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796 条记录 (耗时 0.02 秒)

    Preparation of coated catalysts
    93.
    发明授权
    Preparation of coated catalysts 失效
    涂层催化剂的制备

    公开(公告)号：US4305843A

    公开(公告)日：1981-12-15

    申请号：US126384

    申请日：1980-03-03

    申请人： Richard Krabetz ,  Heinz Engelbach ,  Peter Palm ,  Heinrich Spahn ,  Walter Herrmann

    发明人： Richard Krabetz ,  Heinz Engelbach ,  Peter Palm ,  Heinrich Spahn ,  Walter Herrmann

    IPC分类号： B01J23/00 ,  B01J23/88 ,  B01J23/887 ,  B01J35/08 ,  B01J37/02 ,  B01J23/31 ,  B01J23/22 ,  B01J23/85

    CPC分类号： B01J23/002 ,  B01J23/88 ,  B01J35/08 ,  B01J37/0221 ,  B01J37/0223 ,  B01J23/8876 ,  B01J2523/00

    摘要： A coated catalyst comprising (a) an inert carrier having particles of not less than 100 .mu.m diameter and a surface area of up to 20 m.sup.2 /g and (b) a coating which contains the catalytic material and adheres firmly to the outer surface and to the edge zone, near the surface, of the carrier particles, can be prepared by applying the catalytic material as a 10-70% strength suspension in water to the agitated carrier particles, which are at below 70.degree. C., if the suspension is sprayed, at a constant rate of from 0.01 to 2.0 kg of active material/hour/liter of carrier onto the carrier particles, while at the same time uniformly passing from 0.1 to 12 m.sup.3 (S.T.P.)/hour/liter of carrier of an inert gas at from 20.degree. to 300.degree. C. over the carrier particles, under conditions such that the water only evaporates incompletely but the water content of the resulting coating is less than the maximum degree of saturation of the catalytic material.

    摘要翻译： 一种涂覆的催化剂，包括（a）具有不小于100μm直径的颗粒和至多20m 2 / g的表面积的惰性载体，和（b）包含催化材料并牢固地粘合到外表面的涂层， 到载体颗粒表面附近的边缘区域，可以通过将催化材料作为10-70％强度的悬浮液施加到水中的搅拌的载体颗粒（其在低于70℃）下制备，如果悬浮液 以0.01〜2.0kg的活性物质/小时/升的载体的恒定速率喷涂到载体颗粒上，同时将0.1〜12m 3（STP）/小时/升的载体 在载体颗粒上的20至300℃的惰性气体，使得水仅不完全蒸发，但所得涂层的水含量小于催化材料的最大饱和度。

    Upgrading of aromatic liquids
    94.
    发明授权
    Upgrading of aromatic liquids 失效
    芳香液体升级

    公开(公告)号：US4267033A

    公开(公告)日：1981-05-12

    申请号：US86876

    申请日：1979-10-22

    申请人： Roland H. Heck ,  Stephen M. Oleck ,  Stuart S. Shih ,  Robert C. Wilson

    发明人： Roland H. Heck ,  Stephen M. Oleck ,  Stuart S. Shih ,  Robert C. Wilson

    IPC分类号： B01J23/85 ,  B01J35/10 ,  C10G45/08 ,  C10G45/04

    CPC分类号： C10G45/08 ,  B01J23/85 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061

    摘要： Desulfurization, denitrogenation, deoxygenation and CCR reduction of highly aromatic petroleum and coal derived liquids are conducted with hydrogen and with a refractory base catalyst incorporating at least one Group VIA metal and at least one Group VIII metal. The catalyst has a surface area of between about 100 and 300 m.sup.2 /g and a total pore volume of between about 0.3 and 1.0 cc/g and is further characterized as follows:______________________________________ Pore Volume Distribution, Volume % in Pores of ______________________________________ 0-150 Angstroms diameter 20-40 150-200 Angstroms diameter 40-60 200+ Angstroms diameter 10-30 ______________________________________

    摘要翻译： 使用氢气和掺入至少一种VIA族金属和至少一种第Ⅷ族金属的耐火碱催化剂进行高度芳香族石油和煤衍生液体的脱硫，脱氮，脱氧和降低CCR。 催化剂的表面积为约100至300m2 / g，总孔体积为约0.3至1.0cc / g，并进一步表征如下： - 孔体积分布， - 0- 150埃直径20-40-150-200埃直径40-60 -200+埃直径10-30 -

    Phosphorous-containing catalyst and method for preparing and using same
    95.
    发明授权
    Phosphorous-containing catalyst and method for preparing and using same 失效
    含磷催化剂及其制备和使用方法

    公开(公告)号：US4202798A

    公开(公告)日：1980-05-13

    申请号：US955661

    申请日：1978-10-30

    申请人： Marvin F. L. Johnson ,  Henry Erickson

    发明人： Marvin F. L. Johnson ,  Henry Erickson

    IPC分类号： B01J23/85 ,  B01J27/18 ,  C10G45/04 ,  C10G45/10

    CPC分类号： B01J27/18 ,  B01J23/85 ,  C10G45/04 ,  C10G45/10

    摘要： An improved method for preparing a hydrocarbon hydrotreating catalyst containing a major amount of alumina and a minor amount of at least one Group VIB or Group VIII metal comprising:(1) contacting an aqueous mixture of hydrous alumina with at least one phosphorus-containing compound in an amount sufficient to increase the hydrocarbon hydrotreating activity of the final catalyst and forming a phosphorus-containing hydrous alumina;(2) calcining the phosphorus-containing hydrous alumina and forming a calcined alumina;(3) contacting the calcined alumina with at least one metal-containing compound and forming a metal-containing material, the metal being selected from the group consisting of Group VIB metal, Group VIII metal and mixtures thereof; and(4) calcining the metal-containing material and forming a catalyst having increased hydrocarbon hydrotreating activity.Improved hydrocarbon hydrotreating processes and catalysts are also disclosed.

    摘要翻译： 一种用于制备含有主要量的氧化铝和少量至少一种VIB族或VIII族金属的烃加氢处理催化剂的改进方法，包括：（1）将含水氧化铝的含水混合物与至少一种含磷化合物接触 足以提高最终催化剂的烃加氢处理活性并形成含磷水合氧化铝的量; （2）煅烧含磷水合氧化铝并形成煅烧氧化铝; （3）使煅烧的氧化铝与至少一种含金属的化合物接触并形成含金属的材料，所述金属选自第VIB族金属，第Ⅷ族金属及其混合物; 和（4）煅烧含金属材料并形成具有提高的烃加氢精制活性的催化剂。 还公开了改进的烃加氢处理方法和催化剂。

    Process for the production of 1,4-butanediol and tetrahydrofuran
    97.
    发明授权
    Process for the production of 1,4-butanediol and tetrahydrofuran 失效
    生产1,4-丁二醇和四氢呋喃的方法

    公开(公告)号：US4155919A

    公开(公告)日：1979-05-22

    申请号：US853566

    申请日：1977-11-21

    申请人： Jean Ramioulle ,  Willy Couteau

    发明人： Jean Ramioulle ,  Willy Couteau

    IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J23/85 ,  C07B61/00 ,  C07C27/00 ,  C07C29/132 ,  C07C29/136 ,  C07C29/149 ,  C07C29/17 ,  C07C31/20 ,  C07C67/00 ,  C07D307/08 ,  C07D315/00 ,  C07C27/04

    CPC分类号： C07D315/00 ,  B01J23/85 ,  B01J23/883 ,  C07C29/177 ,  C07D307/08

    摘要： Process for the catalytic hydrogenolysis of maleic anhydride to give 1,4-butanediol and tetrahydrofuran in a single-stage operation by means of hydrogen under heat and pressure, in the presence of a suspension of a reduced solid catalyst, which contains as catalytically active elements Ni in association with Mo and/or W and optionally with Zr and/or Nb, having the following essential characteristics: (I) double oxidizing treatment of the solid catalyst in two stages before its reduction, and (II) conducting the hydrogenolysis of maleic anhydride at a temperature of from 170.degree. to 215.degree. C. under a hydrogen pressure below about 200 bars, in a reaction medium which contains gamma-butyrolactone, for a time such that the amount of gamma-butyrolactone in the final reaction medium is substantially equal to that present in the initial reaction medium.

    摘要翻译： 在含有作为催化活性元素的还原固体催化剂的悬浮液存在下，通过氢气在加热和压力下，单步骤操作中马来酸酐的催化氢解得到1,4-丁二醇和四氢呋喃的方法 与Mo和/或W以及任选地具有Zr和/或Nb相关的Ni，其具有以下基本特征：（I）在还原之前两个阶段对固体催化剂进行双重氧化处理，和（II）进行马来酸氢解 在含有γ-丁内酯的反应介质中，在170-215℃的温度下，在约200巴下的氢气压力下，使得最终反应介质中的γ-丁内酯的量基本上达到 与初始反应介质中存在的相同。