Abstract:
Gold-carbonyl chloride and phosgene are prepared by reacting gold trichloride with carbon monoxide through a process wherein carbon monoxide is bubbled through a solution of gold trichloride in thionyl chloride at room temperature and atmospheric pressure.
Abstract:
A method is disclosed for carrying out enzymic reactions in all cases in which the substrates of the enzymic catalyst are waterinsoluble, which makes the reaction difficult to complete. The improvement consists in using a solvent for the substrate which is water-immiscible. The solvent in question is selected from among the esters of carboxylic acids of from C2 to C10, the alkyl ethers, the alcohols of from C4 to C20, aliphatic, aromatic and cycloaliphatic hydrocarbons and halogen-substituted hydrocarbons.
Abstract:
The present invention relates to the production of cyclic thiocarbonates by reacting a thioglycol or a hydroxydisulphide with carbon oxide in presence of transition metals or transition metal compounds. The thiocarbonates are very important products from a practical point of view since some of them are precursors of the alkylene sulphides or episulphides which are widely employed in the production of polymers with peculiar properties.
Abstract:
Aluminum chlorohydroxide represented by the formula: Al2(OH)x Cly, wherein x and y range from 1 to 3.5 and 5 to 2.5, respectively, is produced by reacting aluminum oxide or hydroxide with an amount of hydrochloric acid which is (1/2.5) to (1/4) of the stoichiometric amount for obtaining aluminum trichloride, at a temperature in the range from 100*C to 160*C, and at a pressure in the range from 0.1 kg/cm2 to 4 kg/cm2 for a period of from 2 to 10 hours.
Abstract translation:由式Al 2(OH)x Cly表示的氯代氢氧化铝,其中x和y分别为1至3.5和5至2.5的范围是通过使氧化铝或氢氧化物与一定量的盐酸反应制得的,该盐酸为(1 / 2.5 )至化学计量量的(1/4),以获得三氯化铝,在100℃至160℃的温度下,在0.1kg / cm 2至4kg / cm 2的压力范围内,对于 时间为2至10小时。
Abstract:
Vulcanizable olefin tetrapolymers are described which are comprised of ethylene, an alpha-olefin having at least three carbon atoms, at least one conventional terpolymer such as endoand exo-dicyclopentadiene, and a minor amount of a polycyclic polyene represented by the formula A-(CH2)n-B, wherein A is a radical consisting of or containing at least one cyclohexane ring with or without an endomethylene bridge, B is a cyclodiene radical and n is a number ranging from 0 to 5.
Abstract:
This invention provides a new catalyst and process for the oxidation and ammoxidation of olefins. The catalysts are of the formula: TeTin Mop Pq Xm Or WHEREIN X is an element selected from groups IB, IIB, IIIA, IIIB, IVB, VIIB and VIII of the Periodic Table of Elements.