Abstract:
Photoactive additives, such as cross-linkable polycarbonate resins, are disclosed. The additive is formed from the reaction of a monohydroxybenzophenone, a dihydroxybenzophenone, a diol chain extender, and one or more linker moieties having functional groups that react with the phenolic groups on the other ingredients. If desired, a secondary linker moiety and/or an end-capping agent can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.
Abstract:
Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density≦300 measured according to ISO 5659-2, and a MAHRE≦90 kW/m2 measured according to ISO 5660-1, a multiaxial impact energy ≧100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.
Abstract:
A thermoplastic composition is disclosed that includes a polyaryl ester polymer or copolymer and a phthalone compound according to the formula wherein Z1 represents the atoms necessary to complete a 9- to 13-membered single or fused aromatic ring structure, Z2 represents the atoms necessary to complete a pyridine or quinoline ring, each R1 and each R2 can independently be halogen, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an aromatic or aliphatic thioether group, an aromatic or aliphatic carboxylic acid ester group, or an aromatic or aliphatic amide group, a is an integer from 0 to 6, b is an integer from 0 to 4, n is 1 or 2, and X is present only if n=2 and is a single bond or a divalent organic radical bonded to the Z1 ring structure through an ether, ketone, or thio linkage.
Abstract:
Photoactive additives are disclosed. The additive includes a benzophenone having at least one substituent that comprises a divalent linker and a linking group, wherein the linking group is a carboxyl group, ester group, or acid halide group. The additive can be a polymer, an oligomer, or a compound. When added to a base polymeric resin, the photoactive additive permits crosslinking upon exposure to ultraviolet light.
Abstract:
Thin walled products having good scratch resistance are disclosed, as are processes for making such products (e.g. films, sheets, and thin walled articles). The product includes a thin layer formed from (A) a cross-linkable polycarbonate resin having endcaps derived from a monohydroxybenzophenone; and (B) if desired, a base polymeric resin. When exposed to ultraviolet light, crosslinking will occur in the layer with the cross-linkable polycarbonate resin, enhancing the scratch resistance properties of the thin layer and the overall product.
Abstract:
A composition comprises a first polycarbonate having a limited oxygen index of greater than 26% measured according to ISO 4589 on a 4 mm thick plaque, wherein an article molded from the first polycarbonate has a smoke density after 4 minutes (DS-4) of greater than 600 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2; and a second polymer different from the first polycarbonate, the second polymer comprising a poly(carbonate-siloxane) copolymer, a polydialkylsiloxane, or a combination comprising at least one of the foregoing; wherein an article molded from the second polymer has a smoke density after 4 minutes (DS-4) of greater than 600 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2; wherein an article molded from the composition has a smoke density after 4 minutes (DS-4) of smaller than 480 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2.
Abstract translation:组合物包含在4mm厚的板上根据ISO 4589测量的具有大于26%的有限氧指数的第一聚碳酸酯,其中由第一聚碳酸酯模制的制品在4分钟后具有烟密度(DS-4)较大 超过600根据ISO 5659-2确定,厚度为3毫米,厚度为50千瓦/平方米; 和不同于第一聚碳酸酯的第二聚合物,第二聚合物包含聚(碳酸酯 - 硅氧烷)共聚物,聚二烷基硅氧烷或包含前述的至少一种的组合; 其中由第二聚合物成型的制品在50kW / m 3的3mm厚的板上具有大于600°的根据ISO 5659-2测定的4分钟(DS-4)之后的烟雾浓度; 其中由所述组合物模制的制品在50kW / m 2的3mm厚的板上具有根据ISO 5659-2测定的小于480的4分钟后的烟浓度(DS-4)。
Abstract:
Photoactive additives are disclosed. The additive includes a benzophenone having at least one substituent that comprises a divalent linker and a linking group, wherein the linking group is a carboxyl group, ester group, or acid halide group. The additive can be a polymer, an oligomer, or a compound. When added to a base polymeric resin, the photoactive additive permits crosslinking upon exposure to ultraviolet light.
Abstract:
Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.
Abstract:
Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density ≦300 measured according to ISO 5659-2, and a MAHRE ≦90 kW/m2 measured according to ISO 5660-1, a multiaxial impact energy ≧100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.
Abstract:
Different interfacial processes for producing photoactive additives are disclosed. Generally, the photoactive additives are formed from a photoactive moiety, a first linker moiety, and a diol chain extender. The resulting additives can be crosslinked with other polymers upon exposure to UV radiation.