公开(公告)号：US4608201A

公开(公告)日：1986-08-26

申请号：US612213

申请日：1984-05-21

Applicant: Gregory J. McCollum

Inventor： Gregory J. McCollum

IPC: C07D223/10 ,  C08G69/20 ,  C07D201/02 ,  C07D201/08

CPC classification number: C08G69/20 ,  C07D223/10

Abstract: A process for preparing a lactam imide involves reacting together a lactam, a non-volatile carboxyl group-containing material, and an anhydride of a volatile carboxylic acid with the proviso that an appreciable amount of non-volatile carboxyl group-containing material and volatile carboxylic acid which is generated as the anhydride reacts are both present in the reaction mixture at the same time.

Abstract translation: 制备内酰胺的方法包括使内酰胺，不挥发性含羧基材料和挥发性羧酸的酸酐反应，条件是可观察量的不挥发性含羧基材料和挥发性羧酸 酸酐反应生成的酸都同时存在于反应混合物中。

公开(公告)号：US4250093A

公开(公告)日：1981-02-10

申请号：US53606

申请日：1979-06-29

Applicant: Frederick A. Pesa ,  Anne M. Graham

Inventor： Frederick A. Pesa ,  Anne M. Graham

IPC: C07D223/10 ,  B01J23/00 ,  B01J23/64 ,  B01J23/84 ,  B01J23/89 ,  C07B61/00 ,  C07D201/02 ,  C07D201/08 ,  C07D207/263 ,  C07D211/76

CPC classification number: B01J37/16 ,  B01J23/462 ,  B01J23/64 ,  B01J23/84 ,  B01J23/89 ,  B01J23/8906 ,  C07D201/08

Abstract: Five, six and seven member nitrogen-containing saturated heterocyclic compounds can be prepared by the catalytic hydrogenation/cyclization of beta, gamma and delta-cyanoesters. Applicants have discovered that this reaction is especially effective when it is conducted in the presence of catalysts comprising at least one of ruthenium and iron.

Abstract translation: 可以通过β，γ和δ-氰酯的催化氢化/环化制备五，六和七元含氮饱和杂环化合物。 申请人已经发现，当在包含钌和铁中的至少一种的催化剂存在下进行时，该反应特别有效。

公开(公告)号：US4165328A

公开(公告)日：1979-08-21

申请号：US901089

申请日：1978-04-28

Applicant: Kenji Nishimura ,  Haruhiko Miyazaki ,  Kenji Kuniyasu ,  Satoru Ono

Inventor： Kenji Nishimura ,  Haruhiko Miyazaki ,  Kenji Kuniyasu ,  Satoru Ono

IPC: C07C45/00 ,  C07C45/78 ,  C07C45/80 ,  C07C45/82 ,  C07C49/403 ,  C07D201/02 ,  C07D201/04 ,  C07D201/16 ,  C07C121/407

CPC classification number: C07C255/00 ,  C07C45/783 ,  C07C45/80 ,  C07C45/82 ,  C07D201/16

Abstract: Disclosed is a process for separating 11-cyanoundecanoic acid, cyclohexanone and .epsilon.-caprolactam from a pyrolysis product obtained by pyrolyzing 1,1'-peroxydicyclohexylamine in the presence of steam at a temperature of 300.degree. to 1,000.degree. C. The pyrolysis product is first contacted with a mixture comprised of aqueous ammonia and at least one organic solvent selected from benzene, toluene and xylene, and the so prepared liquid is separated into the oily layer and the aqueous layer. On one hand, the oily layer is distilled to separate cyclohexanone therefrom. On the other hand, the aqueous layer is acidified to a pH of below 4.0 by adding thereto a mineral acid and maintained at a temperature of 40.degree. to 100.degree. C. to separate crude 11-cyanoundecanoic acid in molten form from the aqueous layer, and then, the separated crude molten 11-cyanoundecanoic acid is washed with hot water to extract .epsilon.-caprolactam therefrom.

Abstract translation: 公开了一种通过在300℃至1000℃的温度下在1,1'-二氧化二环己基胺蒸气存在下热解得到的热解产物中分离出11-氰基十一烷酸，环己酮和ε-己内酰胺的方法。热解产物是先 与由氨水和选自苯，甲苯和二甲苯中的至少一种有机溶剂组成的混合物接触，将如此制备的液体分离成油层和水层。 一方面，将油层蒸馏以分离出环己酮。 另一方面，通过向其中加入无机酸将水层酸化至pH值低于4.0，并保持在40℃至100℃的温度下，将熔融形式的粗的11-氰基十一烷酸与水层分离， 然后，将分离的粗熔融的11-氰基十一烷酸用热水洗涤以从其中提取ε-己内酰胺。

公开(公告)号：US4141896A

公开(公告)日：1979-02-27

申请号：US832008

申请日：1977-09-09

Applicant: Otto Immel ,  Andre DE Jager ,  Bernd-Ulrich Kaiser ,  Hans-Helmut Schwarz ,  Klaus Starke

Inventor： Otto Immel ,  Andre DE Jager ,  Bernd-Ulrich Kaiser ,  Hans-Helmut Schwarz ,  Klaus Starke

IPC: C07D201/02 ,  C07D201/04

CPC classification number: C07D201/04

Abstract: A process for the production of .epsilon.-caprolactum from cyclohexanone oxime by rearrangement in the gaseous phase on a fluid-bed catalyst containing boron oxide, wherein residues from the distillation of cyclohexanone oxime are introduced into the reaction in liquid form, and wherein from 5 to 500 times their quantity of cyclohexanone oxime in vapor form and at least 50 times their quantity of inert gas are present during the reaction.

Abstract translation: 一种通过在含有氧化硼的流化床催化剂上在气相中重新排列从环己酮肟生产ε-己内酰胺的方法，其中将来自环己酮肟蒸馏的残余物以液体形式引入反应中，其中从5至 蒸气形式的环己酮肟的量为其500倍，并且在反应期间存在至少50倍量的惰性气体。

公开(公告)号：US4110340A

公开(公告)日：1978-08-29

申请号：US745019

申请日：1976-11-26

Applicant: John F. Knifton

Inventor： John F. Knifton

IPC: C07D201/02 ,  C07D207/26

CPC classification number: C07D201/02

Abstract: This invention concerns processes for preparing cyclic, five-membered ring, lactams through the carbonylation of allylic substrates in the presence of rhodium catalysts.

Abstract translation: 本发明涉及在铑催化剂存在下通过烯丙基底物的羰基化制备环状五元环，内酰胺的方法。

公开(公告)号：US4038198A

公开(公告)日：1977-07-26

申请号：US571133

申请日：1975-04-24

Applicant: Kuno Wagner ,  Karlheinz Andres

Inventor： Kuno Wagner ,  Karlheinz Andres

IPC: C07D241/08 ,  C07D201/02 ,  C07D201/18 ,  C07D207/263 ,  C08F2/04 ,  C08G8/28 ,  C08G12/40 ,  C08G18/38 ,  C08G18/40 ,  C08G18/67 ,  C08G85/00 ,  C08G18/30 ,  C08G18/34 ,  C09K3/00

CPC classification number: C08G18/38 ,  C07D201/18 ,  C08G12/40 ,  C08G18/40 ,  C08G18/67 ,  C08G8/28 ,  C08G85/00

Abstract: The present invention relates to storage stable multi-component mixtures containing:A. at least one compound selected from the group consisting of lactams and aza lactams;B. at least one compound selected from the group consisting of water, and difunctional acid-group-free organic compounds containing functional groups selected from the group consisting of hydroxyl, primary amino-, secondary amino, and sulfhydryl groups; andC. at least one acid selected from the group consisting ofI. mono- and poly-carboxylic acids,Ii. organic and inorganic acids of phosphorus,Iii. inorganic acids of boron, andIv. partially hydrolyzed antimonous and antimonic acid esters of polyhydroxyl compounds with molecular weights of from 62 to 600.

公开(公告)号：US3843630A

公开(公告)日：1974-10-22

申请号：US32865373

申请日：1973-02-01

Applicant: KANEBO LTD

Inventor： FUJITA I ,  OTOI K ,  YONEYA T

IPC: C07D201/02 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J21/14 ,  B01J23/00 ,  B01J25/00 ,  B01J27/00 ,  B01J29/85 ,  B01J37/26 ,  C07B61/00 ,  C07D41/06

CPC classification number: B01J37/26 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J21/14

Abstract: The present invention relates to a process for producing Epsilon -caprolactam which comprises bringing N-acetyl- Epsilon caprolactam into contact in a gaseous phase with an acid catalyst or basic catalyst in the presence of water vapor.

公开(公告)号：US3816404A

公开(公告)日：1974-06-11

申请号：US20619771

申请日：1971-12-08

Applicant: TEXACO INC

Inventor： KABLAOUI M ,  LOVE R ,  DURANLEAU R

IPC: C07C205/51 ,  C07D201/02 ,  C07D201/10 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07C201/12 ,  C07C201/14 ,  C07D201/10 ,  Y02P20/582 ,  C07C205/45 ,  C07C205/51

Abstract: A METHOD FOR PREPARING CAPROLACTAM BY THE STEPS OF (1) NITRO-OXIDIZING CYCLOHEXENE TO 2-NITROCYCOLHEXANONE, (2) CLEAVING AND ESTERIFYING 2-NITROCYCLOHEXANONE WITH AN ALCOHOL TO FORM AN ALKYL 6-NITROHEXANOATE AND (3) CATALYTICALLY HYDROGENATING AND CYCLIZING THE NITROESTER TO CAPROLACTAM.

公开(公告)号：US3714185A

公开(公告)日：1973-01-30

申请号：US3714185D

申请日：1970-09-25

Applicant: ATLANTIC RICHFIELD CO

Inventor： MC COY J ,  YOO J

IPC: B01J31/24 ,  C07D201/02 ,  C07D27/08

CPC classification number: C07D201/02 ,  B01J21/12 ,  B01J31/1616 ,  B01J31/20 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/321 ,  B01J2531/0219 ,  B01J2531/822 ,  B01J2531/845 ,  Y02P20/588

Abstract: The use of certain complexes of cobalt and rhodium containing phosphine either either unsupported or supported, as catalysts for the cyclo-carbonylation reaction.

Abstract translation: 使用含有膦或铑的某些络合物，无论是负载的还是负载的，都是环羰基化反应的催化剂。

公开(公告)号：US3712887A

公开(公告)日：1973-01-23

申请号：US3712887D

申请日：1970-10-02

Applicant: RHONE POULENC SA

Inventor： COLLEUILLE Y ,  GARDON R

IPC: C07D201/10 ,  C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: E-CAPROLACTAM IS PREPARED FROM A CYCLOHEXANE OXIDATION PRODUCT CONTAINING CYCLOHEXYL HYDROPEROXIDE AND OXIDATION BY-PRODUCTS INCLUDING 6-HYDROPEROXY-HEXANOIC ACID, WHICH HAS BEEN OBTAINED BY LIQUID PHASE OXIDATION OF CYCLOHEXANE, WITHOUT A METAL CATALYST, USING A MOLECULAR OXYGEN CONTAINING GAS, BY WASHING THE OXIDATION PRODUCT WITH WATER, SEPARATING THE RESULTING AQUEOUS PHASE CONTAINING 6-HYDROPEROXYHEXANOIC ACID AND HEATING THE ACID UNDER PRESSURE WITH AMMONIA AND HYDROGEN IN THE PRESENCE OF A HYDROGENATION CATALYST.