecular weight of 30,000 or less and a curing agent, the condensation product being obtained by hydrolysis and condensation of a first and secondsilane compound in the presence of a neutral salt catalyst. The condensation product also has a ratio Y/X of 0.2 or less, wherein X is the number of moles of an OR3 group directly bonded to silicon atoms of the first and second silane compounds, and Y is the number of moles of an OR3 group directly bonded to a silicon atom of the condensation product. The first silane compound is represented by R1—(SiR2a(OR3)3-a), and the second silane compound is represented by R4—(SiR2a(OR3)3-a).
Abstract:
An active energy ray curable composition includes a copolymer and a photo-acid generator, the copolymer being obtained by reacting a cocondensate with a polymerizable unsaturated monomer, wherein the cocondensate is obtained by hydrolyzing and condensing a first silane compound having a hydrolyzable silyl group and a second silane compound having a hydrolyzable silyl group, the cocondensate has 0.1 to 3.0 polymerizable unsaturated groups per molecule, the first silane compound is represented by the general formula (I): R1—(SiR2a(OR3)3-a), and the second silane compound is represented by the general formula (II): R4—(SiR2a(OR3)3-a)).
Abstract:
The present invention aims to develop an aqueous heat-shielding coating material to which low staining properties are imparted to suppress a reduction in heat-shielding properties due to the reduction in solar reflectance caused by adhesion of contaminants in the air during outdoor exposure, thereby maintaining the heat-shielding properties for a long period of time. The above problem is solved by providing a resin composition for an aqueous coating material including: (A1) a water-soluble and/or water-dispersible resin; (A2) a heat-shielding pigment; (B1) an organosilicate and/or a modified product of the organosilicate; and (B2) a curing catalyst that promotes a hydrolysis/condensation reaction of an alkoxysilyl group.
Abstract:
A curable composition includes a condensation product having a weight average molecular weight of 30,000 or less and a curing agent, the condensation product being obtained by hydrolysis and condensation of a first and second silane compound in the presence of a neutral salt catalyst. The condensation product also has a ratio Y/X of 0.2 or less, wherein X is the number of moles of an OR3 group directly bonded to silicon atoms of the first and second silane compounds, and Y is the number of moles of an OR3 group directly bonded to a silicon atom of the condensation product. The first silane compound is represented by R1—(SiR2a(OR3)3-a), and the second silane compound is represented by R4—(SiR2a(OR3)3-a).
Abstract:
A method for producing a siloxane resin, by hydrolyzing and condensing a silane compound containing a hydrolyzable silyl group represented by RnSiX4-n using a neutral salt as a catalyst. In the formula RnSiX4-n , R represents an organic group having a carbon atom directly bonded to Si, X represents a hydroxyl group or a hydrolyzable group, and n represents an integer of 0 to 3, provided that when n is 2 or greater each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.
Abstract:
A method for producing a composite resin includes preparing an organopolysiloxane by performing a hydrolyzing and condensing process on an organotrialkoxysilane comprising alkoxysilyl groups and a hydrocarbon group, and obtaining the composite resin by reacting the organopolysiloxane with an acrylic silicon in a reaction solution. The reaction solution includes the organopolysiloxane, the acrylic silicon, a water-soluble organic solvent, and an acid catalyst. The reaction solution has a solid content ranging from 30 to 55% by weight, and the water-soluble organic solvent has 4 or more carbon atoms. The composite resin contains the organopolysiloxane in an amount of 40 to 90% by weight and the acrylic silicon in an amount of 10 to 60% by weight, and the acrylic silicon has a number average molecular weight of 1000 to 9000.
Abstract:
A method for producing a siloxane resin, by hydrolyzing and condensing a silane compound containing a hydrolyzable silyl group represented by RnSiX4-n using a neutral salt as a catalyst. In the formula RnSiX4-n, R represents an organic group having a carbon atom directly bonded to Si, X represents a hydroxyl group or a hydrolyzable group, and n represents an integer of 0 to 3, provided that when n is 2 or greater each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.
Abstract:
A resin composition containing (A) an organopolysiloxane having a glycidyloxy group, and (B) at least one selected from the group consisting of a triarylalkoxysilane, a diaryldialkoxysilane, a hydrolysate thereof and a partially hydrolyzed/condensed product thereof is provided. The resin composition may further contain (C) a β-dicarbonyl compound. The resin composition may further contain (D) an organic compound having one or more of an epoxy group, an oxetanyl group and a vinyl ether group. The resin composition may be mixed with (E) an organoaluminum compound and/or organotitanium compound and be cured.
Abstract:
A resin composition including (A) a glycidyloxy group-containing organopolysiloxane in an amount of 100 parts by weight, (B) a neutral salt in an amount of 0.001 parts by weight or more and 1 part by weight or less, (C) a β-dicarbonyl compound in an amount of 0.5 parts by weight or more and 10 parts by weight or less, and (D) a solvent in an amount of 20 parts by weight or more and 300 parts by weight or less is provided. In a multi-liquid curable resin composition including a first liquid and a second liquid, the first liquid is the resin composition, and the second liquid contains (E) an organoaluminum compound and/or organotitanium compound.
Abstract:
An active energy ray-curable composition includes (A) a condensate having a weight average molecular weight of 20,000 or less, and (B) a photoacid generator, with the condensate (A) being obtained by hydrolysis/condensation of: (I) a silane compound containing a hydrolyzable silyl group represented by formula (I): R1—(SiR2a(OR3)3-a. A ratio (Y/X) of Y to X is 0.2 or less, where X represents the number of moles of OR3 groups directly bonded to silicon atoms in the silane compound (I) which is a starting material of the condensate (A) and Y represents the number of moles of OR3 groups directly bonded to silicon atoms in the condensate (A).