Catalyst system for converting oxygenated hydrocarbons to aromatics
    91.
    发明授权
    Catalyst system for converting oxygenated hydrocarbons to aromatics 失效
    用于将氧化烃转化为芳族化合物的催化剂体系

    公开(公告)号:US06372680B1

    公开(公告)日:2002-04-16

    申请号:US09361885

    申请日:1999-07-27

    IPC分类号: B01J2906

    摘要: A catalyst system comprising a first solid material comprising a silicoaluminophosphate and a second solid material comprising a zeolite and a compound containing zinc and a metal selected from the group consisting of Group IIIA and Group VIB, and a method of preparing such catalyst system, are disclosed. The thus-obtained catalyst system is employed as a catalyst in the conversion of at least a portion of a hydrocarbon feedstock comprising oxygenated hydrocarbons to aromatics (BTX), and, in particular, xylenes. In an alternate embodiment, a hydrocarbon feedstock comprising oxygenated hydrocarbons are converted to aromatics by sequentially contacting the hydrocarbon feedstock with the first solid material and then the second solid material.

    摘要翻译: 一种催化剂体系,包括含有硅铝磷酸盐的第一固体材料和包含沸石和含有锌和选自IIIA族和VIB族的金属的化合物的第二固体材料及其制备方法 。 将由此获得的催化剂体系用作将至少一部分包含含氧烃的烃原料转化成芳族化合物(BTX),特别是二甲苯的催化剂。 在替代实施方案中,通过使烃原料与第一固体材料然后第二固体材料相继接触将包含含氧烃的烃原料转化为芳族化合物。

    Method of making a zeolite material
    92.
    发明授权
    Method of making a zeolite material 失效
    制备沸石材料的方法

    公开(公告)号:US06300270B1

    公开(公告)日:2001-10-09

    申请号:US09261887

    申请日:1999-03-03

    IPC分类号: B01J2906

    CPC分类号: B01J29/061

    摘要: A catalyst composition prepared by a method which comprises incorporating at least one transition metal into a calcined zeolite-silica material, calcining the resulting transition metal-incorporated calcined zeolite-silica material and contacting the resulting calcined transition metal-incorporated calcined zeolite-silica material with ammonium sulfide is disclosed. The thus-obtained catalyst composition is employed as a catalyst in the conversion of a hydrocarbon feedstock to at least one aromatic.

    摘要翻译: 一种催化剂组合物,其通过包括将至少一种过渡金属掺入煅烧沸石 - 二氧化硅材料中的方法制备,煅烧所得到的过渡金属掺入的煅烧沸石二氧化硅材料,并将所得煅烧过渡金属掺入的煅烧沸石 - 二氧化硅材料与 公开了硫化铵。 如此获得的催化剂组合物用作将烃原料转化为至少一种芳族化合物的催化剂。

    Hydrocarbon conversion processess
    93.
    发明授权
    Hydrocarbon conversion processess 失效
    烃转化过程

    公开(公告)号:US06235955B1

    公开(公告)日:2001-05-22

    申请号:US09632892

    申请日:2000-08-07

    IPC分类号: C07C252

    摘要: A composition, a process for producing the composition, and a hydrocarbon conversion process for converting a hydrocarbon stream such as, for example, gasoline, to olefins and C6 to C8 aromatic hydrocarbons such as toluene and xylenes are disclosed. The composition comprises a silylated catalyst which comprises a zeolite, a clay or silica, and a promoter. The process for producing the composition comprises the steps: (1) combining a zeolite with a clay or silica and a promoter under a condition sufficient to bind the clay to the zeolite to produce a clay-bound zeolite; (2) heating the clay-bound zeolite to produce a modified zeolite; and (3) silylating the modified zeolite with a silylating agent. The hydrocarbon conversion process comprises contacting a hydrocarbon stream with the catalyst composition under a condition sufficient to effect the conversion of a hydrocarbon to an olefin and a C6 to C8 aromatic hydrocarbon.

    摘要翻译: 公开了一种组合物,该组合物的制备方法以及用于将烃流例如汽油转化为烯烃和C 6至C 8芳族烃如甲苯和二甲苯的烃转化方法。 该组合物包含甲硅烷基化催化剂,其包含沸石,粘土或二氧化硅和助催化剂。 制备组合物的方法包括以下步骤:(1)在足以将粘土结合到沸石以产生粘土结合的沸石的条件下,将沸石与粘土或二氧化硅和助催化剂组合; (2)加热粘土结合的沸石以产生改性沸石; 和(3)用甲硅烷基化剂使改性沸石甲硅烷基化。 烃转化方法包括在足以使烃转化为烯烃和C 6至C 8芳族烃的条件下使烃流与催化剂组合物接触。

    Process and catalyst for upgrading liquid hydrocarbons
    95.
    发明授权
    Process and catalyst for upgrading liquid hydrocarbons 失效
    液化烃升级的工艺和催化剂

    公开(公告)号:US6162353A

    公开(公告)日:2000-12-19

    申请号:US469202

    申请日:1999-12-21

    IPC分类号: C10G45/04

    CPC分类号: C10G45/04 C10G2400/02

    摘要: An improved process and novel catalyst for upgrading catalytically cracked liquid hydrocarbons whereby the hydrodesulfurization and liquid yield of the hydrocarbons are enhanced while the octane number thereof is substantially maintained. The process basically comprises contacting the hydrocarbons with the catalyst composition which is comprised of a sulfided, molybdenum carbide and zinc hexaborate promoted, binder bound zeolite in the presence of hydrogen and under conditions sufficient to effect said upgrading.

    摘要翻译: 一种用于改进催化裂化液体烃的改进方法和新型催化剂,从而提高烃的加氢脱硫和液体产率,同时基本维持其辛烷值。 该方法基本上包括使烃与催化剂组合物接触,所述催化剂组合物由硫化物,碳化钼和六硼酸锌组成,所述催化剂组合物在氢的存在下和足以实现所述升级的条件下与粘合剂结合的沸石接触。

    Catalyst composition and processes therefor and therewith
    97.
    发明授权
    Catalyst composition and processes therefor and therewith 失效
    催化剂组合物及其工艺及其

    公开(公告)号:US06124516A

    公开(公告)日:2000-09-26

    申请号:US235071

    申请日:1999-01-21

    摘要: A process for isomerizing hydrocarbons is disclosed. The process includes contacting, under reaction conditions, a hydrocarbon-containing fluid containing a saturated hydrocarbon, preferably a normal paraffin containing in the range of from about 4 carbon atoms to about 10 carbon atoms per molecule, with a composition in a single-stage reaction zone. The process includes isomerizing such saturated hydrocarbon to thereby provide a product containing an isomerized hydrocarbon. The composition used in the process contains a zeolite and a metal carbide. The composition can be produced by combining a metal, preferably such metal is in a metal compound, with the zeolite to thereby provide a metal-promoted zeolite. The metal-promoted zeolite is then calcined or steamed followed by contacting the resulting zeolite with a hydrocarbon, preferably in the presence of hydrogen, to thereby provide a carburized metal-promoted zeolite.

    摘要翻译: 公开了一种使烃异构化的方法。 该方法包括在反应条件下将含有饱和烃,优选每分子约4个碳原子至约10个碳原子的正链烷烃的含烃流体与单步反应中的组合物 区。 该方法包括异构化这种饱和烃,从而提供含有异构化烃的产物。 该方法中使用的组合物含有沸石和金属碳化物。 组合物可以通过将金属(优选金属化合物中的金属)与沸石结合从而提供金属促进的沸石来制备。 然后将金属促进的沸石煅烧或蒸汽,然后使所得的沸石与烃接触,优选在氢的存在下接触,从而提供渗碳的金属促进的沸石。

    Mazzite supported catalyst
    98.
    发明授权

    公开(公告)号:US6124228A

    公开(公告)日:2000-09-26

    申请号:US90719

    申请日:1998-06-04

    摘要: A catalyst, method for preparing the catalyst, and method for using the catalyst having improved conversion and/or selectivity in the dehydrogenation of hydrocarbons. The catalyst being prepared by modifying and impregnating a mazzite zeolite. Modification of the original mazzite zeolite may include steps for ion-exchanging, dealuminating, physically mixing with chromic oxide, shaping, and calcining. Once modified, the mazzite zeolite may be impregnated with at least one metal selected from the group consisting of chromium, molybdenum, tungsten and oxides of these metals.

    Hydrocarbon conversion catalyst composition and processes therefor and
therewith
    99.
    发明授权
    Hydrocarbon conversion catalyst composition and processes therefor and therewith 失效
    烃转化催化剂组合物及其工艺及其

    公开(公告)号:US6124227A

    公开(公告)日:2000-09-26

    申请号:US143321

    申请日:1998-08-28

    摘要: A composition, a process for producing the composition, and a hydrocarbon conversion process for converting a hydrocarbon stream such as, for example, gasoline, to olefins and C.sub.6 to C.sub.8 aromatic hydrocarbons such as toluene and xylenes are disclosed. The composition comprises a silylated catalyst which comprises a zeolite, a clay or silica, and a promoter. The process for producing the composition comprises the steps: (1) combining a zeolite with a clay or silica and a promoter under a condition sufficient to bind the clay to the zeolite to produce a clay-bound zeolite; (2) heating the clay-bound zeolite to produce a modified zeolite; and (3) silylating the modified zeolite with a silylating agent. The hydrocarbon conversion process comprises contacting a hydrocarbon stream with the catalyst composition under a condition sufficient to effect the conversion of a hydrocarbon to an olefin and a C.sub.6 to C.sub.8 aromatic hydrocarbon.

    摘要翻译: 公开了一种组合物,该组合物的制备方法以及用于将烃流例如汽油转化为烯烃和C 6至C 8芳族烃如甲苯和二甲苯的烃转化方法。 该组合物包含甲硅烷基化催化剂,其包含沸石,粘土或二氧化硅和助催化剂。 制备组合物的方法包括以下步骤:(1)在足以将粘土结合到沸石以产生粘土结合的沸石的条件下,将沸石与粘土或二氧化硅和助催化剂组合; (2)加热粘土结合的沸石以产生改性沸石; 和(3)用甲硅烷基化剂使改性沸石甲硅烷基化。 烃转化方法包括在足以使烃转化为烯烃和C 6至C 8芳族烃的条件下使烃流与催化剂组合物接触。