公开(公告)号：US06764846B2

公开(公告)日：2004-07-20

申请号：US09899212

申请日：2001-07-06

申请人： Naoki Yamamori ,  Akio Harada ,  Nobuki Hayase

发明人： Naoki Yamamori ,  Akio Harada ,  Nobuki Hayase

IPC分类号： C12N112

CPC分类号： C12R1/01 ,  C09D5/1606

摘要： The present invention provides a microorganism which, when an underwater structure is formed with a coating film containing it, produces a biojelly in water to prevent fouling of the structure with macroscopic aquatic life, such a coating or a coating film, and a method of preventing attachment of macroscopic aquatic life which comprises using said coating or coating film. The present invention is directed to a strain of microorganism belonging to the genus Alteromonas and having the ability to produce a biojelly.

摘要翻译： 本发明提供一种微生物，当水下结构体形成有含有它的涂膜时，在水中产生生物果冻以防止具有宏观水生生物的结构的结垢，这种涂层或涂膜，以及防止 包括使用所述涂层或涂膜的宏观水生生物的附着。本发明涉及属于变形菌属的微生物菌株，并且具有产生生物果胶的能力。

公开(公告)号：US5861435A

公开(公告)日：1999-01-19

申请号：US530405

申请日：1995-09-15

申请人： Junji Yokoi ,  Isao Nakamura ,  Ryoji Hamade ,  Naoki Yamamori ,  Hiroharu Ohsugi ,  Akio Harada

发明人： Junji Yokoi ,  Isao Nakamura ,  Ryoji Hamade ,  Naoki Yamamori ,  Hiroharu Ohsugi ,  Akio Harada

IPC分类号： C09D5/16 ,  A01N27/00 ,  A01N29/00 ,  A01N33/00 ,  A01N33/26

CPC分类号： C09D5/1687 ,  C09D5/1606 ,  C09D5/1625 ,  Y10S514/918

摘要： A method for preventing settlement of aquatic fouling organisms on surface of an aquatic structure without environmental hazard is provided. The method is based upon absolutely novel concept to prevent the settlement by means of thick slime layer, i.e. bio-jelly, deposited on said surface. The present invention also provides a bio-jelly producing agent and a bio-jelly producing paint both useful for the present method. Further, the present invention provides a novel low toxic antifouling agent.

摘要翻译： 提供了一种在没有环境危害的情况下防止水生结构表面上的水体污染生物沉降的方法。 该方法基于绝对新颖的概念，以通过沉积在所述表面上的厚粘稠层即生物果冻来防止沉降。 本发明还提供了可用于本发明方法的生物果冻生产剂和生物果冻生产油漆。 此外，本发明提供了一种新型的低毒防污剂。

公开(公告)号：US5134197A

公开(公告)日：1992-07-28

申请号：US457940

申请日：1989-12-27

申请人： Naoki Yamamori ,  Hiroharu Ohsugi ,  Koichi Fukuda ,  Akio Harada

发明人： Naoki Yamamori ,  Hiroharu Ohsugi ,  Koichi Fukuda ,  Akio Harada

IPC分类号： C09D133/02 ,  C08G77/398 ,  C08G77/442 ,  C08G77/445 ,  C08L83/04 ,  C09D5/16 ,  C09D167/00 ,  C09D183/04 ,  C09D183/08 ,  C09D183/10

CPC分类号： C09D183/10 ,  C08G77/398 ,  C08G77/442 ,  C08G77/445 ,  C09D183/08 ,  C09D5/1675

摘要： The invention relates to a novel hydrolyzable silicone resin composition comprising a polysiloxane having at least one polyvalent metal ester group represented by either one of the following formulae:(--COO--) (.sub.m --M--(R.sub.2).sub.n--R.sub.1 --COO--).sub.m --M--(R.sub.2).sub.n ##STR1## in which R.sub.2 is a hydroxyl group, an alkoxyl group, an alkyl group, a halogen or oxygen atom; R.sub.1 is a bivalent organic residue; p and q each is 0 or an integer of 1 to 8; m is an integer of 2 or more; n is 0 or an integer of 1 or more, providing that the sum of m and n is equal to the valence number of metal M; and M is a bivalent to tetravalent metal selected from the group consisting of Ti, Al, Mg, Zn, Pb, Zr, Cu, Ni, Co and Sn, its preparation and coating composition containing the same, which is useful in an antifouling paint.

公开(公告)号：US06214902B1

公开(公告)日：2001-04-10

申请号：US08917364

申请日：1997-08-26

申请人： Naoki Yamamori ,  Akio Harada

发明人： Naoki Yamamori ,  Akio Harada

IPC分类号： C08J600

CPC分类号： C09D5/1662

摘要： The present invention provides a nonelution type antifouling method which comprises applying a nonelution type antifouling coating composition comprising at least two resins insoluble in seawater and incompatible with each other on top of the outermost layer of underwater portion of a marine structure and forming a coating film having a microheterogeneo us structure in which granular or disk-like minute protrusions with a mean size of 10 nm to 20 &mgr;m in diameter comprising at least one of said resins occupy 5 to 49% of the surface area of the coating film.

摘要翻译： 本发明提供一种非防腐型防污方法，其包括在海水结构的水下部分的最外层的顶部涂敷含有至少两种不溶于海水的树脂和不相容的非防锈型防污涂料组合物，并形成具有 一种微小异质结构，其中包含至少一种所述树脂的直径为10nm至20μm的平均粒径的微粒或盘状微小突起占涂膜表面积的5至49％。

公开(公告)号：US6123755A

公开(公告)日：2000-09-26

申请号：US990190

申请日：1997-12-12

申请人： Naoki Yamamori ,  Akio Harada

发明人： Naoki Yamamori ,  Akio Harada

IPC分类号： C09D5/16 ,  C09D133/00 ,  C09D155/00 ,  C09D183/07 ,  C08F30/08 ,  C08L83/04

CPC分类号： C09D5/1637 ,  C09D5/1675

摘要： An antifouling coating composition which comprises at least two kinds of mutually incompatible resin compositions and which is capable of forming a microheterogenous coating film having a multiplicity of spherical or disk-like minute protrusions comprising at least one of the resin compositions,at least one of the resin compositions to yield the spherical or disk-like minute protrusions being produced from an antifouling monomer and an ethylenically unsaturated monomer copolymerizable therewith.Since the antifouling coating composition of the present invention contains a resin composition adapted to impart an antifouling effect to the coating film, it displays a long-term antifouling performance beyond the antifouling effect attributable to only said microheterogenous structure.

摘要翻译： 一种防污涂料组合物，其包含至少两种相互不相容的树脂组合物，并且能够形成具有多个球形或圆盘状微小突起的微观异质涂膜，所述微小突起包含至少一种树脂组合物，至少一种 产生由防污单体和可与其共聚的烯键式不饱和单体产生球形或盘状微小突起的树脂组合物。 由于本发明的防污涂料组合物含有适于对涂膜赋予防污效果的树脂组合物，所以其显示出超出仅归于所述微相互结构的防污效果的长期防污性能。

公开(公告)号：US20110178204A1

公开(公告)日：2011-07-21

申请号：US13120608

申请日：2009-09-28

申请人： Naoki Yamamori ,  Hiroshi Tominaga ,  Mamoru Shimada

发明人： Naoki Yamamori ,  Hiroshi Tominaga ,  Mamoru Shimada

IPC分类号： C09D5/16

CPC分类号： C09D5/1612 ,  C08L89/00 ,  C09D5/165 ,  C09D5/1656 ,  C09D105/08 ,  C09D133/08 ,  C09D133/24 ,  C08L2666/26

摘要： Provided are coating composition containing an organic polymer particle (A) composed of an organic polymer having a hydroxyl group and a cationic group in a molecule, the weight average particle size of which being 10 to 35 μm, and a base resin (B), wherein the content of the organic polymer particle (A) is 0.5 to 5.0% by weight in the solid content of the coating composition, and a method of producing the same, and a coating film and underwater structure using the coating composition. The base resin (B) has a group represented by the following general formula (1): —COO-M-OCO-A  (1) (wherein, M represents a divalent or higher valent metal, and A represents an organic acid residue of monobasic acid) or a group represented by the following general formula (2): —COO—Si(R1R2R3)  (2) (wherein, R1, R2 and R3, which may be the same or different, represent an isopropyl group or an n-butyl group) in a side chain, or has a cross-linking structure represented by the following general formula (3): —COO-M-OCO—  (3) (wherein, M represents the same meaning as described above).

摘要翻译： 本发明提供含有由分子内具有羟基和阳离子性基团的有机聚合物构成的有机聚合物粒子（A）的重均粒径为10〜35μm的涂料组合物和基础树脂（B）， 其中，所述有机聚合物粒子（A）的含量为所述涂料组合物的固体成分中的0.5〜5.0重量％，其制造方法，以及使用所述涂料组合物的涂膜和水下结构体。 基础树脂（B）具有以下通式（1）表示的基团：-COO-M-OCO-A（1）（其中，M表示二价以上的金属，A表示有机酸残基 一元酸）或由以下通式（2）表示的基团：-COO-Si（R 1 R 2 R 3）（2）（其中，R 1，R 2和R 3可以相同或不同，表示异丙基或n （3）表示的交联结构：-COO-M-OCO-（3）（其中，M表示与上述相同的含义）。

公开(公告)号：US4499223A

公开(公告)日：1985-02-12

申请号：US602722

申请日：1984-04-23

申请人： Naoki Yamamori ,  Junji Yokoi ,  Motoyoshi Yoshikawa

发明人： Naoki Yamamori ,  Junji Yokoi ,  Motoyoshi Yoshikawa

IPC分类号： C08G63/68 ,  C09D5/16 ,  C08G63/02

CPC分类号： C09D5/165 ,  C08G63/681

摘要： Hydrolyzable polyester resin for an antifouling paint use having at least one metal-ester bondings, the metal being at least one member selected from the Groups Ib, IVa and VIII of the Periodic Table and the metal content being 0.3.about.10 wt %. The polyester resin is useful as resinous vehicle in self-polishing marine paint.

摘要翻译： 用于防污涂料的可水解聚酯树脂使用具有至少一种金属 - 酯键合，该金属是选自元素周期表第Ib，Ⅳa和Ⅷ族中的至少一种，金属含量为0.3％（重量）。 聚酯树脂可用作自抛光船用涂料中的树脂载体。

公开(公告)号：US4482701A

公开(公告)日：1984-11-13

申请号：US426155

申请日：1982-09-28

申请人： Naoki Yamamori ,  Junji Yokoi ,  Motoyoshi Yoshikawa

发明人： Naoki Yamamori ,  Junji Yokoi ,  Motoyoshi Yoshikawa

IPC分类号： C08G63/60 ,  C09D5/16 ,  C09D167/04

CPC分类号： C08G63/60 ,  C08K3/08 ,  C08K3/22 ,  C08K3/28 ,  C08K5/39 ,  C08K5/57 ,  C09D167/04 ,  C09D5/165 ,  Y10S260/43 ,  Y10S525/938

摘要： Preparation of hydrolyzable polyester resin comprising reacting polycarboxylic acid and polyhydric alcohol components, which is characterized by using, as at least part of said polyhydric alcohol component, a metallic salt of hydroxy carboxylic acid of the formula defined and effecting the polycondensation at a temperature which is no more than the decomposition temperature of said metallic salt. The polyester resins are useful as resinous vehicle of varnishes and antifouling paints.

摘要翻译： 包括使多元羧酸和多元醇组分反应的可水解聚酯树脂的制备，其特征在于，使用所述多元醇组分的至少一部分，使用所定义的式定义的羟基羧酸金属盐，并在一定温度下进行缩聚 不超过所述金属盐的分解温度。 聚酯树脂可用作清漆和防污涂料的树脂载体。

公开(公告)号：US5770188A

公开(公告)日：1998-06-23

申请号：US742597

申请日：1996-10-28

申请人： Ryoji Hamade ,  Naoki Yamamori ,  Yoshio Okahata

发明人： Ryoji Hamade ,  Naoki Yamamori ,  Yoshio Okahata

IPC分类号： C07C235/06 ,  C09D5/16 ,  A61K31/74

CPC分类号： C12N11/14 ,  C07C235/06 ,  C09D5/1637

摘要： This invention is related to glucoxide derivatives for enzyme modification of the following general formula (1), to provide a lipid-coated enzyme showing high activity in organic solvents; antifouling paint compositions containing a lipid-coated enzyme being stable in organic solvents by coating with a C.sub.6 to C.sub.30 lipid, and a paint resin, to be capable of forming paint films having good antifouling activity and durability and allowing an enzyme to retain good stability in the paint and in paint films; and self-polishing antifouling paint compositions containing an enzyme-susceptible resin and a lipid-coated enzyme capable of catalyzing the degradation of said resin and being stable in organic solvents by coating with a C.sub.6 to C.sub.30 lipid, to retain the antifouling effect for a prolonged period of time without adversely affecting the environment. ##STR1##

摘要翻译： 本发明涉及用于下述通式（1）的酶修饰的葡萄糖氧化物衍生物，以提供在有机溶剂中显示高活性的脂质包被酶; 含有脂质包被酶的防污涂料组合物能够形成具有良好防污性和耐久性的漆膜，并能使酶保持良好的稳定性，所述涂料的酶通过涂覆C6-C30脂质和涂料树脂在有机溶剂中是稳定的 油漆和油漆膜; 以及含有能够催化所述树脂降解并在有机溶剂中通过涂覆C6〜C30脂质稳定的酶敏感性树脂和脂质包被酶的自抛光防污漆组合物，以保持防污效果延长 时间不会对环境造成不利影响。 （1）

公开(公告)号：US4918147A

公开(公告)日：1990-04-17

申请号：US194286

申请日：1988-05-16

申请人： Naoki Yamamori ,  Masayuki Matsuda ,  Kiyoaki Higo ,  Shinichi Ishikura

发明人： Naoki Yamamori ,  Masayuki Matsuda ,  Kiyoaki Higo ,  Shinichi Ishikura

IPC分类号： A01N55/02 ,  C08F8/44 ,  C08G63/12 ,  C08G63/68 ,  C08G63/88 ,  C08G75/00 ,  C08G75/20 ,  C08G79/02 ,  C09D5/14 ,  C09D5/16 ,  C09D133/04 ,  C09D167/00 ,  C09D201/02

CPC分类号： C08F8/44 ,  C09D5/1662

摘要： A resin composition to be used as a resinous vehicle for an antifouling paint and a process for preparing the same, comprising reacting a mixture of(A) an acid group containing base resin having an acid value in the range of 25-350 mg KOH/g, selected from the group consisting of vinyl resin, polyester resin, alkyd resin and epoxy resin,(B) a metallic salt of low boiling organic basic acid having a boiling point in the range of 100.degree.-240.degree. C., the metal is selected from metals having a valence of 2 or more and a lesser ionization tendency than alkali metals, and(C) an organic monobasic acid having a boiling point of 20.degree. C. or more higher than said low boiling organic basic acid at an elevated temperature which is lower than the decomposition temperature of said metallic salt of said low boiling organic basic acid, while removing the formed low boiling organic basic acid out of the system. The subject composition provides superior antifouling coating compositions.