摘要:
A method is provided involving altering the viscosity of bio-derived paraffins to produce a paraffinic fluid, where the altering step includes chlorinating the bio-derived paraffins; the bio-derived paraffins include a hydrodeoxygenated product produced by hydrodeoxygenating a bio-based feed where the bio-based feed includes bio-derived fatty acids, fatty acid esters, or a combination thereof; the bio-derived paraffins include n-paraffins; and the n-paraffins have a biodegradability of at least 40% after about 23 days of exposure to microorganisms. Also provided are methods of protecting and/or cleaning a substance by applying the paraffinic fluid.
摘要:
Disclosed is a mixture comprising the compound trans-1,1,1,4,4,4-hexafluoro-2-butene and at least one additional compound selected from the group consisting of HFOs, HFCs, HFEs, CFCs, CO2, olefins, organic acids, alcohols, hydrocarbons, ethers, aldehydes, ketones, and others such as methyl formate, formic acid, trans-1,2 dichloroethylene, carbon dioxide, cis-HFO-1234ze+HFO-1225yez; mixtures of these plus water; mixtures of these plus CO2; mixtures of these trans 1,2-dichloroethylene (DCE); mixtures of these plus methyl formate; mixtures with cis-HFO-1234ze+CO2; mixtures with cis-HFO-1234ze+HFO-1225yez+CO2; and mixtures with cis-HFO-1234ze+HFC-245fa. Also disclosed are methods of using and products of using the above compositions as blowing agents, solvents, heat transfer compositions, aerosol propellant compositions, fire extinguishing and suppressant compositions.
摘要:
To provide a composition for a heat cycle system having less influence over the ozone layer, having a low global warming potential and having excellent durability, and a heat cycle system.A composition for a heat cycle system comprising a working fluid containing trifluoroethylene and difluoromethane, and a lubricating oil, wherein the interaction distance (Ra1123) between trifluoroethylene and the lubricating oil as determined from the Hansen solubility parameters is shorter than the interaction distance (Ra32) between difluoromethane and the lubricating oil.
摘要:
Use as heat exchange or hydraulic liquids in circuits or equipments subjected to ionizing radiations and/or irradiation with neutrons, of fluorinated liquids selected from the group formed by: A) (per)fluoropolyethers, B) (per)fluorocarbons, C) hydrofluoroethers, appearing liquid under room conditions (25° C., 1 atm).
摘要:
Azeotropic or azeotrope-like compositions of effective amounts of 1,1,1,2,3,4,4,5,5,5-decafluoropentane, heptane and an alcohol such as methanol, ethanol, n-propanol or isopropanol, to form an azeotropic or azeotrope-like composition are disclosed that are useful as cleaning agents, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.
摘要:
A solid lubricant, consisting of solid perfluorocarbons, with linear or substantially linear carbon atoms chain, containing from 10 to 20 carbon atoms and having a value of surface tension ranging from 13 to 15 dyne/cm, is obtained by dimerization or co-dimerization of perfluorocarbonsulphonyl halogenidesC.sub.n F.sub.2n+1 SO.sub.2 X(in which X represents an atom of halogen), having a linear or substantially linear chain of carbon atoms and bearing the --SO.sub.2 X group at one end of the chain, operating at high temperature, with short reaction times, and preferably in the presence of a metal catalyst.The solid perfluorocarbon lubricant can be used, if desired as a mixture with paraffinic wax, on sliding surfaces, particularly consisting of a polymeric material either porous or made porous.
摘要:
There is proposed a process for the purification of fluorinated lubricants, free from hydrogen, such as perfluorinated ethers or chlorofluorocarbons, whose elimination can be dangerous for the environment owing to the fluorine release, such a process consisting in dissolving the lubricant in a fluorochlorinated hydrocarbon, then in precipitating by means of a grease solvent, in separating, in degasing and finally in filtering in order to remove the mechanical impurities.
摘要:
New polyfluoroalkyl iodides of the formula ##EQU1## are provided, wherein R.sub.f represents a fluorinated hydrocarbon radical with 3 to 18 carbon atoms, R.sub.1 represents hydrogen or fluorine, R.sub.3 and R.sub.4 each independently represents hydrogen, lower alkyl, hydroxyalkyl, carboxy, carbalkoxy, --(CH.sub.2).sub.p OCOR.sub.2, in which R.sub.2 represents hydrogen or alkyl with 1 to 3 carbon atoms and p is 0 or a whole number from 1 to 3, phenyl and alkylphenyl, or R.sub.3 and R.sub.4 together with the carbon atoms to which they are bonded represent an optionally substituted cycloaliphatic radical with 5 or 6 ring carbon atoms, and n is a whole number from 1 to 3.The new compounds are useful as intermediates for the manufacture of oil- and water-repellents, as oil- and water-repellents per se, as lubricants and as surface active assistants.
摘要:
A lubricant for working aluminium comprises an olefin or olefins of formula wherein R and R1 are hydrogen or fluorine, R1 may additionally be mono-, di- or trifluoromethyl and R11 is a saturated straight chain alkyl or fluoroalkyl radical having at least 8 carbon atoms. Preferred are straight-chain olefins or fluoro-olefins having 12 to 25 carbon atoms and unsaturation in the 1 or 2 position, and include cetene; 3,3,4-trifluorohexadecene-1; 1,1,1,2-tetrafluorohexadecene-2 and mixtures of olefins derived from the cracking of paraffin or the Fischer-Tropsch process. The olefins may be used by themselves, or with lubricating mineral oils or diesters, or diluted or dissolved in benzene, chlorinated hydrocarbons or kerosene. They may be also used in the form of aqueous emulsions or as greases. The effectiveness of the lubricants is compared with that of saturated compounds, or with compounds wherein the unsaturation is not in the 1- or 2-position.