公开(公告)号：US06875529B1

公开(公告)日：2005-04-05

申请号：US10748521

申请日：2003-12-30

申请人： Irene Spitsberg ,  Brett Allen Boutwell ,  Robert William Bruce

发明人： Irene Spitsberg ,  Brett Allen Boutwell ,  Robert William Bruce

IPC分类号： C04B35/486 ,  C23C14/08 ,  C23C28/00 ,  C23C28/04 ,  C23C30/00 ,  F01D5/28 ,  B32B15/04 ,  C23C4/10 ,  C23C16/06 ,  F03B3/12

CPC分类号： C04B35/486 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3286 ,  C04B2235/761 ,  C04B2235/77 ,  C23C14/083 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/3455 ,  C23C28/36 ,  F01D5/288 ,  F05D2230/90 ,  F05D2300/5024 ,  F05D2300/611 ,  Y10T428/12611 ,  Y10T428/249953 ,  Y10T428/265

摘要： A reduced thermal conductivity thermal barrier coating having improved impact and erosion resistance for an underlying metal substrate of articles that operate at, or are exposed to, high temperatures. This coating comprises an inner layer nearest to the underlying metal substrate comprising a ceramic thermal barrier coating material, as well as a protective outer layer adjacent to and overlaying the inner layer and having an exposed surface. The outer layer has a thickness up to about 5 mils (127 microns) sufficient to impart impact and erosion resistance to the thermal barrier coating, and comprises a zirconia-containing ceramic composition having a c/a ratio of the zirconia lattice in the range of from about 1.011 to about 1.016 and stabilized in the tetragonal phase by a stabilizing amount of a stabilizing metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india, ytterbia and mixtures thereof. This coating can be used to provide a thermally protected article having a metal substrate and optionally a bond coated layer adjacent to and overlaying the metal substrate. The thermal barrier coating can be prepared by forming the inner layer comprising the ceramic thermal barrier coating material, followed by forming on the inner layer the protective outer layer.

摘要翻译： 对于在高温下操作或暴露于高温的制品的底层金属基底，具有改善的耐冲击性和耐侵蚀性的降低的热导率热障涂层。 该涂层包括最靠近下面的金属基底的内层，其包含陶瓷热障涂层材料，以及与内层相邻并覆盖内层并具有暴露表面的保护外层。 外层具有足以赋予热障涂层抗冲击和耐腐蚀性的至多约5密耳（127微米）的厚度，并且包含含氧化锆的陶瓷组合物，其中氧化锆晶格的ac / a比范围为 约1.011至约1.016，并通过稳定量的选自氧化钇，氧化钙，二氧化铈，钪，氧化镁，印度，镱的稳定金属氧化物及其混合物在四方相中稳定化。 该涂层可用于提供具有金属基底和任选的与金属基底相邻并覆盖金属基底的粘结涂层的热保护制品。 可以通过形成包含陶瓷热障涂层材料的内层，然后在内层上形成保护外层来制备热障涂层。

公开(公告)号：US06787195B2

公开(公告)日：2004-09-07

申请号：US10248635

申请日：2003-02-03

申请人： Hongyu Wang ,  Yuk-Chiu Lau ,  Irene Spitsberg ,  Arnold T. Henry

发明人： Hongyu Wang ,  Yuk-Chiu Lau ,  Irene Spitsberg ,  Arnold T. Henry

IPC分类号： C23C404

CPC分类号： C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  C23C4/02 ,  C23C4/11 ,  C04B41/4527 ,  C04B41/5037 ,  C04B41/5024 ,  C04B35/565 ,  C04B35/584

摘要： A process of depositing a coating system suitable for use as an environmental barrier coating on various substrate materials, particularly those containing silicon and intended for high temperature applications such as the hostile thermal environment of a gas turbine engine. The process comprises depositing a first coating layer containing mullite, and preferably a second coating layer of an alkaline earth aluminosilicate, such as barium-strontium-aluminosilicate (BSAS), by thermal spraying while maintaining the substrate at a temperature of 800° C. or less, preferably 500° C. or less, by which a substantially crack-free coating system is produced with desirable mechanical integrity.

摘要翻译： 一种沉积涂覆系统的方法，该涂覆系统适合用作各种基材上的环境屏障涂层，特别是含有硅并用于高温应用的那些涂层系统，例如燃气涡轮发动机的恶劣的热环境。 该方法包括通过热喷涂沉积包含莫来石的第一涂层，优选地是碱土金属硅铝酸盐的第二涂层，例如钡 - 锶 - 硅酸铝（BSAS），同时将基材保持在800℃的温度，或 较少，优选500℃或更低，由此产生具有期望的机械完整性的基本上无裂纹的涂层体系。

公开(公告)号：US06706325B2

公开(公告)日：2004-03-16

申请号：US09944909

申请日：2001-08-31

申请人： Irene Spitsberg ,  Robert William Bruce

发明人： Irene Spitsberg ,  Robert William Bruce

IPC分类号： C23C1408

CPC分类号： C23C28/321 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12944

摘要： An article protected by a thermal barrier coating system is fabricated by providing an article substrate having a substrate surface, thereafter depositing a bond coat on the substrate surface, the bond coat having a bond coat surface, and thereafter processing the bond coat to flatten the bond coat surface. A thermal barrier coating is deposited overlying the bond coat surface. The thermal barrier coating is yttria-stabilized zirconia having a yttria content of from about 3 percent by weight to about 5 percent by weight of the yttria-stabilized zirconia.

摘要翻译： 通过提供具有基材表面的制品基材，然后在基材表面上沉积粘合涂层，粘合涂层具有粘合涂层表面，然后加工粘合涂层使粘合剂平坦化，制造由热障涂层系统保护的物品 外套表面。 覆盖在粘结涂层表面上的热障涂层被沉积。 热障涂层是氧化钇稳定的氧化锆，其氧化钇含量为氧化钇稳定的氧化锆的约3重量％至约5重量％。

公开(公告)号：US06607852B2

公开(公告)日：2003-08-19

申请号：US09894249

申请日：2001-06-27

申请人： Irene Spitsberg ,  Hongyu Wang ,  Bangalore Aswatha Nagaraj

发明人： Irene Spitsberg ,  Hongyu Wang ,  Bangalore Aswatha Nagaraj

IPC分类号： B32B904

CPC分类号： C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  Y10T428/24942 ,  Y10T428/263 ,  Y10T428/265 ,  C04B41/5035 ,  C04B41/5037 ,  C04B41/5024 ,  C04B41/5031 ,  C04B41/5042 ,  C04B2111/00405 ,  C04B35/565 ,  C04B35/584 ,  C04B35/806

摘要： Improved adhesion of thermal barrier coating systems to nonmetallic substrates using a layer of silica on an underlying nonmetallic substrate that includes a silicon containing material is described. The improved adhesion occurs because the improved thermal barrier system improves the temperature capability of the system by providing a layer adjacent the substrate that has improved thermal performance and that is not subject to deterioration. The application of a silica layer of predetermined thickness adjacent the substrate also forms a diffusion barrier for oxygen while eliminating the need to transform an external layer of the substrate by a pre-oxidation step. This diffusion barrier prevents any oxidizable component of the substrate from decomposing. The thermal/environmental barrier coating (T/EBC) system includes an intermediate layer containing YSZ and BSAS, mullite and/or alumina, which is preferably used in combination with a mullite layer that overlies the surface of the silica layer, a layer of BSAS between the mullite layer and the intermediate layer, and a thermal barrier coating of YSZ overlying the intermediate layer.

摘要翻译： 描述了在包括含硅材料的下面的非金属基底上使用一层二氧化硅改善了热障涂层系统对非金属基底的粘合性。 改善的粘合性是因为改进的热障系统通过提供具有改善的热性能并且不会劣化的衬底附近的层来提高系统的温度能力。 在衬底附近施加预定厚度的二氧化硅层还形成氧的扩散阻挡层，而不需要通过预氧化步骤转化衬底的外层。 该扩散阻挡层防止基底的任何可氧化组分分解。 热/环境屏障涂层（T / EBC）系统包括含有YSZ和BSAS，莫来石和/或氧化铝的中间层，其优选与叠加在二氧化硅层表面上的莫来石层组合使用，BSAS层 在莫来石层和中间层之间，以及覆盖中间层的YSZ的热障涂层。

公开(公告)号：US09309895B2

公开(公告)日：2016-04-12

申请号：US13525562

申请日：2012-06-18

申请人： Dave Siddle ,  Sudhir Brahmandam ,  Irene Spitsberg

发明人： Dave Siddle ,  Sudhir Brahmandam ,  Irene Spitsberg

IPC分类号： F04D29/02 ,  F04D29/16 ,  F04D29/22

CPC分类号： F04D29/026 ,  F04D29/167 ,  F04D29/2222 ,  F04D29/2294 ,  F05D2230/90 ,  F05D2300/2263 ,  F05D2300/611

摘要： A closed impeller has a base cover, which has a base interior surface, and a second cover. A vane, which has an inlet distal end and an outlet distal end, is on the base interior surface. The vane has low and high pressure side surfaces wherein they have a low or high pressure midpoint, respectively. A hard coating is on the low and high pressure side surfaces. The hard coating has a minimum low and high pressure coating thickness at their respective midpoints. The minimum low, as well as high, pressure coating thickness ranging between about 0.085 and about 0.8 of either one of the maximum outlet coating thickness at the outlet distal end or the maximum inlet coating thickness at the inlet distal end, respectively.

摘要翻译： 封闭的叶轮具有底盖，其具有底部内表面和第二盖。 具有入口远端和出口远端的叶片在基部内表面上。 叶片具有低和高压侧表面，其中它们分别具有低压或高压中点。 硬涂层位于低压侧和高压侧表面。 硬涂层在各自的中点处具有最小的低压和高压涂层厚度。 分别在出口远端的最大出口涂层厚度或入口远端的最大入口涂层厚度中的任一个之间的最小低压力以及高的压力涂层厚度在约0.085和约0.8之间。

公开(公告)号：US20120003425A1

公开(公告)日：2012-01-05

申请号：US12827294

申请日：2010-06-30

申请人： Sudhir Brahmandam ,  Irene Spitsberg ,  Michael James Verti

发明人： Sudhir Brahmandam ,  Irene Spitsberg ,  Michael James Verti

IPC分类号： C09D1/00 ,  B32B9/00 ,  B32B15/04 ,  B28B7/38 ,  B32B3/00

CPC分类号： C03B11/086 ,  C03B2215/03 ,  C03B2215/11 ,  C03B2215/12 ,  C03B2215/22 ,  Y10T428/24355 ,  Y10T428/265 ,  Y10T428/31678

摘要： A system for precision glass molding comprising a substrate and a coating. The substrate has less than 1.2 wt. % minor constituents. The coating comprises TiAlxNy, wherein x is about 0.7-1.5 and y is about 2.0-3.0. The coating is applied on at least a portion of the substrate.

摘要翻译： 一种用于精密玻璃成型的系统，包括基底和涂层。 基材的含量小于1.2wt。 ％次要成分。 涂层包含TiAlxNy，其中x为约0.7-1.5，y为约2.0-3.0。 将涂层施加在基材的至少一部分上。

公开(公告)号：US07919187B2

公开(公告)日：2011-04-05

申请号：US11616361

申请日：2006-12-27

申请人： Brian Thomas Hazel ,  Christine Walston ,  Irene Spitsberg

发明人： Brian Thomas Hazel ,  Christine Walston ,  Irene Spitsberg

IPC分类号： B32B13/04 ,  B05D3/02

CPC分类号： C04B41/85 ,  C04B35/195 ,  C04B41/009 ,  C04B41/5024 ,  C04B41/52 ,  C04B41/89 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3217 ,  C04B2235/3481 ,  C04B2235/79 ,  C04B2235/80 ,  C23C4/11 ,  C23C4/18 ,  C23C28/04 ,  C23C30/00 ,  F01D5/288 ,  F05D2230/90 ,  F05D2300/211 ,  F05D2300/2112 ,  F23M2900/05004 ,  F23R3/007 ,  Y02T50/67 ,  Y02T50/672 ,  C04B41/4527 ,  C04B41/5096 ,  C04B41/5037 ,  C04B41/5042 ,  C04B35/565 ,  C04B35/584 ,  C04B35/806 ,  C04B41/0072 ,  C04B41/4519 ,  C04B2111/0025

摘要： A protective coating for use on a silicon-containing substrate, and deposition methods therefor. The coating has a strontium-aluminosilicate (SAS) composition that is less susceptible to degradation by volatilization and in corrosive environments as a result of having at least an outer surface region that consists essentially of one or more stoichiometric crystalline phases of SAS and is substantially free of a nonstoichiometric second crystalline phase of SAS that contains a substoichiometric amount of silica. The coating can be produced by carrying out deposition and heat treatment steps that result in the entire coating or just the outer surface region of the coating consisting essentially of the stoichiometric celsian phase.

摘要翻译： 用于含硅基材的保护涂层及其沉积方法。 涂层具有锶 - 硅铝酸盐（SAS）组合物，其通过挥发和腐蚀性环境中较不易于降解，因为至少具有由SAS的一个或多个化学计量结晶相组成的至少一个外表面区域，并且基本上没有 的非化学计量的第二结晶相的SAS，其含有亚化学计量的二氧化硅。 可以通过进行沉积和热处理步骤来产生涂层，所述沉积和热处理步骤导致整个涂层或仅基本上由化学计量的凝胶相组成的涂层的外表面区域。

公开(公告)号：US07597966B2

公开(公告)日：2009-10-06

申请号：US11160164

申请日：2005-06-10

申请人： Irene Spitsberg ,  Brett Allen Rohrer Boutwell ,  Robert William Bruce ,  Curtis Alan Johnson ,  Bangalore Aswatha Nagaraj ,  William Scott Walston

发明人： Irene Spitsberg ,  Brett Allen Rohrer Boutwell ,  Robert William Bruce ,  Curtis Alan Johnson ,  Bangalore Aswatha Nagaraj ,  William Scott Walston

IPC分类号： B32B9/00

CPC分类号： C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/249953 ,  Y10T428/249955

摘要： A thermal barrier coating and deposition process for a component intended for use in a hostile thermal environment, such as the turbine, combustor and augmentor components of a gas turbine engine. The TBC has a first coating portion on at least a first surface portion of the component. The first coating portion is formed of a ceramic material to have at least an inner region, at least an outer region overlying the inner region, and a columnar microstructure whereby the inner and outer regions comprise columns of the ceramic material. The columns of the inner region are more closely spaced than the columns of the outer region so that the inner region of the first coating portion is denser than the outer region of the first coating portion, wherein the higher density of the inner region promotes the impact resistance of the first coating portion.

摘要翻译： 用于在敌对热环境中使用的部件的热障涂层和沉积工艺，例如燃气轮机的涡轮机，燃烧器和增压器部件。 所述TBC在所述部件的至少第一表面部分上具有第一涂覆部分。 第一涂覆部分由陶瓷材料形成，至少具有内部区域，至少覆盖内部区域的外部区域和柱状微结构，由此内部和外部区域包括陶瓷材料的列。 内部区域的列与外部区域的列紧密地间隔开，使得第一涂覆部分的内部区域比第一涂覆部分的外部区域更致密，其中内部区域的较高密度促进了冲击 第一涂布部分的电阻。

公开(公告)号：US07449254B2

公开(公告)日：2008-11-11

申请号：US11040855

申请日：2005-01-21

申请人： Irene Spitsberg ,  Christine Govern ,  Bangalore Aswatha Nagaraj ,  David Joseph Mitchell

发明人： Irene Spitsberg ,  Christine Govern ,  Bangalore Aswatha Nagaraj ,  David Joseph Mitchell

IPC分类号： B32B18/00

CPC分类号： C04B35/195 ,  C04B35/486 ,  C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3225 ,  C23C28/042 ,  C23C28/048 ,  F05B2230/90 ,  F05C2253/12 ,  Y10T428/12576 ,  Y10T428/12667 ,  Y10T428/12729 ,  C04B41/4527 ,  C04B41/5024 ,  C04B41/5042 ,  C04B41/5051 ,  C04B41/5044 ,  C04B41/5027 ,  C04B41/522 ,  C04B35/565 ,  C04B35/584 ,  C04B35/806

摘要： An article comprising a substrate formed of a silicon-comprising material, such as an article exposed to the hostile thermal environment of a gas turbine engine. The article further comprises an environmental barrier layer, e.g., an alkaline earth metal aluminosilicate, and a physical barrier layer overlying the environmental barrier layer. The physical barrier layer comprises zirconia or hafnia stabilized with an oxide of a metal selected from the group consisting of magnesium, calcium, scandium, yttrium, and lanthanide metals; and a low CTE oxide selected from the group consisting of niobia and tantala; and mixtures thereof. A method for preparing an environmental barrier coating system on a substrate formed of a silicon-comprising material is also disclosed.

摘要翻译： 一种制品，其包括由含硅材料形成的基底，例如暴露于燃气涡轮发动机的恶劣热环境的制品。 该制品还包括环境阻挡层，例如碱土金属铝硅酸盐和覆盖环境阻挡层的物理阻挡层。 物理阻隔层包括用选自镁，钙，钪，钇和镧系金属的金属的氧化物稳定的氧化锆或氢氧化铪; 和选自iobia和tantala的低CTE氧化物; 及其混合物。 还公开了一种在由含硅材料形成的基底上制备环境屏障涂层系统的方法。

公开(公告)号：US07442444B2

公开(公告)日：2008-10-28

申请号：US11150098

申请日：2005-06-13

申请人： Brian Thomas Hazel ,  Irene Spitsberg ,  Brett Allen Boutwell

发明人： Brian Thomas Hazel ,  Irene Spitsberg ,  Brett Allen Boutwell

IPC分类号： B32B15/04 ,  B32B18/00 ,  F01D5/14

CPC分类号： C04B35/806 ,  C04B35/16 ,  C04B35/185 ,  C04B35/195 ,  C04B35/573 ,  C04B35/58085 ,  C04B35/584 ,  C04B35/62863 ,  C04B41/52 ,  C04B41/89 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3225 ,  C04B2235/3427 ,  C04B2235/3463 ,  C04B2235/3481 ,  C04B2235/5244 ,  C04B2235/5248 ,  C23C4/02 ,  C23C28/042 ,  C23C28/048 ,  C23C28/322 ,  C23C28/345 ,  C23C28/3455 ,  C23C28/36 ,  C23C30/00 ,  F01D5/288 ,  F05D2230/90 ,  F05D2260/95 ,  F05D2300/222 ,  F05D2300/611 ,  Y10T428/12611 ,  Y10T428/12674 ,  Y10T428/264 ,  C04B41/5071 ,  C04B41/53 ,  C04B41/0072 ,  C04B41/4558 ,  C04B41/5035 ,  C04B41/5024 ,  C04B41/5037 ,  C04B41/4529 ,  C04B41/5031 ,  C04B41/4527 ,  C04B41/5042 ,  C04B41/522

摘要： An article comprising a silicon-containing substrate, a silicide-containing bond coat layer overlying the substrate, and typically an environmental barrier coating overlaying the bond coat layer. An article is also provided wherein the environmental barrier coating comprises: (1) an optional inner silica scale layer overlaying the bond coat layer; (2) intermediate layer overlaying the inner silica scale layer, or the bond coat layer in the absence of the inner silica scale layer, and comprising mullite, or a combination of mullite with a barium strontium aluminosilicate, a yttrium silicate, or a calcium aluminosilicate; and (3) an outer steam-resistant barrier layer overlaying the intermediate layer and consisting essentially of an alkaline earth silicate/aluminosilicate. Processes are also provided for forming the silicide-containing bond coat layer over the substrate, followed by forming the environmental barrier coating over the bond coat layer.

摘要翻译： 包括含硅基材，覆盖在基材上的含硅化物粘合涂层的物品，通常是覆盖粘合涂层的环境阻挡涂层。 还提供了一种制品，其中所述环境保护涂层包括：（1）覆盖所述粘合涂层的任选的内部二氧化硅刻度层; （2）覆盖内部二氧化硅刻度层的中间层或不存在内部二氧化硅刻度层的粘合涂层，并且包含莫来石或莫来石与铝酸钡锶钡，硅酸钇或硅铝酸钙的组合 ; 和（3）覆盖中间层并基本上由碱土金属硅酸盐/硅铝酸盐组成的外部耐蒸汽阻挡层。 还提供了用于在衬底上形成含硅化物粘合涂层的工艺，然后在粘合涂层上形成环境阻挡涂层。