摘要:
The invention relates to the preparation of low-viscosity ester mixtures for transesterification of vegetable or animal fats or oils with monofunctional esters.
摘要:
The present invention relates to aqueous polyurethane-polyurea dispersions having two discrete maxima in the particle size distribution, wherein the maximum of the fine fraction is between 51 and 150 nm and the maximum of the coarse fraction is between 160 and 700 nm. The present invention also relates to a process for preparing the polyurethane-polyurea dispersions, to coating compositions containing these polyurethane-polyurea dispersions, and to coated substrates prepared from these coating compositions.
摘要:
The present invention relates to a hydroxy-functional copolymer P, which is present as a dispersion and/or solution in water, and is obtained by successively carrying out process steps A-D: A) initially introducing a hydrophobic polymer containing hydroxyl groups into a reaction vessel, B) introducing an initiator component into that vessel, C) subsequently polymerizing a hydrophobic monomer mixture containing hydroxyl groups in that vessel and D) subsequently polymerizing a hydrophilic monomer mixture containing hydroxyl and acid groups in that vessel. The present invention also relates to a process for the preparation of copolymers P following the procedure previously set forth and to coating compositions containing these copolymers P and one or more crosslinking agents.
摘要:
The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes contain terminal hydrazide groups and correspond to the formula wherein the terminal, modified hydrazide groups are present in an amount of 1 to 25% by weight [calculated as C(O)—NH—NH—C(O), MW 84], based on the weight of the polyurethanes, and wherein X represents OR′ or NHR′, R represents the residue obtained by removing the isocyanate groups from an NCO prepolymer, R′ represents a group which is inert to Isocyanate groups under the conditions used to form the polyurethane of in formula I, R″ represents a divalent, linear or branched aliphatic group containing 2 to 10 carbon atoms, provided that there are at least two carbons between the oxygen atoms, wherein the aliphatic group may optionally be substituted by heteroatoms to form ether or ester groups, m is 0 or 1 and n is 2 to 4.
摘要:
The present invention relates to aqueous polyurethane-urea dispersions having a resin solids content of at least 35 wt. % and a pH of at least 7.5 which are prepared bya) forming an isocyanate-terminated prepolymer by reacting a difunctional polyol having a molecular weight of 500 to 6000, a low molecular weight alcohol, a diisocyanate and/or triisocyanate and an isocyanate-reactive compound which has an acid group,b) neutralizing 65% to 95% of the acid groups prior to dispersing the prepolymer in water,c) dispersing the neutralized prepolymer in water,d) chain extending the isocyanate groups with water to form a polyurethane-urea, ande) after completion of the chain extending reaction adding additional neutralizing agent to provide a total amount of neutralizing agent that is sufficient to neutralize at least 115% of the acid groups of component D),wherein the polyurethane-urea contains 1.0 to 4.0%, based on resin solids, of the isolated urea groups. The present invention also relates to a process for the preparation of these polyurethane-urea dispersions and to their use in coating compositions.
摘要:
The present invention relates to aqueous polyurethane dispersions having a resin solids content of 20 to 60 wt %, a viscosity at 23.degree. C. of 10 to 20,000 mPa.s and a pH of 5.5 to 8.5, wherein the polyurethane has a weight average molecular weight of 5,000 to 500,000 and a urethane group content (calculated as --NHCO--O--, molecular weight=59) of 2.5 to 15 wt %, and is based on a polyisocyanate component containing 50 to 100 wt % of 1-methyl-2,4- and/or -2,6-diisocyanatocyclohexane.The present invention also relates to aqueous binder compositions containing these aqueous polyurethane dispersions and known crosslinking resins and to the use of the aqueous polyurethane dispersions and aqueous binder compositions as binders for glass fiber sizings.
摘要:
This invention relates to aqueous, crosslinkable binder dispersions which have a low solvent content and contain hydroxy-functional polyethers, hydroxy-functional acrylate copolymers and hydroxy- and carboxy-functional acrylate copolymers, to a process for the production of these binders, to one and two-component binder compositions containing these binders and to the use of the binder compositions in coating compositions.
摘要:
An aqueous dispersion of a polyester polyurethane which contains as essential building component 1-methyl-2,4- and/or -2,6-diisocyanatocyclohexane and its use as the binder for one- or two-component coating compositions, optionally in combination with cross-linking agent resins selected from optionally blocked polyisocyanates and/or aminoplast resins.
摘要:
The present invention relates to a process for the production of oxidatively crosslinkable, water-dilutable binders bya) forming a copolymer having intramolecular carboxylic anhydride groups by copolymerizing anhydride-functional compounds, other olefinically unsaturated monomers and 5 to 50% by weight, based on the weight of the olefinically unsaturated monomers used for the production of the copolymers a), of monomers which cannot be homopolymerized under the reaction conditions,b) subsequently reacting by ring-opening esterification at least 50% of the anhydride groups present in the copolymer with one or more unsaturated monohydric alcohols,c) reacting by ring-opening esterification up to 50% of the anhydride groups with monohydric saturated alcohols having a molecular weight of 32 to 200 either before, during or after step b),d) optionally reacting 1 to 70% of the carboxyl groups formed in steps b) and c) with organic epoxide compounds ande) neutralizing at least a portion of the carboxyl groups formed in steps b) and c).The present invention also relates to the binders obtained by this process and to their use in water-dilutable lacquers and coating compositions.