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公开(公告)号：US20130014880A1
公开(公告)日：2013-01-17
申请号：US13556248
申请日：2012-07-24
申请人： Andy Haishung TSOU , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
发明人： Andy Haishung TSOU , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
IPC分类号： B60C1/00
CPC分类号： B32B7/12 , B32B25/04 , B32B25/08 , B32B25/16 , B32B2307/724 , B32B2307/7265 , B32B2319/00 , B32B2377/00 , B32B2605/00 , B60C1/0008 , B60C1/0025 , B60C5/14 , C08L9/00 , C08L23/16 , C08L23/283 , C08L2312/00 , Y10T152/10495 , Y10T152/10855 , Y10T428/1386 , Y10T428/31721 , Y10T428/3175 , Y10T428/31797 , Y10T428/31826 , Y10T428/3183 , Y10T428/31917 , C08L2666/04 , C08L2666/06 , C08L2666/08 , C08L2666/02
摘要： A vulcanizable layered composition comprising at least two layers and at least one tie layer. The first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises about 50 to about 100 weight % of at least one halogenated isobutylene containing elastomer; up to about 50 weight % of at least one high diene elastomer; about 20 to about 50 weight % of at least one filler; up to about 30 weight % of at least one processing oil; about 1 to about 20 parts per hundred (phr) of at least one tackifier; and about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers. The fluid permeation prevention layer preferably comprises a thermoplastic engineering resin component and an elastomer component.
摘要翻译： 一种可硫化的层状组合物，其包含至少两层和至少一层粘结层。 两层的第一层包括防止流体渗透的层，所述两层的第二层包含至少一种高二烯橡胶，并且所述粘结层包含约50至约100重量％的至少一种含卤代异丁烯的弹性体; 至多约50重量％的至少一种高二烯弹性体; 约20至约50重量％的至少一种填料; 至多约30重量％的至少一种加工油; 约1至约20份/ 100（phr）的至少一种增粘剂; 和约0.2至约15份/ 100份橡胶（phr）的弹性体固化体系。 流体防渗层优选包含热塑性工程树脂组分和弹性体组分。
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12.发明申请公开(公告)号：US20100331452A1
公开(公告)日：2010-12-30
申请号：US12682490
申请日：2007-10-11
CPC分类号： C08J3/005 , B29C47/0011 , B29C47/40 , C08J2377/00 , C08L15/00 , C08L23/28 , C08L23/283 , C08L77/00 , C08L2666/02 , C08L2666/06
摘要： A durable, flexible, impermeable thermoplastic elastomer composition is produced using a dynamic vulcanization process conducted in a high shear mixer at elevated temperature. The composition comprises cured particles of a first halogenated isobutylene-containing elastomer and particles of a second elastomer having at least one functional group capable of reacting with and grafting to a polyamide, the particles of the first and second elastomers dispersed in a continuous thermoplastic polyamide matrix, said process comprising: (1) dispersing a curative in the halogenated elastomer and forming a pre-compounded, preferably pelletized composition; (2) introducing polyamide resin and optional stabilizers into the mixer and shearing and heating to melt the polyamide and form a mixture; (3) introducing a nylon plasticizer to reduce the viscosity of the polyamide mixture to substantially match that of the pre-compounded elastomer under mixing conditions; (4) introducing pellets of the pre-compounded elastomer into the mixer and initiating dynamic vulcanization of the elastomer and polyamide components; (5) introducing the second elastomer and continuing heating and shearing to disperse the second elastomer and substantially complete dynamic vulcanization; and delivering the thermoplastic elastomer composition from the mixer. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.
摘要翻译： 使用在高剪切混合器中在高温下进行的动态硫化方法制备耐用的，柔性的，不渗透的热塑性弹性体组合物。 该组合物包含含有第一卤代异丁烯的弹性体的固化颗粒和具有至少一个能够与聚酰胺反应和接枝到聚酰胺上的官能团的第二弹性体颗粒，第一和第二弹性体的颗粒分散在连续的热塑性聚酰胺基质 所述方法包括：（1）将固化剂分散在卤化弹性体中并形成预混合的，优选颗粒状的组合物; （2）将聚酰胺树脂和任选的稳定剂引入混合器中并剪切和加热以熔化聚酰胺并形成混合物; （3）在混合条件下引入尼龙增塑剂以降低聚酰胺混合物的粘度与预混合弹性体的粘度基本一致; （4）将预混合弹性体的颗粒引入混合器中并引发弹性体和聚酰胺组分的动态硫化; （5）引入第二弹性体并继续加热和剪切以分散第二弹性体并基本上完成动态硫化; 并从混合器中输送热塑性弹性体组合物。 这样的组合物特别适用于诸如轮胎内衬和阻挡膜或层的应用。
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13.发明申请POLYAMIDE RESIN COMPOSITION HAVING SUPERIOR EXTENSIBILITY AND FLEXING FATIGUE AND PNEUMATIC TIRE AND HOSE USING THE SAME 有权具有超强扩展性和柔韧性疲劳的聚酰胺树脂组合物及使用其的气动轮胎和软管公开(公告)号：US20100099821A1
公开(公告)日：2010-04-22
申请号：US12523477
申请日：2007-01-18
IPC分类号： C08G59/16
CPC分类号： C08L77/00 , C08L51/04 , C08L51/06 , C08L77/02 , C08L77/06 , C08L2666/14 , C08L2666/02 , C08L2666/06 , C08L2666/24
摘要： A polyamide resin composition, having an excellent extensibility and flexing fatigue, composed of a polyamide resin (A), as a matrix, and a modifying polymer (C), dispersed therein, having a functional group (B) reactive with the polyamide resin (A), wherein a tensile stress at break of the modifying polymer (C) is 30 to 70% of the tensile stress at break of the polyamide resin (A), and a tensile elongation at break of the modifying polymer (C) is 100 to 500% of the tensile elongation at break of the polyamide resin (A) as well as a pneumatic tire and hose using the same.
摘要翻译： 具有聚酰胺树脂（A），作为基质的聚酰胺树脂（A）和分散有聚酰胺树脂（B）的官能团（B））的改性聚合物（C）具有优异的伸长性和挠曲疲劳性的聚酰胺树脂组合物 A），其中，改性聚合物（C）的断裂拉伸应力为聚酰胺树脂（A）的断裂拉伸应力的30〜70％，改性聚合物（C）的拉伸断裂伸长率为100 至聚酰胺树脂（A）的断裂拉伸伸长率的500％，以及使用其的充气轮胎和软管。
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公开(公告)号：US07560514B2
公开(公告)日：2009-07-14
申请号：US10548298
申请日：2003-03-06
申请人： Yoshihiro Soeda , Andy Haishung Tsou , Yoshiaki Hashimura , Hiroyuki Kaidou , Jerry Willie Ball
发明人： Yoshihiro Soeda , Andy Haishung Tsou , Yoshiaki Hashimura , Hiroyuki Kaidou , Jerry Willie Ball
CPC分类号： C08L77/06 , C08L23/28 , C08L23/283 , C08L77/00 , C08L77/02 , C08L2312/00 , C08L2666/20 , C08L2666/06 , C08L2666/08
摘要： A thermoplastic elastomer composition comprising a dynamically vulcanized blend of (A) a partially cured halogenated isobutylene elastomer and (B) a polyamide, wherein a tensile modulus at 100% elongation of the halogenated isobutylene elastomer dispersed in the polyamide matrix is less than 0.60 MPa.
摘要翻译： 一种热塑性弹性体组合物，其包含（A）部分固化的卤代异丁烯弹性体和（B）聚酰胺的动态硫化共混物，其中分散在聚酰胺基质中的卤代异丁烯弹性体的100％伸长时的拉伸模量小于0.60MPa。
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15.发明授权Thermoplastic elastomer composition having viscosity-enhanced and vulcanized elastomer dispersions 有权具有粘度增强和硫化弹性体分散体的热塑性弹性体组合物公开(公告)号：US07538158B2
公开(公告)日：2009-05-26
申请号：US10548059
申请日：2003-03-06
CPC分类号： C08L23/283 , C08L77/00 , C08L2666/20
摘要： A thermoplastic elastomer composition having improved mechanical properties and fatigue resistance comprising (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an amine component selected from tertiary amines and secondary diamines, wherein the elastomers are dispersed as a domain in a continuous phase of the polyamide.
摘要翻译： 一种具有改进的机械性能和抗疲劳性的热塑性弹性体组合物，其包含（A）卤代异丁烯弹性体，（B）聚酰胺和（C）选自叔胺和仲二胺的胺组分，其中弹性体作为结构域分散在连续 聚酰胺的相。
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公开(公告)号：US07485677B2
公开(公告)日：2009-02-03
申请号：US10478281
申请日：2002-05-29
CPC分类号： B60C1/0008 , C08K3/346 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/283 , C08L77/00 , C08L23/28 , C08L2666/20 , C08L2666/04
摘要： The present invention is a blend of an halogenated elastomer and a clay, desirably an exfoliated clay, to form a nanocomposite suitable for an air barrier. In one embodiment, the halogenated elastomer is a polymer comprising C4 to C7 isoolefin derived units, a para-methylstyrene derived units, and para-(halomethylstyrene) derived units. In another embodiment, the halogenated elastomer is a butyl-type rubber. The clay may or may not have an additional exfoliating treatment present prior to blending with the interpolymer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an innerliner or innertube.
摘要翻译： 本发明是卤化弹性体和粘土的混合物，理想地是剥离粘土，以形成适合于空气屏障的纳米复合材料。 在一个实施方案中，卤化弹性体是包含C4-C7异烯烃衍生单元，对甲基苯乙烯衍生单元和对 - （卤代甲基苯乙烯）衍生单元的聚合物。 在另一个实施方案中，卤化弹性体是丁基型橡胶。 在与共聚体共混之前，粘土可以或可以不具有额外的去角质处理。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为内衬或内管。
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公开(公告)号：US07407999B2
公开(公告)日：2008-08-05
申请号：US10476936
申请日：2002-05-29
CPC分类号： C08L23/22 , C08K3/346 , C08L21/00 , C08L23/283 , C08L77/00 , C08L23/28 , C08L2666/20 , C08L2666/04 , C08L2666/02
摘要： The present invention is a blend of a thermoplastic engineering resin and an interpolymer of, on one embodiment, a C4 to C7 isomonoolefin, a para-methylstyrene and a para-(halomethylstyrene), the interpolymer having been pre-mixed with an exfoliated-clay, the entire blend forming a nanocomposite. The resin may or may not have a clay present prior to blending with the interpolymer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an air barrier.
摘要翻译： 本发明是一种热塑性工程树脂和一种互聚物的混合物，在一个实施方案中，C 4-14 C 6 - 异丁烯烯烃，对甲基苯乙烯和对 - （卤代甲基苯乙烯），共聚体已经与剥离粘土预混合，整个共混物形成纳米复合材料。 在与共聚体共混之前，树脂可以具有也可以不具有粘土。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为空气屏障。
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18.发明授权公开(公告)号：US09266812B2
公开(公告)日：2016-02-23
申请号：US13332644
申请日：2011-12-21
IPC分类号： C10M107/42 , C07C67/343 , C08F283/14 , C08F299/00 , C10M145/14 , C08G61/12
CPC分类号： C07C67/343 , C08F283/14 , C08F299/00 , C08G61/12 , C08G2261/419 , C08G2261/724 , C10M145/14 , C10M2205/08 , C10M2209/084 , C07C69/608
摘要： Provided is a comb polyolefin. The comb polyolefin has a copolymer of a multifunctional acrylate monomer and a α,ω-diene monomer terminated with a polyolefin substituent. There is also a process for making a comb polyolefin. There is also a polymer backbone. There is also a polyolefin blend. There is also a lubricant composition including the comb polyolefin.
摘要翻译： 提供梳状聚烯烃。 梳形聚烯烃具有多官能丙烯酸酯单体与以聚烯烃取代基封端的α，ω-二烯单体的共聚物。 还有一种制备梳形聚烯烃的方法。 还有一个聚合物骨架。 还有一种聚烯烃混合物。 还有一种包括梳形聚烯烃的润滑剂组合物。
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19.发明授权Enhanced durability performance of lubricants using functionalized metal phosphate nanoplatelets 有权使用功能化金属磷酸盐纳米片增强润滑剂的耐久性能公开(公告)号：US09228149B2
公开(公告)日：2016-01-05
申请号：US13928687
申请日：2013-06-27
IPC分类号： C10M125/24
CPC分类号： C10M125/24 , C10M2201/085 , C10M2203/1006 , C10M2203/1025 , C10M2205/00 , C10M2205/0285 , C10M2215/28 , C10N2220/021 , C10N2220/022 , C10N2220/082 , C10N2220/084 , C10N2230/02 , C10N2230/06 , C10N2240/10 , C10N2250/12 , C10N2210/04
摘要： A method for improving wear protection in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil having a HTHS viscosity of less than 2.6 cP at 150° C. The formulated oil has a composition including a major amount of a lubricating oil base stock and a minor amount of metal phosphate nanoplatelets. The metal phosphate nanoplatelets are dispersed in the lubricating oil base stock sufficient for the formulated oil to pass wear protection requirements of one or more engine tests selected from TU3M, Sequence IIIG, Sequence IVA and OM646LA. Also provided are lubricating engine oil composition having improved wear protection.
摘要翻译： 在150℃下使用具有小于2.6cP的HTHS粘度的配制油作为润滑油，通过润滑油润滑的发动机中改善磨损保护的方法。配制油具有主要量的润滑油 油基料和少量金属磷酸盐纳米片。 金属磷酸盐纳米片分散在润滑油基础原料中足以使配方油通过一种或多种选自TU3M，序列IIIG，序列IVA和OM646LA的发动机试验的耐磨保护要求。 还提供了具有改进的磨损保护的润滑发动机油组合物。
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公开(公告)号：US08840996B2
公开(公告)日：2014-09-23
申请号：US13329792
申请日：2011-12-19
IPC分类号： B32B9/00
CPC分类号： C08K3/36 , C08K3/32 , C08K7/14 , C08K9/06 , C08K2003/328 , C08L23/0815 , Y10T428/2993 , Y10T428/2995 , C08L23/26
摘要： A process for making a silica-polyolefin composite. The process has the steps of (a) reacting silica particles and an alkyl halosilane in the presence of a solvent and a catalyst to form silane-functionalized silica particles and (b) reacting the silane-functionalized silica particles with a vinyl-terminated polyolefin. There are other processes for making a silica-polyolefin composites. There are other processes for making metal phosphate-polyolefin composites.
摘要翻译： 一种制备二氧化硅 - 聚烯烃复合材料的方法。 该方法具有以下步骤：（a）在溶剂和催化剂存在下使二氧化硅颗粒和烷基卤硅烷反应形成硅烷官能化二氧化硅颗粒，和（b）硅烷官能化二氧化硅颗粒与乙烯基封端的聚烯烃反应。 还有其他制备二氧化硅 - 聚烯烃复合材料的方法。 制备金属磷酸盐 - 聚烯烃复合材料还有其他工艺。
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