Abstract:
The invention provides fuel mixtures containing fuel oil, glycerol, glycerol impurities and non-ionic surfactants. The mixtures remain homogeneous longer and are more chemically stable than previous mixtures. Upon combustion, the mixtures generate reduced SOx, NOx and particulate matter emissions compared to residual fuels and offer improved engine performance over previous mixtures.
Abstract:
Provided herein are, inter alia, heavy crude oil emulsion compositions and methods of making the same. The compositions and methods provided herein are particularly useful for the transport of heavy crude oils.
Abstract:
The present invention provides a stable fuel composition that can be used as a drop-in replacement for number 2 fuel oil without requiring infrastructure changes. The fuel comprises a continuous phase of mostly biofuel, an aqueous disperse phase, and at least one emulsifier. The continuous phase contains about 50 wt % to about 95 wt % of at least one liquid vegetable or liquid animal oil/fat or mixtures thereof; about 1 wt % to about 20 wt % of a renewable or fossil fuel derived thinning solvent or mixtures thereof, with or without 1 wt % to about 25 wt % of a C1-C4 monohydric alcohols, and with or without about 1 wt % to about 30 wt % of petroleum middle distillate. The aqueous phase contains about 1 wt % to about 50 wt % of deionized/purified water, with or without 1 wt % to about 25 wt % of a C1-C4 monohydric alcohols.
Abstract:
A fuel composition for use in internal-combustion engines has a lower grade fuel component, and a microemulsion. The microemulsion includes at least one of hydrous component, renewable component, and polar component being present in an amount effective for forming the fuel composition. The fuel composition may enhance lubricity, corrosion, and water stability without the use of other additives and inhibitors.
Abstract:
An emulsifier for a water-in-oil (W/O) emulsion fuel wherein reseparation between oil and water does not take place for a long period of time because of a stable emulsion state with homogenous dispersion. The emulsifier for a water-in-oil emulsion fuel includes the following (1) to (7) components: (1) heavy oil A: 50 mL or more 100 mL, (2) heavy oil B: 100 mL or more 200 mL, (3) heavy oil C: 300 mL or more 450 mL, (4) methanol: 100 mL or more 150 mL, (5) ethanol: 100 mL or more 200 mL, (6) palm oil: 100 mL or more 150 mL, and (7) water: 100 mL or more 200 mL.
Abstract:
There is provided an apparatus for manufacturing a reformed fuel. The apparatus for manufacturing a reformed fuel includes a water tank unit configured to supply water which is aerated and, then, to which an ultrasonic wave or an electric field is applied; an oil tank configured to supply oil pre-treated by a first catalyst; a mixing tank connected to the water tank unit and the oil tank, and configured to generate mixture oil by mixing the water introduced from the water tank unit and the oil introduced from the oil tank; and a combination chamber unit connected to the mixing tank, and configured to generate a reformed fuel by supplying a second catalyst to the mixture oil introduced from the mixing tank.
Abstract:
Provided herein are, inter alia, heavy crude oil emulsion compositions and methods of making the same. The compositions and methods provided herein are particularly useful for the transport of heavy crude oils.
Abstract:
A mixing apparatus is disclosed. The mixing apparatus comprises a mixing device having a constant flow area. The mixing device is configured to create a shearing environment. Several types of mixing apparatus are disclosed. Methods for producing aqueous fuel emulsions with consistently uniform dispersed phase particle sizes using a mixing apparatus are also disclosed.
Abstract:
A blendstock for forming a fuel composition for use in internal-combustion engines, includes a polar fluid component, a microblender component, and a neutralizer component. The neutralizer component is present in an amount effective to substantially neutralize the microblender component to allow for the microblender component to substantially spontaneously blend with the polar fluid component. The polar fluid component may include a water component and an alcohol component, and the neutralizer component may include an ammonia component. The blendstock may be added to a hydrocarbon fuel, such as diesel fuel, to form the fuel composition.
Abstract:
Fatty esters of oligoesters of a dicarboxylic acid and a polyol retaining at least one free hydroxyl group, particularly of the formula (I): R1—[OR2O—C(O)—R3—(O)C—]m—R4 (I), where R1 is H, a monocarboxylic acid group, or R6O—[C(O)—R3—(O)C]—; R2s are residues of polyols having at least one substituent free hydroxyl; R3s are hydrocarbylene; R4 is —OH, —OM where M is a salt forming metal, amine or ammonium, —OR6, or —OR2O—R7; R5 is C7 to C21 hydrocarbyl; R6 is C8 to C22 hydrocarbyl; R7 is H, or —C(O)R5; and m is 1 to 20; provided that at least one of R1 and R4 is or includes a C8 to C22 group, are surfactants. A range of surfactant properties can be obtained by varying the molecules within these ranges. Especially where R2 is derived from a higher polyol e.g. sorbitol, R3 is C2 to C6, and the fatty terminal group is C8 to C14, the products can be highly water soluble and effective oil in water emulsifiers.