公开(公告)号：US20150337083A1

公开(公告)日：2015-11-26

申请号：US14758657

申请日：2014-01-06

Applicant: RHODIA OPERATIONS

Inventor： Stephane JEOL ,  Floryan DECAMPO ,  Peng LI

IPC: C08G69/40 ,  C08J5/00 ,  C08G69/14

CPC classification number: C08G69/40 ,  C08G69/08 ,  C08G69/14 ,  C08G69/16 ,  C08G69/36 ,  C08J5/00 ,  C08J2377/02 ,  C08L77/02

Abstract: The present invention relates to a novel polyamide synthesized from biobased monomers. The novel polyamide comprises the repeat unit of following formula (I). The present invention also relates to the process for the preparation of said polyamide, to its uses and to articles and compositions comprising said polyamide.

Abstract translation: 本发明涉及由生物基单体合成的新型聚酰胺。 新型聚酰胺包含下式（I）的重复单元。 本发明还涉及制备所述聚酰胺及其用途的方法以及包含所述聚酰胺的制品和组合物。

公开(公告)号：US20160152585A1

公开(公告)日：2016-06-02

申请号：US14896796

申请日：2013-06-14

Applicant: RHODIA OPERATIONS ,  RHODIA (CHINA) CO., LTD.

Inventor： Floryan DECAMPO ,  Peng LI

IPC: C07D307/52

CPC classification number: C07D307/52 ,  B01J31/2295 ,  B01J2231/4283 ,  B01J2531/827

Abstract: Disclosed is a process for the production of furanic compound comprising at least one amine function, comprising reacting a furanic compound having at least one hydroxyl function or at least one aldehyde function with a second reactant having an amine function, in the presence of an iridium catalyst.

Abstract translation: 公开了一种生产包含至少一种胺官能团的呋喃化合物的方法，包括在铱催化剂存在下使具有至少一个羟基官能团的呋喃化合物或至少一种醛官能团与具有胺官能团的第二反应物反应 。

公开(公告)号：US20150368218A1

公开(公告)日：2015-12-24

申请号：US14765855

申请日：2014-02-05

Applicant: RHODIA OPERATIONS ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

Inventor： Jean-Marc CLACENS ,  Floryan DECAMPO ,  Fabien GRASSET ,  Benjamin KATRYNIOK ,  Franck DUMEIGNIL ,  Sebastien PAUL ,  Veronique RATAJ

IPC: C07D307/46 ,  B01J21/18 ,  B01J27/198

CPC classification number: C07D307/46 ,  B01J21/18 ,  B01J27/198 ,  C07C45/38 ,  C07C47/12 ,  C07C47/228

Abstract: The present invention concerns a process for the production of an aldehyde compound by an oxidation reaction of an alcohol compound in the presence of a mesostructured vanadium phosphorus mixed oxide catalyst, at a temperature comprised between 50° C. and 200° C., in presence of an oxidant. The reaction medium may also comprise a solvent.

Abstract translation: 本发明涉及通过醇化合物在介质结构化的钒磷混合氧化物催化剂存在下的氧化反应生产醛化合物的方法，在50℃和200℃之间的温度下，在存在 的氧化剂。 反应介质还可以包含溶剂。

公开(公告)号：US20170226286A1

公开(公告)日：2017-08-10

申请号：US15498923

申请日：2017-04-27

Applicant: RHODIA OPERATIONS

Inventor： Stéphane JEOL ,  Floryan DECAMPO ,  Leon ZHU

IPC: C08G69/26 ,  C08G69/28

CPC classification number: C08G69/26 ,  B29C45/0001 ,  B29C47/0004 ,  B29C49/0005 ,  B29K2077/00 ,  B29K2077/10 ,  B29L2031/731 ,  C08G69/00 ,  C08G69/28

Abstract: The present disclosure relates to a novel polyamide synthesized from biobased monomers. The novel polyamide comprises the repeating unit of formula I, described herein, in which R represents a covalent bond or a divalent hydrocarbon-based group chosen from saturated or unsaturated aliphatics, saturated or unsaturated cycloaliphatics, aromatics, arylaliphatics and alkylaromatics. The present disclosure also relates to a process for preparing the said polyamide, to its uses, and to articles and compositions comprising the said polyamide.

公开(公告)号：US20170217916A1

公开(公告)日：2017-08-03

申请号：US15324932

申请日：2015-07-08

Applicant: RHODIA OPERATIONS

Inventor： Peng LI ,  Floryan DECAMPO

IPC: C07D307/52

CPC classification number: C07D307/52 ,  C07C209/26 ,  C07C211/26

Abstract: A process for the production of aromatic primary amines, by reacting an aromatic dialdehyde with hydrogen and ammonia or an ammonia-liberating compound, in the presence of a hydrogenation catalyst and an amine, wherein the molar ratio of the amine to the aromatic dialdehyde is no less than 1:4 at the start of the reaction.

公开(公告)号：US20150344453A1

公开(公告)日：2015-12-03

申请号：US14652493

申请日：2013-12-20

Applicant: RHODIA OPERATIONS ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C. N. R. S.)

Inventor： Floryan DECAMPO ,  Damien CARTIGNY ,  Mohamad OUSMANE ,  Marc PERA TITUS

IPC: C07D307/52 ,  C07C211/46 ,  C07C211/01 ,  B01J31/18 ,  C07F5/00 ,  C07F15/02 ,  C07F7/28 ,  C07F9/00 ,  C07C209/18 ,  C07C211/52

CPC classification number: C07D307/52 ,  B01J31/12 ,  B01J31/14 ,  B01J31/1805 ,  B01J2231/44 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/56 ,  B01J2531/842 ,  C07C209/16 ,  C07C209/18 ,  C07C211/01 ,  C07C211/27 ,  C07C211/46 ,  C07C211/52 ,  C07C211/54 ,  C07F5/003 ,  C07F7/28 ,  C07F9/005 ,  C07F15/025

Abstract: The present invention concerns a process to obtain primary, secondary or tertiary amines, via a direct amination reaction of alcohols in presence of bis(perfluoroalkylsulfonimide) acid or salts thereof catalysts, and derivatives.

Abstract translation: 本发明涉及通过在双（全氟烷基亚磺酰亚胺）酸或其盐催化剂及其衍生物的存在下醇的直接胺化反应获得伯，仲或叔胺的方法。

公开(公告)号：US20200172501A1

公开(公告)日：2020-06-04

申请号：US16781356

申请日：2020-02-04

Applicant: RHODIA OPERATIONS

Inventor： Peng LI ,  Floryan DECAMPO

IPC: C07D307/52 ,  C07C209/26

Abstract: The present disclosure relates to a process for the production of aromatic primary amines, by reacting an aromatic dialdehyde with hydrogen and ammonia or an ammonia-liberating compound, in the presence of a hydrogenation catalyst and an amine, wherein the molar ratio of the amine to the aromatic dialdehyde is no less than 1:4 at the start of the reaction.

公开(公告)号：US20160251290A1

公开(公告)日：2016-09-01

申请号：US15027645

申请日：2014-10-07

Applicant: RHODIA OPERATIONS ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Xiaoshuang FENG ,  Floryan DECAMPO ,  Yan ZHAO ,  Zhaoyu FAN ,  Luca MERLO ,  Claudio OLDANI

IPC: C07C41/09 ,  B01J31/10 ,  C11D1/72

CPC classification number: C07C41/09 ,  B01J31/10 ,  C08G65/34 ,  C08G2650/54 ,  C08L71/00 ,  C11D1/72 ,  C07C43/13

Abstract: Disclosed is a process for preparing at least one ether compound, comprising reacting at least one alcohol (I) with at least one polyol (II) in the presence of a functional polymer [polymer (F)] as a catalyst (X), wherein: the alcohol (I) is represented by the general formula (1): R1-OH (1) wherein R1 is a hydrocarbon group having 1 to 36 carbon atoms, the polyol (II) is represented by the general formula (2): R2-(OH) m (2) wherein R2 represents the skeleton moiety of the polyol and m is an integer of from 2 to 20, and polymer (F) is a polymer comprising recurring units derived from at least one ethylenically unsaturated monomer [monomer (M)] and bearing at least one cation exchange group. Further disclosed is a surfactant composition obtained by said process, and featuring an excellent detergency performance.

Abstract translation: 公开了一种制备至少一种醚化合物的方法，包括在功能性聚合物[聚合物（F）]作为催化剂（X）的存在下使至少一种醇（I）与至少一种多元醇（II）反应，其中 醇（I）由通式（1）表示：R1-OH（1）其中R1是具有1至36个碳原子的烃基，多元醇（II）由通式（2）表示： R2-（OH）m（2）其中R2表示多元醇的骨架部分，m为2至20的整数，聚合物（F）为包含衍生自至少一种烯属不饱和单体[单体 （M）]并带有至少一个阳离子交换基团。 进一步公开了通过所述方法获得的表面活性剂组合物，具有优异的洗涤性能。

公开(公告)号：US20160244401A1

公开(公告)日：2016-08-25

申请号：US15027727

申请日：2013-10-15

Applicant: RHODIA OPERATIONS ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

Inventor： Zhen YAN ,  Mohamad OUSMANE ,  Marc PERA-TITUS ,  Floryan DECAMPO

IPC: C07C209/18 ,  B01J23/63

CPC classification number: C07C209/18 ,  B01J23/63 ,  B01J35/1019 ,  B01J37/0201 ,  C07C209/16 ,  C07C2601/16 ,  C07D215/06 ,  C07D307/14 ,  C07D307/52 ,  C07C211/48 ,  C07C211/12 ,  C07C211/11 ,  C07C211/09 ,  C07C211/10 ,  C07C211/27 ,  C07C211/45

Abstract: Disclosed is a process for preparing a primary, a secondary or a tertiary amine via the direct amination of an alcohol in the presence of a catalyst. The catalyst is composed of palladium or a palladium compound and a cerium oxide supporter.

Abstract translation: 公开了一种在催化剂存在下通过醇的直接胺化来制备伯，仲或叔胺的方法。 催化剂由钯或钯化合物和氧化铈载体组成。

公开(公告)号：US20160060199A1

公开(公告)日：2016-03-03

申请号：US14784845

申请日：2014-04-17

Applicant: RHODIA OPERATIONS ,  ECOLE NORMALE SUPERIEURE DE LYON

Inventor： Floryan DECAMPO ,  Wenjuan ZHOU

IPC: C07C45/28 ,  C07C29/48

CPC classification number: C07C45/28 ,  C07C29/48 ,  C07C2601/08 ,  C07C2601/14 ,  C07C2601/18 ,  C07C35/08 ,  C07C35/06 ,  C07C35/20 ,  C07C49/395 ,  C07C49/403 ,  C07C49/413

Abstract: The present invention concerns a method of oxidizing a cycloalkane to form a product mixture containing a corresponding alcohol and ketone, said method comprising contacting a cycloalkane with an oxidant agent in the presence of catalytic effective amount of metal triflates or metal triflmidates catalysts.

Abstract translation: 本发明涉及氧化环烷烃以形成含有相应的醇和酮的产物混合物的方法，所述方法包括在催化有效量的金属三氟甲磺酸盐或金属三氟甲磺酸盐催化剂的存在下使环烷烃与氧化剂接触。