公开(公告)号：US20120103790A1

公开(公告)日：2012-05-03

申请号：US13378151

申请日：2010-06-09

申请人： Matthias Krull ,  Roman Morschhaeuser

发明人： Matthias Krull ,  Roman Morschhaeuser

IPC分类号： C07C51/00

CPC分类号： C07C67/08 ,  B01J19/126 ,  B01J2219/1215 ,  B01J2219/1227 ,  B01J2219/1272 ,  B01J2219/1281 ,  B01J2219/1284 ,  B01J2219/129 ,  H05B6/701 ,  H05B6/806 ,  C07C69/68 ,  C07C69/54 ,  C07C69/14 ,  C07C69/24

摘要： The invention relates to a continuous method for producing aliphatic carbonic acid esters by reacting at least one aliphatic carboxylic acid of formula (I) R1—COOH (I), wherein R1 represents hydrogen or an optionally substituted aliphatic hydrocarbon group with 1 to 50 carbon atoms, with at least one alcohol of formula (II) R2—(OH)n (II), wherein R2 represents an optionally substituted hydrocarbon group with 1 to 100 C atoms and n is an integer from 1 to 10, in the presence of at least one transesterification catalyst in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form the ester.

摘要翻译： 本发明涉及通过使至少一种式（I）R1-COOH（I）的脂族羧酸（其中R 1表示氢或任选取代的脂族烃基与1至50个碳原子）反应制备脂族碳酸酯的连续方法 与（II）R 2 - （OH）n（II）的至少一种醇，其中R 2表示任选取代的具有1至100个C原子的烃基，n为1至10的整数，在 在微波照射下，反应管中的至少一个酯交换催化剂的纵轴在微波微波施加器的微波的传播方向上延伸以形成酯。

公开(公告)号：US20120088918A1

公开(公告)日：2012-04-12

申请号：US13378167

申请日：2010-06-09

申请人： Matthias Krull ,  Roman Morschhaeuser

发明人： Matthias Krull ,  Roman Morschhaeuser

IPC分类号： C07D213/803 ,  C07C67/08

CPC分类号： B01J19/126 ,  B01J2219/1215 ,  B01J2219/1227 ,  B01J2219/1272 ,  B01J2219/1281 ,  B01J2219/1284 ,  C07C67/08 ,  C07D213/79 ,  H05B6/701 ,  H05B6/806 ,  C07C69/78 ,  C07C69/82 ,  C07C69/76 ,  C07C69/84

摘要： The invention relates to a continuous method for producing aromatic carboxylic acid esters by reacting at least one aromatic carboxylic acid of formula (I) Ar—COOH (I), wherein Ar represents an optionally substituted aryl group with 5 to 50 atoms, with at least one alcohol of formula (II) R2—(OH)n (II), wherein R2 represents an optionally substituted hydrocarbon group with 1 to 100 C atoms and n is an integer from 1 to 10, in the presence of at least one transesterification catalyst in a reaction tube, the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form the ester.

摘要翻译： 本发明涉及通过使至少一种式（I）Ar-COOH（I）的芳族羧酸（其中Ar表示任选取代的具有5至50个原子的芳基）与芳族羧酸酯反应生成芳族羧酸酯的方法， 一种式（II）的醇R 2 - （OH）n（II），其中R 2表示任选取代的具有1至100个C原子的烃基，n是1至10的整数，在至少一种酯交换催化剂 在反应管中，其纵轴在微波辐射下在微波微波施加器的微波的传播方向上延伸以形成酯。

公开(公告)号：US08067635B2

公开(公告)日：2011-11-29

申请号：US12444655

申请日：2007-10-05

申请人： Matthias Krull ,  Roman Morschhaeuser ,  Alexander Lerch ,  Helmut Ritter ,  Sarah Schmitz

发明人： Matthias Krull ,  Roman Morschhaeuser ,  Alexander Lerch ,  Helmut Ritter ,  Sarah Schmitz

IPC分类号： C07C231/02

CPC分类号： C07C231/02 ,  Y02P20/582 ,  C07C233/65

摘要： The invention relates to a method for producing tertiary amides of alkylphenyl carboxylic acids by reacting at least one secondary amine with at least one alkylphenyl carboxylic acid to form an ammonium salt, said ammonium salt being subsequently converted into the tertiary amide by means of microwave radiation.

摘要翻译： 本发明涉及通过使至少一种仲胺与至少一种烷基苯基羧酸反应形成铵盐来生产烷基苯基羧酸叔酰胺的方法，所述铵盐随后通过微波辐射转化成叔酰胺。

公开(公告)号：US20110089021A1

公开(公告)日：2011-04-21

申请号：US12935720

申请日：2009-03-18

申请人： Matthias Krull ,  Roman Morschhaeuser

发明人： Matthias Krull ,  Roman Morschhaeuser

IPC分类号： C07C51/06

CPC分类号： C07C231/02 ,  B01J19/126 ,  C07C233/05 ,  C07C233/65 ,  C07C235/06 ,  C07C235/34

摘要： The invention relates to a method for producing carboxylic acid amides, according to which at least one carboxylic acid of formula (I) R3—COON   (I) wherein R3 is hydrogen or an optionally substituted hydrocarbon radical comprising between 1 and 50 carbon atoms, is reacted with at least one amine of formula (II) HNR1R2   (II) wherein R1 and R2 are independently hydrogen or an optionally substituted hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is reacted in the presence of superheated water, under microwave irradiation, to form a carboxylic acid amide.

摘要翻译： 本发明涉及一种制备羧酸酰胺的方法，根据该方法，至少一种式（I）的R 3 -COON（I）羧酸或其中R 3为氢或含有1至50个碳原子的任选取代的烃基的羧酸是 与至少一种式（II）的胺HNR1R2（II）反应，其中R 1和R 2独立地是氢或包含1至100个C原子的任选取代的烃基，以形成铵盐，并且所述铵盐在 在微波照射下存在过热水，形成羧酸酰胺。

公开(公告)号：US20110089019A1

公开(公告)日：2011-04-21

申请号：US12935661

申请日：2009-03-18

申请人： Matthias Krull ,  Roman Morschhaeuser ,  Michael Seebach ,  Ralf Bierbaum ,  Christoph Kayser

发明人： Matthias Krull ,  Roman Morschhaeuser ,  Michael Seebach ,  Ralf Bierbaum ,  Christoph Kayser

IPC分类号： C07C231/00 ,  C07B45/00 ,  C07C233/65

CPC分类号： C07C231/02 ,  B01J19/126 ,  C07D213/82 ,  C07C233/65 ,  C07C235/60

摘要： The invention relates to a continuous method for producing amides of aromatic carboxylic acids, according to which at least one aromatic carboxylic acid of formula (I) Ar—COON   (I) wherein Ar is an optionally substituted aryl radical comprising between 5 and 50 atoms, is reacted with at least one amine of formula (II) HNR1R2   (II) wherein R1 and R2 are independently hydrogen or a hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is then reacted to form a carboxylic acid amide, under microwave irradiation in a reaction pipe, the longitudinal axis of the pipe being oriented in the direction of propagation of the microwaves of a monomode microwave applicator.

摘要翻译： 本发明涉及一种生产芳族羧酸酰胺的连续方法，根据该方法，至少一种式（I）Ar-COON（I）的芳族羧酸，其中Ar是包含5至50个原子的任选取代的芳基， 与式（II）HNR1R2（II）的至少一种胺反应，其中R 1和R 2独立地为氢或包含1至100个C原子的烃基，以形成铵盐，然后所述铵盐反应形成 羧酸酰胺，在反应管中的微波照射下，管的纵向轴线沿着单模微波施加器的微波的传播方向取向。

公开(公告)号：US20100010244A1

公开(公告)日：2010-01-14

申请号：US12444669

申请日：2007-10-05

申请人： Matthias Krull ,  Roman Morschhaeuser ,  Peter Klug ,  Alexander Lerch ,  Christoph Kayser ,  Helmut Ritter ,  Sarah Schmitz

发明人： Matthias Krull ,  Roman Morschhaeuser ,  Peter Klug ,  Alexander Lerch ,  Christoph Kayser ,  Helmut Ritter ,  Sarah Schmitz

IPC分类号： C07C233/18 ,  C07C231/02

CPC分类号： C07C231/02 ,  C07C233/18

摘要： The invention relates to a method for producing fatty acid alkanol amides by reacting at least one amine that contains at least one primary or secondary amino group and at least one hydroxyl group with at least one fatty acid to form an ammonium salt, said ammonium salt being subsequently converted into the alkanol amide by means of microwave radiation.

摘要翻译： 本发明涉及一种生产脂肪酸链烷醇酰胺的方法，该方法是使至少一种含有至少一个伯或仲氨基和至少一个羟基的胺与至少一种脂肪酸反应形成铵盐，所述铵盐为 随后通过微波辐射转化成链烷醇酰胺。

公开(公告)号：US07377949B2

公开(公告)日：2008-05-27

申请号：US10495559

申请日：2002-11-02

申请人： Matthias Krull ,  Martina Hess

发明人： Matthias Krull ,  Martina Hess

IPC分类号： C10L1/18

CPC分类号： C10L1/192 ,  C10L1/143 ,  C10L1/1616 ,  C10L1/191 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364

摘要： An additive for middle distillates with a maximum sulfur content of 0.05 percent by weight, comprising at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).

摘要翻译： 包含最大硫含量为0.05重量％的中间馏分的添加剂，包含至少一种具有至少3个OH基团（A）和至少一种烷基酚醛树脂（C）的烷氧基​​化多元醇的脂肪酸酯。

公开(公告)号：US20060254128A1

公开(公告)日：2006-11-16

申请号：US10484971

申请日：2002-07-09

申请人： Matthias Krull ,  Markus Kupetz

发明人： Matthias Krull ,  Markus Kupetz

IPC分类号： C10L1/18

CPC分类号： C10L10/08 ,  C10L1/191

摘要： The invention relates to an additive for improving the lubrication capacity of fuel oils with a maximum sulphur content of 0.035 wt. %. Said additive contains at least one ester of a bivalent or polyvalent alcohol and a mixture of unsaturated and optionally saturated fatty acids, whose carbon chain lengths are between 8 and 30 carbon atoms, the aforementioned esters having an OH value less than 200 mg KOH/g ester and an iodine value greater than 100 g I/100 g ester. The invention also relates to fuel oils with a maximum sulphur content of 0.035 wt. %, which contain the inventive additives. The novel additives exhibit less tendency to emulsify than the additives in prior art.

摘要翻译： 本发明涉及一种用于改善最大硫含量为0.035重量％的燃料油的润滑能力的添加剂。 ％。 所述添加剂含有至少一种二价或多价醇的酯和碳链长度为8至30个碳原子的不饱和脂肪酸和任选的饱和脂肪酸的混合物，上述酯的OH值小于200mg KOH / g 酯，碘值大于100g I / 100g酯。 本发明还涉及最大硫含量为0.035重量％的燃料油。 ％，其含有本发明的添加剂。 与现有技术中的添加剂相比，新型添加剂显示出较少的乳化倾向。

公开(公告)号：US20060162241A1

公开(公告)日：2006-07-27

申请号：US11391643

申请日：2006-03-28

申请人： Matthias Krull

发明人： Matthias Krull

IPC分类号： C10L1/18

CPC分类号： C10L10/08 ,  C10L1/143 ,  C10L1/1835 ,  C10L1/19 ,  C10L1/1905 ,  C10L1/191 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364 ,  C10M169/04 ,  C10M169/044 ,  C10M2205/022 ,  C10M2207/282 ,  C10M2209/101 ,  C10N2220/024 ,  C10N2220/026 ,  C10N2230/06 ,  C10N2230/10 ,  C10N2230/43

摘要： An additive for improving the lubricity of fuel oils having a maximum sulfur content of 0.035% by weight, comprising A) at least one partial ester composed of a di- or polyhydric alcohol and unsaturated and optionally also saturated fatty acids whose carbon chain lengths are between 8 and 30 carbon atoms, at least 60% of the fatty acid radicals containing at least one double bond, and B) at least one alkylphenol-aldehyde resin, obtainable by the condensation of (i) at least one alkylphenol having at least one C6-C24-alkyl or C6-C24-alkenyl radical and (ii) at least one aldehyde or ketone, to a degree of condensation of between 2 and 50 alkylphenol units.

摘要翻译： 一种用于改善最大硫含量为0.035重量％的燃料油的润滑性的添加剂，其包含A）至少一种由二元或多元醇组成的偏酯和不饱和和任选的饱和脂肪酸，其碳链长度在 8个和30个碳原子，至少60％的含有至少一个双键的脂肪酸基团，和B）至少一种烷基酚醛树脂，可通过（i）至少一种具有至少一个C C 2 -C 24 - 烷基或C 6 -C 24 - 链烯基，和（ii）至少一个 醛或酮，至2至50个烷基酚单元的缩合度。

公开(公告)号：US20050126070A1

公开(公告)日：2005-06-16

申请号：US10972577

申请日：2004-10-25

申请人： Matthias Krull

发明人： Matthias Krull

IPC分类号： C10L1/192 ,  C10L1/02 ,  C10L1/04 ,  C10L1/14 ,  C10L1/18 ,  C10L1/195 ,  C10L1/196 ,  C10L1/197 ,  C10L1/22 ,  C10L1/224 ,  C10L1/236 ,  C10L5/00

CPC分类号： C10L1/1955 ,  C10L1/143 ,  C10L1/146 ,  C10L1/19 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364

摘要： The invention provides a fuel oil composition F) comprising F1) a fuel oil of mineral origin and F2) a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units having C8-C16-alkyl radicals, the structural units being selected from C8-C16-alkyl (meth)acrylates, C8-C16-alkyl vinyl esters, C8-C16-alkyl vinyl ethers, C8-C16-alkyl(meth)acrylamides, C8-C16-alkyl allyl ethers and C8-C16-diketenes, where the sum R R = m 1 · ∑ i ⁢ w 1 ⁢ i · n 1 ⁢ i + m 2 · ∑ j ⁢ w 2 ⁢ j · n 2 ⁢ j + … + m g · ∑ p ⁢ w gp · n gp of the molar averages of the carbon chain length distributions in the alkyl radicals of the monomers B) is from 11.0 to 14.0, where m1, m2, . . . mg are the molar fractions of the abovementioned monomers B) in the polymer, and the sum of the molar fractions m1 to mg=1, w1i, w1j. . . w2i, w2j. . . wgp are the proportions by weight of the individual chain lengths i, j, p of the alkyl radicals of the different monomers B) 1 to g, and n1i, n1j. . . n2i, n2j. . . ngp are the chain lengths of the alkyl radicals i, j, . . . p of the monomers B) 1 to g.