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1.发明授权Polyester composition and film using same, sheet-like structure, electric insulation sheet, and solar cell back sheet, and manufacturing method therefor 有权聚酯组合物和使用其的薄膜，片状结构，电绝缘片和太阳能电池背板及其制造方法公开(公告)号：US09396836B2
公开(公告)日：2016-07-19
申请号：US14003032
申请日：2012-02-29
申请人： Tadamasa Suzuki , Shigeru Aoyama , Hiroji Kojima , Kozo Takahashi
发明人： Tadamasa Suzuki , Shigeru Aoyama , Hiroji Kojima , Kozo Takahashi
CPC分类号： H01B3/421 , C08G63/80 , C08G63/83 , C08J5/18 , C08J2367/02 , C08K3/32 , H01L31/049 , Y02E10/50 , Y10T156/10 , Y10T428/2495 , C08L67/00
摘要： A polyester composition contains polyester, a phosphoric acid and an alkali metal phosphate, a phosphorous element content P (mol/t) is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of the polyester composition. The polyester composition contains at least one metal element of Mn and Ca, any divalent metal element content other than Mn and Ca is 5 ppm or less, and when an alkali metal element content relative to the polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in the polyester composition which is calculated by expression (i) below and the phosphorous element content P (mol/t) satisfy expression (ii): (i) M=M1/2+M2 and (ii) 1.1≦M/P≦3.0.
摘要翻译： 聚酯组合物含有聚酯，磷酸和碱金属磷酸盐，相对于整个聚酯组合物，磷元素含量P（mol / t）为1.8mol / t以上且5.0mol / t以下。 聚酯组合物含有至少一种Mn和Ca的金属元素，Mn和Ca以外的二价金属元素含量为5ppm以下，当相对于聚酯组合物的碱金属元素含量为M1（mol / t ），并且相对于聚酯组合物的Mn元素含量和Ca元素含量的总量以M2（mol / t）表示，聚酯组合物中的金属元素含量M（mol / t）由式（i ）和磷元素含量P（mol / t）满足式（ii）：（i）M = M1 / 2 + M2和（ii）1.1＆nlE; M / P＆nlE; 3.0。
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2.发明申请POLYESTER COMPOSITION AND FILM USING SAME, SHEET-LIKE STRUCTURE, ELECTRIC INSULATION SHEET, AND SOLAR CELL BACK SHEET, AND MANUFACTURING METHOD THEREFOR 有权聚酯组合物和使用其的膜，片状结构，电绝缘片和太阳能电池片及其制造方法公开(公告)号：US20140023841A1
公开(公告)日：2014-01-23
申请号：US14003032
申请日：2012-02-29
申请人： Tadamasa Suzuki , Shigeru Aoyama , Hiroji Kojima , Kozo Takahashi
发明人： Tadamasa Suzuki , Shigeru Aoyama , Hiroji Kojima , Kozo Takahashi
IPC分类号： H01B3/42
CPC分类号： H01B3/421 , C08G63/80 , C08G63/83 , C08J5/18 , C08J2367/02 , C08K3/32 , H01L31/049 , Y02E10/50 , Y10T156/10 , Y10T428/2495 , C08L67/00
摘要： A polyester composition contains polyester, a phosphoric acid and an alkali metal phosphate, a phosphorous element content P (mol/t) is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of the polyester composition. The polyester composition contains at least one metal element of Mn and Ca, any divalent metal element content other than Mn and Ca is 5 ppm or less, and when an alkali metal element content relative to the polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in the polyester composition which is calculated by expression (i) below and the phosphorous element content P (mol/t) satisfy expression (ii): (i) M=M1/2+M2 and (ii) 1.1≦M/P≦3.0.
摘要翻译： 聚酯组合物含有聚酯，磷酸和碱金属磷酸盐，相对于整个聚酯组合物，磷元素含量P（mol / t）为1.8mol / t以上且5.0mol / t以下。 聚酯组合物含有至少一种Mn和Ca的金属元素，Mn和Ca以外的二价金属元素含量为5ppm以下，当相对于聚酯组合物的碱金属元素含量为M1（mol / t ），并且相对于聚酯组合物的Mn元素含量和Ca元素含量的总量以M2（mol / t）表示，聚酯组合物中的金属元素含量M（mol / t）由式（i ）和磷元素含量P（mol / t）满足表达式（ii）：（i）M = M1 / 2 + M2和（ii）1.1 @ M / P 3.0。
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3.发明授权Polyester film, laminated film, solar battery backsheet and solar battery 有权聚酯薄膜，层压薄膜，太阳能电池背板和太阳能电池公开(公告)号：US08981212B2
公开(公告)日：2015-03-17
申请号：US13376287
申请日：2010-06-02
申请人： Shigeru Aoyama , Ayako Shimazu , Atsushi Shiomi , Kozo Takahashi
发明人： Shigeru Aoyama , Ayako Shimazu , Atsushi Shiomi , Kozo Takahashi
IPC分类号： H01L31/00 , B32B5/16 , C08J5/18 , H01L31/048
CPC分类号： C08J5/18 , B32B9/00 , B32B2307/412 , C08J2367/02 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y02E10/52 , Y10T428/249921 , Y10T428/254
摘要： A polyester film includes particles and two kinds of crystalline polyester resins in which a sea-island structure is formed, wherein, if a crystallization temperature of a crystalline polyester resin A that forms a continuous phase or matrix phase in the polyester film is represented by TccA and a crystallization temperature of a crystalline polyester resin B that forms a dispersion phase or domain phase in the polyester film is represented by TccB, expression (1) below is satisfied, and a degree of flatness of the dispersion phase is 3 or more, and 70% or more of a total number of the particles present in the dispersion phase or are in contact with the dispersion phase: TccA−TccB≧5° C. Expression (1).
摘要翻译： 聚酯膜包括颗粒和形成海岛结构的两种结晶聚酯树脂，其中如果在聚酯膜中形成连续相或基质相的结晶性聚酯树脂A的结晶温度由TccA 在聚酯膜中形成分散相或畴相的结晶性聚酯树脂B的结晶温度由TccB表示，满足下述式（1），分散相的平坦度为3以上， 存在于分散相中或与分散相接触的颗粒总数的70％以上：TccA-TccB≥5℃。表达式（1）。
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4.发明授权公开(公告)号：US08609255B2
公开(公告)日：2013-12-17
申请号：US13389637
申请日：2010-09-07
CPC分类号： B32B27/36 , B32B27/18 , B32B27/20 , B32B2250/24 , B32B2307/3065 , B32B2307/71 , B32B2307/714 , B32B2457/12 , H01L31/049 , Y02E10/50 , Y10T428/2495 , Y10T428/31721 , Y10T428/31786
摘要： A polyester film has a laminate structure including a polyester layer (layer P1) containing a crystalline polyester and inorganic particles and a polyester layer (layer P2) containing a crystalline polyester, inorganic particles, and an antihydrolysis segment, wherein the content (Wa2) of the inorganic particles in the layer P2 is at least 10 mass % of the layer P2, the difference between the content (Wa2) (mass %) of the inorganic particles in the layer P2 and the content (Wa1) (mass %) of the inorganic particles in the layer P1, Wa2−Wa1, is 5 to 25 mass %, and the content (Wb2) of the antihydrolysis segment in the layer P2 is 0.02 to 1.5 mass % of the layer P2.
摘要翻译： 聚酯膜具有包含含有结晶性聚酯和无机粒子的聚酯层（层P1）和含有结晶性聚酯，无机粒子和抗水解链段的聚酯层（P2层）的层叠结构，其中，含量（Wa2） 层P2中的无机颗粒为层P2的至少10质量％，层P2中的无机粒子的含量（质量％）（Wa2）与含量（Wa1）（质量％）之差 层P1，Wa2-Wa1中的无机粒子为5〜25质量％，层P2中的抗水解段的含量（Wb2）为层P2的0.02〜1.5质量％。
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公开(公告)号：US20120202083A1
公开(公告)日：2012-08-09
申请号：US13502208
申请日：2010-10-19
申请人： Atsushi Shiomi , Shigeru Aoyama , Ayako Shimazu , Kozo Takahashi
发明人： Atsushi Shiomi , Shigeru Aoyama , Ayako Shimazu , Kozo Takahashi
CPC分类号： B29C55/12 , B29K2067/00 , B29K2105/16 , B29K2995/0017 , B29K2995/0055 , B32B27/36 , C08J5/18 , C08J2367/02 , C08K3/013 , C08K3/22 , C08L67/02 , C08L81/02 , C08L81/04 , H01L31/049 , Y02E10/50 , Y10T428/31786 , C08L2666/18 , C08L81/00
摘要： A biaxially oriented polyester film including a polyester layer (P1 layer) containing a polyester including ethylene terephthalate as a main constituent, a high melting point resin having a melting point TmB1 of not less than 260° C. and not more than 320° C., and inorganic particles, wherein content of the high melting point resin in the P1 layer, WB1, is not less than 2% by mass and not more than 40% by mass based on the P1 layer; in the P1 layer, dispersion phases composed of the high melting point resin are present in the polyester; and average longitudinal length of the dispersion phases is not more than 10,000 nm (10 μm).
摘要翻译： 包含含有以对苯二甲酸乙二醇酯为主要成分的聚酯的聚酯层（P1层）的双轴取向聚酯膜，熔点TmB1为260℃以上320℃以下的高熔点树脂 以及P1层中的高熔点树脂的含量WB1相对于P1层为2质量％以上且40质量％以下的无机粒子， 在P1层中，由高熔点树脂构成的分散相存在于聚酯中; 并且分散相的平均纵向长度不大于10,000nm（10μm）。
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公开(公告)号：US08709589B2
公开(公告)日：2014-04-29
申请号：US12602866
申请日：2008-05-29
申请人： Shigeru Aoyama , Akikazu Kikuchi , Kozo Takahashi
发明人： Shigeru Aoyama , Akikazu Kikuchi , Kozo Takahashi
CPC分类号： C08L67/02 , B32B3/26 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/205 , B32B27/325 , B32B27/36 , B32B2255/10 , B32B2270/00 , B32B2307/21 , B32B2307/306 , B32B2307/40 , B32B2307/4026 , B32B2307/416 , B32B2307/50 , B32B2307/514 , B32B2307/558 , B32B2457/12 , B32B2457/20 , B32B2457/202 , B32B2551/00 , B32B2590/00 , C08J5/18 , C08J2367/02 , C08L45/00 , C08L67/00 , C08L67/025 , G02B6/0065 , G02F1/133605 , Y10T428/249986 , Y10T428/249988 , Y10T428/249991 , Y10T428/249992 , Y10T428/2982 , Y10T428/31786 , C08L2666/18 , C08L2666/04 , C08L2666/02
摘要： A white polyester film has a high level of whiteness, reflectivity, lightness, or thermal dimensional stability, and a surface light source that is produced with the white polyester film and has a high level of brightness characteristics. The white polyester film includes a white polyester layer (W layer) containing a polyester resin component (A) and a component (B) incompatible with the resin component (A) and having voids inside, wherein the incompatible component (B) is a cyclic-olefin resin (b) having a glass transition temperature of 110° C. or more, and the content Z of the cyclic-olefin resin (b) in the white polyester layer (W layer) is from 5% by weight to 50% by weight, based on the amount of the white polyester layer (W layer). The surface light source is produced therewith.
摘要翻译： 白色聚酯薄膜具有高白度，反射率，亮度或热尺寸稳定性，以及由白色聚酯薄膜制成且具有高亮度特性的表面光源。 白色聚酯膜包括含有聚酯树脂成分（A）的白色聚酯层（W层）和与树脂成分（A）不相容的成分（B），内部具有空隙，其中不相容性成分（B）为环状 玻璃化转变温度为110℃以上的α-烯烃树脂（b），白色聚酯层（W层）中的环状烯烃树脂（b）的含量Z为5重量％〜50体积％ ，基于白色聚酯层（W层）的量。 表面光源由其制成。
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7.发明授权Polyester film and a production process thereof, and a surface light source, solar battery backsheet and solar battery respectively obtained by using the same 有权聚酯薄膜及其制造方法，以及分别通过使用该聚酯薄膜的表面光源，太阳能电池底片和太阳能电池公开(公告)号：US08680206B2
公开(公告)日：2014-03-25
申请号：US12745028
申请日：2008-11-28
申请人： Shigeru Aoyama , Akikazu Kikuchi , Kozo Takahashi
发明人： Shigeru Aoyama , Akikazu Kikuchi , Kozo Takahashi
IPC分类号： B32B27/36
CPC分类号： C08J5/18 , B32B2367/00 , C08J2367/02 , C08L23/02 , C08L23/12 , C08L23/20 , C08L51/06 , C08L67/02 , C08L2205/03 , H01L31/049 , Y02E10/50 , Y10T428/254 , C08L2666/24
摘要： A polyester film includes a polyester layer (W layer) containing an aromatic polyester resin (A) and a component (B) incompatible with the polyester resin (A), wherein the incompatible component (B) contains an acid-denaturated polyolefin resin (b2) and is dispersed as dispersion pieces with a flatness of 10 or higher in the polyester layer (W layer), and wherein volume occupancy of the dispersion pieces in the polyester layer (W layer) is 3 vol % to less than 50 vol %, and volume occupancy of voids in the polyester layer (W layer) is less than 3 vol %.
摘要翻译： 聚酯膜包括含有芳香族聚酯树脂（A）的聚酯层（W层）和与聚酯树脂（A）不相容的成分（B），其中不相容成分（B）含有酸变性聚烯烃树脂（b2 ），在聚酯层（W层）中分散为10以上的分散体，其中聚酯层（W层）中的分散体的体积占有率为3体积％〜小于50体积％ 并且聚酯层（W层）中空隙的体积占有率小于3体积％。
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8.发明申请POLYESTER FILM, LAMINATED FILM, AND SOLAR BATTERY BACKSHEET EMPLOYING AND SOLAR BATTERY THAT USE THE FILM 有权聚酯膜，层压膜和太阳能电池背板使用和太阳能电池使用电影公开(公告)号：US20120080089A1
公开(公告)日：2012-04-05
申请号：US13376287
申请日：2010-06-02
申请人： Shigeru Aoyama , Ayako Shimazu , Atsushi Shiomi , Kozo Takahashi
发明人： Shigeru Aoyama , Ayako Shimazu , Atsushi Shiomi , Kozo Takahashi
IPC分类号： H01L31/0216 , B32B5/16 , B29C47/00 , B32B27/36
CPC分类号： C08J5/18 , B32B9/00 , B32B2307/412 , C08J2367/02 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y02E10/52 , Y10T428/249921 , Y10T428/254
摘要： A polyester film includes particles and two kinds of crystalline polyester resins in which a sea-island structure is formed, wherein, if a crystallization temperature of a crystalline polyester resin A that forms a continuous phase or matrix phase in the polyester film is represented by TccA and a crystallization temperature of a crystalline polyester resin B that forms a dispersion phase or domain phase in the polyester film is represented by TccB, expression (1) below is satisfied, and a degree of flatness of the dispersion phase is 3 or more, and 70% or more of a total number of the particles present in the dispersion phase or are in contact with the dispersion phase: TccA−TccB≧5° C. Expression (1).
摘要翻译： 聚酯膜包括颗粒和形成海岛结构的两种结晶聚酯树脂，其中如果在聚酯膜中形成连续相或基质相的结晶性聚酯树脂A的结晶温度由TccA 在聚酯膜中形成分散相或畴相的结晶性聚酯树脂B的结晶温度由TccB表示，满足下述式（1），分散相的平坦度为3以上， 存在于分散相中或与分散相接触的颗粒总数的70％以上：TccA-TccB≥5℃。表达式（1）。
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公开(公告)号：US20100209694A1
公开(公告)日：2010-08-19
申请号：US12679587
申请日：2008-09-25
申请人： Shigeru Aoyama , Akikazu Kikuchi , Kozo Takahashi
发明人： Shigeru Aoyama , Akikazu Kikuchi , Kozo Takahashi
IPC分类号： B32B3/26
CPC分类号： G02B5/0284 , G02B5/0242 , G02B5/0247 , G02B5/08 , G02F1/133605 , G02F2201/086 , G02F2202/36 , Y10T428/249986
摘要： A white film includes therein resin particles and voids formed around the resin particles, the film having a layer (S layer), wherein the number-average particle size Dn of the resin particles is 1.5 μm or less, the resin particles are contained in a number of 0.05 or more particles/μm2, and a proportion of the number of resin particles having a particle diameter of 2 μm or more is 15% or less.
摘要翻译： 白色膜包括树脂颗粒和在树脂颗粒周围形成的空隙，该膜具有层（S层），其中树脂颗粒的数均粒径Dn为1.5μm以下，树脂颗粒包含在 0.05以上的粒子数/μm2，粒径为2μm以上的树脂粒子数的比例为15％以下。
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10.发明申请公开(公告)号：US20120192944A1
公开(公告)日：2012-08-02
申请号：US13389637
申请日：2010-09-07
IPC分类号： H01L31/0216 , B32B5/00 , B32B5/02 , B32B27/36
CPC分类号： B32B27/36 , B32B27/18 , B32B27/20 , B32B2250/24 , B32B2307/3065 , B32B2307/71 , B32B2307/714 , B32B2457/12 , H01L31/049 , Y02E10/50 , Y10T428/2495 , Y10T428/31721 , Y10T428/31786
摘要： A polyester film has a laminate structure including a polyester layer (layer P1) containing a crystalline polyester and inorganic particles and a polyester layer (layer P2) containing a crystalline polyester, inorganic particles, and an antihydrolysis segment, wherein the content (Wa2) of the inorganic particles in the layer P2 is at least 10 mass % of the layer P2, the difference between the content (Wa2) (mass %) of the inorganic particles in the layer P2 and the content (Wa1) (mass %) of the inorganic particles in the layer P1, Wa2−Wa1, is 5 to 25 mass %, and the content (Wb2) of the antihydrolysis segment in the layer P2 is 0.02 to 1.5 mass % of the layer P2.
摘要翻译： 聚酯膜具有包含含有结晶性聚酯和无机粒子的聚酯层（层P1）和含有结晶性聚酯，无机粒子和抗水解链段的聚酯层（层P2）的层压结构，其中，含量（Wa2）为 层P2中的无机颗粒为层P2的至少10质量％，层P2中的无机粒子的含量（质量％）（Wa2）与含量（Wa1）（质量％）之差 层P1，Wa2-Wa1中的无机粒子为5〜25质量％，层P2中的抗水解段的含量（Wb2）为层P2的0.02〜1.5质量％。
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