Abstract:
A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of the first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.
Abstract:
An advanced control method is disclosed for the polymerization of an alpha-olefin in a substantially horizontal, quench-cooled, stirred bed reactor.
Abstract:
The present invention relates to a fluidized bed reactor in which olefins are polymerized or copolymerized in a bed formed by particles being polymerized and fluidized with the aid of a circulating gas. In the reactor, a circulating gas is fed from a gas space above the fluidized bed into the lower part of the reactor. The lower part of the reactor includes an annular space having an defined by an upwards tapering rotating conical surface and an outer wall defined by a downwards tapering rotating conical surface.
Abstract:
A method and apparatus for exposing particles to a fluid including the steps of adding fluid and particles to a container having impeller means therein, generating a current with the impeller so as to subject the particles to centrifugal and convective forces resulting in the formation of a well-defined and localized fluidized bed of particles, and maintaining the existence of the current through the fluidized bed so that the particles are thereby exposed to the fluid. The fluidized bed is located in a region removed from the impeller when the particles are more dense than the fluid, and the fluidized bed is located in a region near the impeller when the particles are less dense than the fluid. A method of exposing a first fluid to a second fluid, the second fluid being either a gas or a liquid immiscible in the first fluid is also disclosed. The method includes the steps of adding the first and second fluids to a container having impeller means therein, generating with the impeller a current in the first fluid which subjects the second fluid to centrifugal and convective forces resulting in the formation of a well defined and localized bed of a dispersed phase of the second fluid remaining in a region near the impeller, and maintaining the existence of the current through the region so that the dispersed phase in the fluidized bed is exposed to the first fluid.
Abstract:
Apparatus for treating particles while the particles are suspending in a circulating stream of air or other fluid. The apparatus causes particles to rotate around a vertical axis in confined circular paths of travel generally lying in a horizontal plane.
Abstract:
The process and the system are used for carrying out the quench-cooled, vapor-phase polymerization of olefin monomer in a horizontally disposed reactor vessel which comprises contacting olefin monomer, or a mixture of olefin monomers, with a polymerization catalyst system in the presence of hydrogen in the reactor vessel to form a polymer product. The improvement comprises introducing a titanium-containing catalyst component of the catalyst system into the top side of the reactor vessel at a point adjacent to the upstream end of the reactor vessel and introducing a cocatalyst plus modifer component of the catalyst system into the top side of the reactor vessel at a distance, downstream of the point of introduction of the titanium-containing catalyst component, which is equal to 25% of the inside diameter of the reactor vessel.
Abstract:
A horizontal agitation bed type vapor phase polymerization apparatus for olefins provided on its lower curved surface with plural cells each having an opening facing on the polymerization reaction system and further having small holes formed in its side wall portion for feeding a starting olefin gas.
Abstract:
A horizontal agitation bed type vapor phase polymerization apparatus for olefins, having a lower curved surface constructed by a perforated plate so as to allow a olefin gas to be fed uniformly throughout the reaction system through the said perforated plate.
Abstract:
A rotating fluidized bed heat exchanger particularly adaptable as a heat exchange unit in the recuperator section of conventional gas turbine engines comprising an annular fluidized bed, defined by inner and outer spaced apart coaxial cylindrical, perforated walls, which rotates about the longitudinal axis of the cylinders. The bed is comprised of pulverulent inert particulate material and includes fluid-containing heat exchange tubes passing substantially longitudinally therethrough. Hot gases, such as turbine exhaust gases, enter the bed through the outer perforated wall, heat and fluidize the bed particles, heat the fluid, usually compressed air, in the tubes, and exit the bed through the inner perforated wall. The heat exchange tubes direct the fluid flowing therein from an inlet adjacent the inner perforated wall to an outlet adjacent the outer perforated wall such that the fluid flows substantially countercurrently to the hot fluidizing gas. In a preferred embodiment, the heat exchange tubes comprise an inlet tube extending longitudinally adjacent the inner perforated wall, an outlet tube extending longitudinally adjacent the outer perforated wall and a plurality of tubes interconnecting the inlet and outlet tubes.
Abstract:
A method for preheating a rotatable fluidizable bed (106) comprises rotating the bed chamber (112) slowly to cause the particles (114) to slowly tumble and mix. During tumbling, one or more burners (150, 160) extending into the chamber (112), heat the particles (114) until the desired operating or ignition temperature is reached. Temperature sensors (170) in thermal communication with the bed particles (114) sense the temperature and provide either an indication thereof or an initiating signal which, in the case of a rotating fluidized bed combustor (10), terminates preheating, accelerates the bed chamber (112) rotation to normal combustor (10) operating speed and/or introduces fluidizing air and/or fuel flow through the bed chamber (112).