摘要:
A process for producing rigid polyurethane foams or rigid polyisocyanurate foams is provided. The process contains the reaction of polyisocyanate, fatty acid modified polyetherpolyol, polyetherpolyol, optionally flame retardant, blowing agent, catalyst, and optionally further auxiliary and/or admixture agent, wherein the polyetherpolyol is obtained by a process containing reacting orthotolylenediamine and optionally further co-starters with alkylene oxide containing ethylene oxide wherein the ethylene oxide content is more than 20 wt %, and then reacting the reaction product with alkylene oxide containing propylene oxide wherein the 1,2-propylene oxide content is more than 20 wt %, in the presence of a catalyst.
摘要:
A urethane-based pressure-sensitive adhesive including a polyurethane-based resin, in which: the polyurethane-based resin includes a polyurethane-based resin obtained by curing a composition containing a polyol (A) and a polyfunctional isocyanate compound (B); and the polyol (A) contains a polyol (A1) having 3 OH groups and a number-average molecular weight Mn of 8,000 to 20,000. The urethane-based pressure-sensitive adhesive is excellent in reworkability, initial wettability, and transparency, and is preferably excellent in adhesive residue-preventing property, that preferably has a large wetting rate, and that is preferably prevented from showing external appearance unevenness due to orange peel. Also provided is a surface protective film using such urethane-based pressure-sensitive adhesive in its pressure-sensitive adhesive layer. Further provided is an optical member or electronic member to which such surface protective film is attached.
摘要:
A resin composition includes: a polyol (A) having two or more OH groups; a polyfunctional isocyanate compound (B); and a catalyst (C), in which: the content ratio of the polyfunctional isocyanate compound (B) with respect to 100 parts by weight of the polyol (A) is 1 part by weight to 100 parts by weight; and the catalyst (C) includes an iron complex compound. The resin composition can serve as a pressure-sensitive adhesive composition that is a material for forming a pressure-sensitive adhesive layer containing a polyurethane-based resin, the resin composition showing extremely high reactivity without any use of a tin compound as a catalyst, allowing a cross-linking reaction between a polyol and a polyfunctional isocyanate compound to rapidly progress, and being capable of providing a pressure-sensitive adhesive layer having high transparency. Also provided are a pressure-sensitive adhesive sheet and a surface protective film each including such pressure-sensitive adhesive layer.
摘要:
An encapsulated particle includes a core particle and a polyurethane disposed about the core particle. The polyurethane includes the reaction product of an aromatic isocyanate component and a polyol component. The polyol component includes a polyol derived from an aromatic amine-based initiator and an aliphatic polyether polyol. The polyol derived from the aromatic amine-based initiator has a nominal functionality of 4. The aliphatic polyether polyol has a nominal functionality of from 2 to 4. The weight ratio of the polyol derived from the aromatic amine-based initiator and the aliphatic polyether polyol is from about 1:2 to 2:1. A method of forming the encapsulated particle is also provided.
摘要:
Semi-rigid polyurethane foams having a density of 90 to 180 kg/m3 and a compressive strength of 20 to 95 kPa are produced by reacting a polyisocyanate with an isocyanate-reactive component that includes an o-toluenediamine initiated polyether polyol. These foams are particularly useful as composites for automotive interior components.
摘要翻译:通过使多异氰酸酯与包含邻甲苯胺引发的聚醚多元醇的异氰酸酯反应性组分反应,制备密度为90至180kg / m 3,抗压强度为20至95kPa的半刚性聚氨酯泡沫。 这些泡沫特别适用于汽车内饰件的复合材料。
摘要:
The present invention discloses aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising 80 mole percent or greater of terephthalic acid; B) a polyether polyol having a nominal functionality greater than 2 and less than or equal to 4, a molecular weight of 250 to 1000 and has a polyoxypropylene content of at least 70% by weight of the polyol; and C) a glycol other than B having a molecular weight from 60 to 250; wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 15 to 70 weight percent of B); and 10 to 50 weight percent of C).
摘要:
An embodiment of a closed-cell polymeric rigid foam may be made using a one-shot method and a reaction system that includes a hydrofluoroalkene physical blowing agent and a polyol mixture having an aminic polyol. The hydrofluoroalkene blowing agent has 3 to 5 carbon atoms and a boiling point between 10° C. and 40° C. at 1 atmosphere pressure. Embodiments of rigid foams may have high closed cell content and are particularly well suited for thermal insulation.
摘要:
The invention provides polyisocyanate prepolymers, characterised in that they contain polyether carbonate polyols as structural component, their preparation and their use as isocyanate component in 1- and 2-component systems for surface-coating compositions, adhesives and sealing materials.
摘要:
A polyurethane foam and a resin composition that may be used to form the polyurethane foam are provided. The resin composition includes a first polyol based upon ethylene diamine and having about 100% ethylene oxide capping and present in an amount of from about 0.3 to about 15 parts by weight based on 100 parts by weight of the resin composition, a second polyol, and a physical blowing agent having at least 4 carbon atoms. The polyurethane foam includes the reaction product of an isocyanate component and the resin composition comprising the first and second polyol, in the presence of the physical blowing agent. A method of forming the polyurethane foam on a substrate combines the isocyanate component and the resin composition to form a reaction mixture. The reaction mixture is applied onto the substrate to form the polyurethane foam.
摘要:
Polyurethane foams are made and attached to a substrate having an open cavity, but reacting prepolymer and polyol components in the presence of certain carbamate blowing agents. This process allows for very fast curing, good quality, adherent foamy to be produced on, for example, vehicle parts and assemblies, for acoustical or vibration dampening and for structural reinforcement.