ABS molding compositions having improved processability
    91.
    发明授权
    ABS molding compositions having improved processability 失效
    ABS成型组合物具有改善的加工性能

    公开(公告)号:US06639000B2

    公开(公告)日:2003-10-28

    申请号:US09955890

    申请日:2001-09-18

    IPC分类号: C08K520

    摘要: An additive mixture containing a dibenzoate and either or both of a compound containing at least one structural unit and a compound containing at least one structural unit is disclosed. The additive combination enhances the processability of a thermoplastic molding composition that contains a (co)polymer of styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride and N-substituted maleimide and a graft copolymer.

    摘要翻译: 公开了含有二苯甲酸酯和含有至少一个结构单元的化合物和包含至少一种结构单元的化合物中的一种或两种的添加剂混合物。 添加剂组合增强了含有苯乙烯,甲基丙烯酸甲酯,丙烯腈,甲基丙烯腈,马来酸酐和N-取代的马来酰亚胺的共聚合物和接枝共聚物的热塑性模塑组合物的加工性能。

    Elastic-thermoplastic graft polymers prepared by multi-stage free radical polymerization

    公开(公告)号:US06569951B2

    公开(公告)日:2003-05-27

    申请号:US09967311

    申请日:2001-09-28

    IPC分类号: C08F27904

    摘要: An elastic-thermoplastic graft polymer prepared by a multi-stage free radical polymerization is described. The elastic-thermoplastic graft polymer is prepared by polymerizing (i) one or more monomers containing vinyl groups, and (ii) at least one molecular weight regulating compound, in the presence of (iii) at least one rubber in latex form. The ratio of monomers (M) to the molecular weight regulating compound (MWR) is altered throughout the various stages of the polymerization method. The M:MWR ratio is: from 50:1 to 400:1 in the first stage; from 100:1 to 800:1 in the second stage; and from 200:1 to 2000:1 in the third stage of the polymerization. In at least one further reaction stage of the polymerization, the monomers, in the absence of the molecular weight regulating compound, are polymerized in the presence of the rubber. This further reaction stage occurs before the first stage and/or after the third stage of the polymerization. The multi-stage polymerization is conducted such that: M:MWR (first stage)≦M:MWR (second stage)

    Polycarbonate/graft polymer moulding compositions with reduced deposit
formation
    95.
    发明授权
    Polycarbonate/graft polymer moulding compositions with reduced deposit formation 失效
    具有降低沉积物形成的聚碳酸酯/接枝聚合物模塑组合物

    公开(公告)号:US5994463A

    公开(公告)日:1999-11-30

    申请号:US047598

    申请日:1998-03-25

    摘要: Thermoplastic polycarbonate/graft polymer moulding compositions containingA) 5 to 95 parts by weight of an aromatic polycarbonate,B) 1 to 50 parts by weight of at least one thermoplastic homopolymer, copolymer or terpolymer of styrene, .alpha.-methylstyrene, acrylonitrile, N-substituted maleimide or mixtures thereof,C) 1 to 50 parts by weight of at least one graft polymer ofC.1) 5 to 90 parts by weight of styrene, .alpha.-methylstyrene, acrylonitrile, N-substituted maleimide or mixtures thereof, onC.2) 95 to 10 parts by weight of a rubber with a glass transition temperature .ltoreq.0.degree. C. andD) 1 to 25 parts by weight (per 100 parts by weight A+B+C) of at least one additive selected from flame retardants, lubricants, antistatic agent, mould release agents or mixtures thereof,characterised in that the component B) is produced by bulk, solution or suspension polymerisation and has an oligomer content .ltoreq.1 wt. %, component C) is produced by emulsion polymerisation and the total oligomer content of the moulding compositions is .ltoreq.0.6 wt. %.

    摘要翻译: 含有A)5-95重量份的芳族聚碳酸酯的热塑性聚碳酸酯/接枝聚合物模塑组合物,B)1至50重量份的至少一种苯乙烯,α-甲基苯乙烯,丙烯腈,N-甲基苯乙烯的共聚物或三元共聚物, 取代的马来酰亚胺或其混合物,C)1至50重量份的至少一种C.1的接枝聚合物)C至5重量份的苯乙烯,α-甲基苯乙烯,丙烯腈,N-取代的马来酰亚胺或其混合物,在C .2)95至10重量份的玻璃化转变温度为0℃的橡胶和D)1至25重量份(每100重量份A + B + C)至少一种添加剂 选自阻燃剂,润滑剂,抗静电剂,脱模剂或其混合物,其特征在于组分B)通过本体,溶液或悬浮液聚合制备,并且具有低聚物含量为1重量%。 %,组分C)通过乳液聚合制备,并且模塑组合物的总低聚物含量为0.6重量%。 %。

    Thermoplastic molding compositions
    99.
    发明授权
    Thermoplastic molding compositions 有权
    热塑性成型组合物

    公开(公告)号:US07186778B2

    公开(公告)日:2007-03-06

    申请号:US09997952

    申请日:2001-11-30

    IPC分类号: C08L51/04

    摘要: Thermoplastic molding compositions containing grafted polymers produced with different initiator systems are disclosed. The compositions are distinguished by a combination of good toughness and reduced opacity. As a result, appreciably smaller quantities of pigment are needed to color the molding composition.

    摘要翻译: 公开了含有用不同引发剂体系生产的接枝聚合物的热塑性模塑组合物。 组合物通过良好的韧性和降低的不透明度的组合来区分。 结果,需要明显较少量的颜料来着色成型组合物。

    ABS moulding material with improved workability and a high lustre
    100.
    发明授权
    ABS moulding material with improved workability and a high lustre 失效
    ABS成型材料具有改善的加工性和高光泽

    公开(公告)号:US07074854B2

    公开(公告)日:2006-07-11

    申请号:US10204137

    申请日:2001-02-12

    IPC分类号: C08L51/04

    摘要: A Polymer compositions that features high degree of toughness, very good processability and extremely high gloss is disclosed. The composition contains (I) a graft rubber polymer obtained by emulsion polymerization of styrene and acrylonitrile in the presence of a mixture of (A) a butadiene polymer latex having a mean particle diameter d50≦250 nm, a particle size distribution width of 20 to 80 nm and a gel content of 30 to 95 wt. %, (B) a butadiene polymer latex with a mean particle diameter d50>250 to 350 nm, a particle size distribution width of 30 to 100 nm and gel content of 30 to 80 wt. %, and (C) a butadiene polymer latex (C) with a mean particle diameter d50>350 nm, a particle size distribution width of 40 to 150 nm, and a gel content of 50 to 95 wt. %. and (II) a rubber-free copolymer of styrene and acrylonitrile. At least one of (A), (B) and (C) is a product of seed polymerization.

    摘要翻译: 公开了具有高韧性,非常好的加工性和极高光泽度的聚合物组合物。 该组合物含有(I)通过苯乙烯和丙烯腈的乳液聚合得到的接枝橡胶聚合物,该混合物是(A)平均粒径d <50%= 250nm的丁二烯聚合物胶乳 ,粒径分布宽度为20〜80nm,凝胶含量为30〜95wt。 %,(B)平均粒径d <50> 250〜350nm,粒径分布宽度为30〜100nm,凝胶含量为30〜80重量%的丁二烯聚合物胶乳。 %,和(C)平均粒径d <50 <350纳米,粒度分布宽度为40〜150nm,凝胶含量为50〜95的丁二烯聚合物胶乳(C) 重量 %。 和(II)苯乙烯和丙烯腈的无橡胶共聚物。 (A),(B)和(C)中的至少一种是种子聚合的产物。