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公开(公告)号：US5831139A
公开(公告)日：1998-11-03
申请号：US832321
申请日：1997-03-26
CPC分类号： C10G59/00 , Y10S585/94
摘要： A process combination is disclosed to selectively upgrade naphtha in accordance with expected trends leading to more-aliphatic gasolines. Such gasolines contain lower concentrations of aromatics and have lower end points with concomitant reduced harmful automotive emissions. The present process combination converts the higher-boiling portion of the naphtha, yields isobutane and other isoparaffins which are particularly suitable for upgrading or blending, and reduces cyclics in intermediate processing steps.
摘要翻译： 公开了一种方法组合以根据导致更多脂肪族汽油的预期趋势选择性地升级石脑油。 这种汽油含有较低浓度的芳族化合物，具有较低的终点，同时减少有害的汽车排放。 本方法组合转化石脑油的较高沸点部分，产生特别适用于升级或混合的异丁烷和其它异链烷烃，并减少中间处理步骤中的循环。
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公开(公告)号：US5716897A
公开(公告)日：1998-02-10
申请号：US685763
申请日：1996-07-24
CPC分类号： B01J29/85 , B01J29/126 , B01J2229/26 , B01J2229/42
摘要： Applicants have developed a catalyst for various hydrocarbon conversion processes which is tolerant to the presence of large mounts of sulfur (1000 ppm) in the feedstream. The catalyst consists of a MeAPSO support that has dispersed thereon palladium and a modifier such as lanthanum or dysprosium.
摘要翻译： 申请人已经开发了用于各种烃转化方法的催化剂，其耐受在进料流中存在大量的硫（1000ppm）。 催化剂由分散有钯和改性剂如镧或镝的MeAPSO载体组成。
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公开(公告)号：US5366617A
公开(公告)日：1994-11-22
申请号：US997971
申请日：1992-12-28
IPC分类号： B01J29/63 , C10G35/09 , C10G35/095
CPC分类号： B01J29/61 , B01J29/63 , C10G35/095
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a catalyst containing a platinum-group metal, a nonacidic large-pore molecular sieve, and a metal modifier which is positioned on the catalyst to be extrinsic to the pores of the molecular sieve. The use of this catalyst results in greater selectivity converting paraffins to aromatics and improved catalyst stability particularly when processing feedstocks containing small amounts of sulfur compounds.
摘要翻译： 使用含有铂族金属，非酸性大孔分子筛和金属改性剂的催化剂来实现选择性地将烷烃脱氢环化到芳族化合物的重整方法，该催化剂位于催化剂上， 分子筛。 使用该催化剂导致更有选择性的将烷烃转化为芳族化合物和改进的催化剂稳定性，特别是当加工含少量硫化合物的原料时。
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公开(公告)号：US5314854A
公开(公告)日：1994-05-24
申请号：US974544
申请日：1992-11-12
申请人： Leonid B. Galperin
发明人： Leonid B. Galperin
IPC分类号： B01J23/40 , B01J29/04 , B01J29/068 , B01J29/60 , B01J29/62 , B01J35/00 , C07C15/02 , C10G35/085 , C10G35/095 , B01J29/10 , B01J29/32
CPC分类号： C10G35/095 , B01J29/068 , B01J29/62 , B01J35/0006 , B01J2229/26 , B01J2229/42
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a bed of catalyst particles containing multiple Group VIII (8-10) noble metals having different gradients within the catalyst particles and a nonacidic large-pore molecular sieve. The use of this bed of catalyst particles results in greater selectivity of conversion of paraffins to aromatics and improved catalyst stability, particularly in the presence of small amounts of sulfur.
摘要翻译： 使用在催化剂颗粒内具有不同梯度的不同梯度的多种VIII族（8-10）贵金属和非酸性大孔分子筛的催化剂颗粒床进行选择性地将烷烃脱氢环化成芳族化合物的重整方法。 使用这种催化剂颗粒床导致链烷烃转化为芳族化合物的更大选择性和改善的催化剂稳定性，特别是在少量硫的存在下。
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15.发明授权Arylalkane sulfonate compositions produced using isomerization, dehydrogenation, and alkylation 失效使用异构化，脱氢和烷基化生产的芳基磺酸盐组合物公开(公告)号：US06515169B1
公开(公告)日：2003-02-04
申请号：US10205672
申请日：2002-07-25
IPC分类号： C07C30928
CPC分类号： C07C15/107 , C07C2529/18 , C07C2529/70 , C10M105/06 , C10M2203/06
摘要： The present invention is a process for producing aryl-alkanes by paraffin isomerization followed by paraffin dehydrogenation and then by alkylation of an aryl compound by a lightly branched olefin. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过石蜡异构化，然后进行链烷烃脱氢，然后通过轻支化烯烃烷基化芳基化合物来制备芳基烷烃的方法。 烷基化区的流出物包括再循环到异构化步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
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公开(公告)号：US6008423A
公开(公告)日：1999-12-28
申请号：US986385
申请日：1997-12-08
CPC分类号： B01J29/40 , C07C6/123 , B01J2229/42 , C07C2521/04 , C07C2523/08 , C07C2523/18 , C07C2523/36 , C07C2527/167 , C07C2529/40 , Y02P20/52
摘要： An improved process is disclosed for the selective disproportionation and transalkylation of toluene. The process uses a zeolitic catalyst, preferably comprising a binder, containing a weak metal in a defined reduced state which is believed to provide Lewis acidity in the catalyst. The catalyst and process provide improved selectivity for the production of paraxylene.
摘要翻译： 公开了用于甲苯的选择性歧化和烷基转移的改进方法。 该方法使用优选包含粘合剂的沸石催化剂，其含有限定还原态的弱金属，据信其在催化剂中提供路易斯酸度。 催化剂和方法为对二甲苯的生产提供了改进的选择性。
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公开(公告)号：US5888922A
公开(公告)日：1999-03-30
申请号：US648632
申请日：1996-05-13
申请人： Leonid B. Galperin
发明人： Leonid B. Galperin
CPC分类号： B01J31/1616 , B01J31/183 , B01J2231/52 , B01J2531/025 , B01J2531/824 , B01J2531/845 , B01J2531/847
摘要： A catalyst system is described and claimed which is useful for various hydrocarbon conversion processes and is tolerant to large amounts of sulfur (about 30,000 ppm sulfur) in the feedstream. The catalyst comprises a first component which comprises at least one Group VIII metal dispersed on an inorganic oxide support and a second component comprising a metal phthalocyanine dispersed on an inorganic oxide support. Preferred Group VIII metals are platinum and palladium, while preferred metal phthalocyanines are cobalt or nickel phthalocyanine. Preferred inorganic oxide supports are molecular sieves, aluminas and mixtures thereof.
摘要翻译： 描述和要求保护的催化剂体系，其可用于各种烃转化方法，并且在进料流中耐受大量硫（约30,000ppm硫）。 催化剂包含第一组分，其包含分散在无机氧化物载体上的至少一种Ⅷ族金属和包含分散在无机氧化物载体上的金属酞菁的第二组分。 优选的VIII族金属是铂和钯，而优选的金属酞菁是钴或镍酞菁。 优选的无机氧化物载体是分子筛，氧化铝及其混合物。
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公开(公告)号：US5464800A
公开(公告)日：1995-11-07
申请号：US378117
申请日：1995-01-24
IPC分类号： B01J29/068 , B01J29/62 , B01J35/00 , C10G35/095 , B01J29/60
CPC分类号： C10G35/095 , B01J29/068 , B01J29/62 , B01J35/0006 , B01J2229/26 , B01J2229/42 , B01J35/008
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a bed of catalyst particles containing multiple Group VIII (8-10) noble metals having different gradients within the catalyst particles and a nonacidic large-pore molecular sieve. The use of this bed of catalyst particles results in greater selectivity of conversion of paraffins to aromatics and improved catalyst stability, particularly in the presence of small amounts of sulfur.
摘要翻译： 使用在催化剂颗粒内具有不同梯度的不同梯度的多种VIII族（8-10）贵金属和非酸性大孔分子筛的催化剂颗粒床进行选择性地将烷烃脱氢环化成芳族化合物的重整方法。 使用这种催化剂颗粒床导致链烷烃转化为芳族化合物的更大选择性和改善的催化剂稳定性，特别是在少量硫的存在下。
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公开(公告)号：US5463155A
公开(公告)日：1995-10-31
申请号：US151692
申请日：1993-11-15
CPC分类号： C10G59/02
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain an isoparaffin-rich product for blending into gasoline. A naphtha feedstock is subjected to ring cleavage to convert naphthenes to paraffins using a nonacidic catalyst followed by isomerization of paraffins to obtain an increased proportion of isoparaffins.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得用于混合成汽油的富含异链烷烃的产物。 将石脑油原料进行环切割，使用非酸催化剂将环烷烃转化成链烷烃，随后将链烷烃异构化，以获得比例增加的异链烷烃。
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公开(公告)号：US07811964B2
公开(公告)日：2010-10-12
申请号：US10990378
申请日：2004-11-17
CPC分类号： C10G35/09 , B01J23/6567 , B01J35/0093 , B01J37/0009 , B01J37/0207 , B01J37/24 , C10G35/085
摘要： A process for preparing a naphtha reforming catalyst has been developed. The process involves the use of a chelating ligand such as ethylenediaminetetraacetic acid (EDTA). The aqueous solution of the chelating ligand and a tin compound is used to impregnate a support, e.g., alumina extrudates. A platinum-group metal is also an essential component of the catalyst. Rhenium may also be a component. A reforming process using the catalyst has enhanced yield, activity, and stability for conversion of naphtha into valuable gasoline and aromatic products.
摘要翻译： 已经开发了制备石脑油重整催化剂的方法。 该方法包括使用螯合配体如乙二胺四乙酸（EDTA）。 螯合配体和锡化合物的水溶液用于浸渍载体，例如氧化铝挤出物。 铂族金属也是催化剂的重要组成部分。 铼也可以是组分。 使用该催化剂的重整方法具有提高的石脑油转化成贵重汽油和芳香族产物的产率，活性和稳定性。
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